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On Going to a New Era of Microgel Exhibiting Volume Phase Transition

Haruma Kawaguchi2020-08-17Gels

The discovery of phenomena of volume phase transition has had a great impact not only on bulk gels but also on the world of microgels. In particular, research on poly(N-isopropylacrylamide) (PNIPAM) microgels, whose transition temperature is close to body temperature, has made remarkable progress in almost 35 years. T…

Liquid Crystal Research AdvancementsHydrogels: synthesis, properties, applicationsAdvanced Materials and Mechanics

Undecidability of the Spectral Gap in One Dimension

Johannes Bausch、Toby S. Cubitt、Angelo Lucia 等 4 位作者2020-08-17Physical Review X

A new analysis proves that it is not possible for numerical algorithms to determine if a 1D quantum system has a spectral gap, showing that basic properties of even simple systems are, in some instances, impossible to predict.

Quantum Computing Algorithms and ArchitectureQuantum many-body systemsQuasicrystal Structures and Properties

Functional Heterochain Polymers Constructed by Alkyne Multicomponent Polymerizations

Xiaolin Liu、Ting Han、Jacky W. Y. Lam 等 4 位作者2020-08-17Macromolecular Rapid Communications

Heterochain polymers such as DNA and proteins are abundant in nature, but they are not ubiquitous in man-made polymers due to the synthetic difficulties. Traditional polymerization methodologies including chain polymerization, step-growth polymerization, and coordination polymerization all show obvious drawbacks in sy…

Organic Electronics and PhotovoltaicsSynthetic Organic Chemistry MethodsSynthesis and properties of polymers

Sustainable Preparation of Microcapsules with Desirable Stability and Bioactivity Using Phosphonium Ionic Liquid as a Functional Additive

Jiale Yang、Zhiyuan Zhou、You Liang 等 10 位作者2020-08-17ACS Sustainable Chemistry & Engineering

A microcapsule is an ideal choice to realize effective utilization of a pesticide and reduce environmental pollution. A novel preparation method of a microcapsule was developed by complex coacervation of phosphonium ionic liquid (PIL) with gelatin. PIL was newly synthesized and used to dissolve and disperse avermectin…

Nanoparticles: synthesis and applicationsNanocomposite Films for Food PackagingPolymer-Based Agricultural Enhancements

The interaction of shockwaves with a vapour bubble in boiling histotripsy: The shock scattering effect

Ki Joo Pahk、Sunho Lee、Pierre Gélat 等 5 位作者2020-08-17Ultrasonics Sonochemistry

Boiling histotripsy is a High Intensity Focused Ultrasound (HIFU) technique which uses a number of short pulses with high acoustic pressures at the HIFU focus to induce mechanical tissue fractionation. In boiling histotripsy, two different types of acoustic cavitation contribute towards mechanical tissue destruction:…

Ultrasound and Hyperthermia ApplicationsUltrasound and Cavitation PhenomenaPhotoacoustic and Ultrasonic Imaging

Near-Infrared Radiation-Based Mild Photohyperthermia Therapy of Non-Melanoma Skin Cancer with PEGylated Reduced Nanographene Oxide

Raquel Costa‐Almeida、Diana Bogas、José R. Fernandes 等 9 位作者2020-08-17Polymers

Using a one-step thermal reduction and non-covalent chemical functionalization process, PEGylated reduced nanographene oxide (rGOn-PEG) was produced from nanographene oxide (GOn) and characterized in terms of particle size, dispersion stability, chemistry, and photothermal properties, in view of its use for phototherm…

Nanoplatforms for cancer theranosticsCarbon and Quantum Dots ApplicationsGraphene and Nanomaterials Applications

First principles investigation of thermoelectric and mechanical properties of VScO3 semiconductor perovskite for sustainable and renewable energy

Nada T. Mahmoud、Ahmad A. Mousa、Jamil M. Khalifeh2020-08-17Results in Physics

Semiconductor perovskite material has given important interest as a potential thermoelectric material (TE) due to its large thermopower (Seebeck coefficient, S). VScO3 Semiconductor Perovskite is investigated by the Density Functional Theory (DFT) using full potential linearized augmented plane wave (FP-LAPW) method w…

Perovskite Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesHeusler alloys: electronic and magnetic properties

Electrochemical performance and storage mechanism study of conjugate donor–acceptor organic polymers as anode materials of lithium-ion battery

Qing Yuan、Chunxia Li、Xin Guo 等 8 位作者2020-08-17Energy Reports

The low redox potential of conjugated donor–acceptor (D–A) type polymer due to strong electron interaction between donor units and acceptor units is benefit to increase the power density, which is suitable to serve as the anode materials of lithium-ion battery. In this paper, the D–A type polymers containing phenanthr…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesConducting polymers and applications

Poly(amidoamine) Dendrimer-Gold Nanohybrids in Cancer Gene Therapy: A Concise Overview

Jin Li、Mingwu Shen、Xiangyang Shi2020-08-17ACS Applied Bio Materials

Nonviral gene delivery has been considered as a powerful tool for cancer therapy because of its inherent advantages of nontoxicity, high specificity, and therapeutic efficacy. Successful cancer gene therapy mostly depends on the design of highly efficient and nontoxic vectors that can compress genetic materials and ef…

Advanced biosensing and bioanalysis techniquesRNA Interference and Gene DeliveryDendrimers and Hyperbranched Polymers

Physical properties of graphene-oxide modified asphalt and performance analysis of its mixtures using response surface methodology

Abbas Mukhtar Adnan、Xue Luo、Chaofeng Lü 等 5 位作者2020-08-17International Journal of Pavement Engineering

