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Elucidating Atropisomerism in Nonplanar Porphyrins with Tunable Supramolecular Complexes

Karolis Norvaiša、John E. O’Brien、Dáire Gibbons 等 4 位作者2020-08-17Chemistry - A European Journal

Atropisomerism is a fundamental feature of substituted biaryls resulting from rotation around the biaryl axis. Different stereoisomers are formed due to restricted rotation about the single bond, a situation often found in substituted porphyrins. Previously NMR determination of porphyrin atropisomers proved difficult,…

Porphyrin and Phthalocyanine ChemistryMolecular spectroscopy and chiralityAxial and Atropisomeric Chirality Synthesis

Orthogonal long-period fiber grating for directly exciting the orbital angular momentum

Zhao Liu、Guoxuan Zhu、Yali Li 等 8 位作者2020-08-17Optics Express

An orthogonal long-period fiber grating (OLPFG) is proposed and demonstrated for directly exciting the orbital angular momentum (OAM), without the need for other devices. This grating was produced using CO2 laser exposure in the orthogonal direction. A helical phase was then optically induced in the OLPFG, with a chir…

Plasmonic and Surface Plasmon ResearchOrbital Angular Momentum in OpticsOptical Coatings and Gratings

Orthogonal Printable Reduced Graphene Oxide 2D Materials as Hole Transport Layers for High-Performance Inverted Polymer Solar Cells: Sheet Size Effect on Photovoltaic Properties

Jong‐Jin Park、Youn‐Jung Heo、Jin-Mun Yun 等 7 位作者2020-08-17ACS Applied Materials & Interfaces

Creating an orthogonal printable hole-transporting layer (HTL) without damaging the underlying layer is still a major challenge in fabricating large-area printed inverted polymer solar cells (PSCs). In this study, we prepared orthogonal-processable fluorine-functionalized reduced graphene oxide (FrGO) series with vari…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsNanowire Synthesis and Applications

High-Performance, Vacuum-Free, and Self-Powered CsPbIBr2 Photodetectors Boosted by Ultra-Wide-Bandgap Ga2O3 Interlayer

Zeyulin Zhang、Wentao Zhang、Qubo Jiang 等 11 位作者2020-08-17IEEE Electron Device Letters

In this letter, ultra-wide-bandgap Ga2O3as the interlayer is grown by mist chemical vapor deposition (mist-CVD) between perovskite and TiO2electron transport layer in perovskite photodetectors (PDs). To get a stable working condition and low-cost fabrication, all-inorganic CsPbIBr2is adopted and the expensive vacuum-d…

GaN-based semiconductor devices and materialsPerovskite Materials and ApplicationsGa2O3 and related materials

Room temperature infrared detectors made of PbTe/CdTe multilayer composite

S. Chusnutdinow、S. Schreyeck、S. Kret 等 5 位作者2020-08-17Applied Physics Letters

We report on fabrication and characterization of infrared detectors made of a composite material—PbTe/CdTe multilayer (ML). The multilayer consists of 10 repetitions of 35 nm thick PbTe layers and 75 nm thick CdTe layers grown by molecular beam epitaxy on GaAs (100) semi-insulating substrates. Simple technological met…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsAdvanced Semiconductor Detectors and Materials

Multiple-Labeled Antibodies Behave Like Single Emitters in Photoswitching Buffer

Dominic A. Helmerich、Gerti Beliu、Markus Sauer2020-08-17ACS Nano

Abstract The degree of labeling (DOL) of antibodies has so far been optimized for high brightness and specific and efficient binding. The influence of the DOL on the blinking performance of antibodies used in direct stochastic optical reconstruction microscopy (dSTORM) has so far attained limited attention. Here, we i…

Advanced biosensing and bioanalysis techniquesAdvanced Fluorescence Microscopy TechniquesPhotochromic and Fluorescence Chemistry

A GPU implementation of classical density functional theory for rapid prediction of gas adsorption in nanoporous materials

Musen Zhou、Jianzhong Wu2020-08-17The Journal of Chemical Physics

Nanoporous materials are promising as the next generation of absorbents for gas storage and separation with ultrahigh capacity and selectivity. The recent advent of data-driven approaches in materials modeling provides alternative routes to tailor nanoporous materials for customized applications. Typically, a data-dri…

Metal-Organic Frameworks: Synthesis and ApplicationsZeolite Catalysis and SynthesisMachine Learning in Materials Science

Controlled nano-particle dyeing of cotton can ensure low cytotoxicity risk with multi-functional property enhancement

Asimananda Khandual、Nibedita Rout、Suresh K. Verma 等 9 位作者2020-08-17Materials Today Chemistry

The Nanoparticle (NP) and their oxides are being progressively used and expected to be more frequently used in textiles. Nanoparticle (NP) has higher toxicological risk than larger particles because of their physicochemical properties, chemical reactivity and biological activity. In fact, the stability of nano-oxide p…

Nanoparticles: synthesis and applicationsDyeing and Modifying Textile FibersTextile materials and evaluations

On the Use of the Angle of Incidence in Support Vector Regression Surrogate Models for Practical Reflectarray Design

Daniel R. Prado、Jesús A. López‐Fernández、Manuel Arrebola 等 4 位作者2020-08-17IEEE Transactions on Antennas and Propagation

A common approach in the literature when obtaining surrogate models of reflectarray unit cells is to include, among other variables, the angles of incidence as input variables to the model. In this work, we use support vector regression (SVR) to compare this approach with a new strategy which consists in grouping the…

Metamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface TechnologiesAntenna Design and Optimization

Realization of Inverted Organic Solar Cells by Using Sol-Gel Synthesized ZnO/Y2O3 Core/Shell Nanoparticles as Electron Transport Layer

Prerna Mahajan、Anoop Singh、Ram Datt 等 5 位作者2020-08-17IEEE Journal of Photovoltaics

In this article, we describe a simple, low-cost, and environment friendly sol-gel technique to form an effective protective Y2O3 layer over the core ZnO surface. The synthesized ZnO/Y2O3 core/shell nanoparticles have been studied for the investigation of morphology, purity, structure, luminescence, and electronic prop…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Design of a Novel IPMSM Bridge for Torque Ripple Reduction

Cheon-Ho Song、Do-Hyun Kim、Ki‐Chan Kim2020-08-17IEEE Transactions on Magnetics

The interior permanent magnet synchronous motor uses a barrier structure to block the magnetic flux circulating inside the rotor and to send the magnetic flux into the air gap. Although the airgap magnetic flux density can be increased through the barrier, there is the disadvantage of increased torque ripple. Thus, th…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsMagnetic Bearings and Levitation Dynamics

The Use of High-Intensity Focused Ultrasound for the Rewarming of Cryopreserved Biological Material

Alberto Olmo、Pablo Barroso、Fatima Barroso 等 4 位作者2020-08-17IEEE Transactions on Ultrasonics Ferroelectrics and Frequency Control

High-intensity focused ultrasound (HIFU) has been used in different medical applications in the last years. In this work, we present for the first time the use of HIFU in the field of cryopreservation, the preservation of biological material at low temperatures. An HIFU system has been designed with the objective of a…

Ultrasound and Hyperthermia ApplicationsMicrofluidic and Bio-sensing TechnologiesUltrasound and Cavitation Phenomena

Comparison of Capillary Flow Porometry (CFP) and Liquid Extrusion Porometry (LEP) Techniques for the Characterization of Porous and Face Mask Membranes

René Israel Peinador、J.I. Calvo、R. Ben Aïm2020-08-17Applied Sciences

This work aims to study the characterization of several membrane filters by using capillary flow porometry (CFP) and liquid extrusion porometry (LEP) to obtain their pore size distributions (PSD) and mean pore diameters (davg). Three polymeric membranes of different materials namely, polyethylene (PET), cellulose nitr…

Membrane Separation TechnologiesSurface Modification and SuperhydrophobicityHigh voltage insulation and dielectric phenomena

Interactions between Transition-Metal Surfaces and MoS2 Monolayers: Implications for Hydrogen Evolution and CO2 Reduction Reactions

Avdhoot Datar、Maya Bar‐Sadan、Ashwin Ramasubramaniam2020-08-17The Journal of Physical Chemistry C

Transition-metal dichalcogenides (TMDs), such as molybdenum disulfide (MoS 2 ), are of significant current interest as inexpensive, earth-abundant catalysts for reactions such as electrochemical hydrogen evolution and CO 2 reduction. While several high-throughput studies have focused on understanding the relative acti…

Electrocatalysts for Energy Conversion2D Materials and ApplicationsAdvanced battery technologies research

Structural Analysis of Single-Sided Axial-Flux Permanent Magnet Machines With Different Magnetic Materials

Wenlong Li、Pengzhao Song、Shruthi Mukundan 等 8 位作者2020-08-17IEEE Transactions on Magnetics

Structural analysis of single-sided axial-flux permanent magnet (AFPM) machines for automotive cooling applications is presented in this article. First, the machine configuration and various magnetic materials for this machine, namely, electrical steel (ES) and soft magnetic composite (SMC), are introduced. Second, an…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsMagnetic Bearings and Levitation Dynamics

Multipath Data Storage by Third-Order Nonlinear Optical Properties in Zinc Oxide Nanostructures

Federico Ortíz-Trejo、M. Trejo-Valdéz、Juan Pablo Campos-López 等 5 位作者2020-08-17Applied Sciences

Simultaneous activation of multiphotonic absorption and nonlinear optical refraction were employed for developing a multipath load balancing technique assisted by light and zinc oxide nanostructures. Data storage as the real and imaginary part of the third-order nonlinear optical behavior of different regions in bidim…

Gold and Silver Nanoparticles Synthesis and ApplicationsNonlinear Optical Materials StudiesLaser-Ablation Synthesis of Nanoparticles

Microscopic description of quadrupole-octupole coupling in actinides with the Gogny-D1M energy density functional

R. Rodrı́guez-Guzmán、Y M Humadi、L M Robledo2020-08-17Journal of Physics G Nuclear and Particle Physics

Abstract The interplay between quadrupole and octupole degrees of freedom is discussed in a series of U, Pu, Cm and Cf isotopes both at the mean-field level and beyond. In addition to the static Hartree–Fock–Bogoliubov approach, dynamical beyond-mean-field correlations are taken into account via both parity restoratio…

Nuclear physics research studiesRare-earth and actinide compoundsNuclear Materials and Properties

Synthesis of multiwalled carbon nanotubes from polyethylene waste to enhance the rheological behavior of lubricating grease

Ateyya A. Aboul‐Enein、Enas Arafa、Samira M. Abdel-Azim 等 4 位作者2020-08-17Fullerenes Nanotubes and Carbon Nanostructures

Carbon nanotubes (CNTs) are attracting great interest in enhancing rheological behavior and thermal performance of lubricating grease. In this study, CNTs were synthesized by catalytic chemical vapor deposition (CCVD) method using low-density polyethylene (LDPE) waste as a cheap carbon source and Co/MgO as an effectiv…

Polymer crystallization and propertiesLubricants and Their Additives

On-Surface Self-Assembly of Metal-Organic Architectures: Insights from Computer Simulations

Karolina Gdula、Damian Nieckarz2020-08-17The Journal of Physical Chemistry C

Molecular self-assembly based on the spontaneous arrangement of simple, functional molecules on atomically flat surfaces has been recognized, in the past decades, as an extremely useful tool for the rational fabrication of one-atom-thick nanomaterials, with potential application in heterogeneous catalysis, selective a…

Molecular Junctions and NanostructuresBlock Copolymer Self-AssemblySurface Chemistry and Catalysis

Probabilistic seismic loss estimation of aging highway bridges subjected to multiple earthquake events

Bhaskar Panchireddi、Jayadipta Ghosh2020-08-17Structure and Infrastructure Engineering

This study investigates the seismic life-cycle cost of aging highway bridges under chloride exposure when subjected to multiple main shock earthquake events along the design lifetime of the structure. While chloride induced corrosion manifests as a continuous deterioration process, earthquake occurrences are typically…

Corrosion Behavior and InhibitionInfrastructure Maintenance and MonitoringConcrete Corrosion and Durability