In this work, the effect of graphene oxide (GO) on the physical performance related properties of an asphalt binder was investigated in terms of penetration, softening point, viscosity (110–185°C), and ductility as well as temperature performance indices. Subsequently, response surface methodology (RSM) was used to ex…

Asphalt Pavement Performance EvaluationPolymer Nanocomposites and PropertiesInfrastructure Maintenance and Monitoring

On the Synergistic Effect of Multi-Walled Carbon Nanotubes and Graphene Nanoplatelets to Enhance the Functional Properties of SLS 3D-Printed Elastomeric Structures

Gennaro Rollo、Alfredo Ronca、Pierfrancesco Cerruti 等 11 位作者2020-08-17Polymers

Elastomer-based porous structures realized by selective laser sintering (SLS) are emerging as a new class of attractive multifunctional materials. Herein, a thermoplastic polyurethane (TPU) powder for SLS was modified by 1 wt.% multi-walled carbon nanotube (MWCNTs) or a mixture of MWCNTs and graphene (GE) nanoparticle…

Conducting polymers and applicationsAdditive Manufacturing and 3D Printing TechnologiesPolymer Nanocomposite Synthesis and Irradiation

Bond dissociation energies of transition metal oxides: CrO, MoO, RuO, and RhO

Jason J. Sorensen、Erick Tieu、Andrew Sevy 等 7 位作者2020-08-17The Journal of Chemical Physics

Through the use of resonant two-photon ionization spectroscopy, sharp predissociation thresholds have been identified in the spectra of CrO, MoO, RuO, and RhO. Similar thresholds have previously been used to measure the bond dissociation energies (BDEs) of many molecules that have a high density of vibronic states at…

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and SensorsRadioactive element chemistry and processing

Thermoresponsive Cationic Block Copolymer Brushes for Temperature‐Modulated Stem Cell Separation

Kenichi Nagase、Ayumu Ota、Tadashi Hirotani 等 6 位作者2020-08-17Macromolecular Rapid Communications

Recently, cell separation methods have become important for preparing cells for transplantation therapy. In this study, a thermoresponsive cationic block copolymer brush is developed as an effective cell separation tool. This brush is prepared on glass surfaces using two steps of activator regenerated by electron tran…

Hydrogels: synthesis, properties, applicationsPolymer Surface Interaction Studies3D Printing in Biomedical Research

Anisotropically Conductive Biodegradable Scaffold with Coaxially Aligned Carbon Nanotubes for Directional Regeneration of Peripheral Nerves

Souvik Ghosh、Swati Haldar、Sumeet Gupta 等 8 位作者2020-08-17ACS Applied Bio Materials

Fascicular rearrangement of an injured peripheral nerve requires reconnection of nerve sprouts from anterior and Büngner bands from distal sides of the lesion, failing to which leads to inefficient regeneration of the injured nerve. However, existing neural scaffolds have limited neuroregeneration efficiency because o…

Nerve injury and regenerationElectrospun Nanofibers in Biomedical ApplicationsGraphene and Nanomaterials Applications

Mucoadhesive Ionic Liquid Gel Patches for Oral Delivery

Kevin Peng、Yujie Shi、Anthony Labarbiera 等 4 位作者2020-08-17ACS Biomaterials Science & Engineering

Oral delivery of biologic drugs is a highly desired yet challenging goal because of the many barriers posed by the GI tract. Ionic liquids (ILs) and deep eutectic solvents (DESs) such as choline and geranate (CAGE) have demonstrated the potential to improve intestinal absorption of insulin and poorly soluble drugs. As…

Advanced Drug Delivery SystemsOcular Surface and Contact LensPickering emulsions and particle stabilization

Cytotoxicity and Immune Dysfunction of Dendritic Cells Caused by Graphene Oxide

Zhiwen Yang、Yongning Pan、Tingting Chen 等 9 位作者2020-08-17Frontiers in Pharmacology

Graphene, known as “black gold”, has important applications in various fields. In previous studies, it has been proved that graphene oxide (GO) which is a derivative of graphene has low toxicity. However, the immunotoxicity of GO has not been fully elucidated. In this work, we used DC2.4 cell line to investigate the i…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applicationsGraphene and Nanomaterials Applications

Complementary Resistive Switching and Synaptic-Like Memory Behavior in an Epitaxial SrFeO2.5 Thin Film through Oriented Oxygen-Vacancy Channels

Venkata Raveendra Nallagatla、Jihun Kim、Kyoungjun Lee 等 6 位作者2020-08-17ACS Applied Materials & Interfaces

Oxygen-vacancy-ordered brownmillerite oxides offer a reversible topotactic phase transition by significantly varying the oxygen stoichiometry of the material without losing its lattice framework. This phase transition leads to substantial changes in the physical and chemical properties of brownmillerite oxides, includ…

Advanced Memory and Neural ComputingElectronic and Structural Properties of OxidesFerroelectric and Negative Capacitance Devices

Uniting Drug and Delivery: Metal Oxide Hybrid Nanotherapeutics for Skin Wound Care

Martin T. Matter、Sebastian Probst、Severin Läuchli 等 4 位作者2020-08-17Pharmaceutics

Wound care and soft tissue repair have been a major human concern for millennia. Despite considerable advancements in standards of living and medical abilities, difficult-to-heal wounds remain a major burden for patients, clinicians and the healthcare system alike. Due to an aging population, the rise in chronic disea…

Nanoparticles: synthesis and applicationsElectrospun Nanofibers in Biomedical ApplicationsWound Healing and Treatments

The ups and downs of ectoine: structural enzymology of a major microbial stress protectant and versatile nutrient

Lucas Hermann、Christopher-Nils Mais、Laura Czech 等 6 位作者2020-08-17Biological Chemistry

Ectoine and its derivative 5-hydroxyectoine are compatible solutes and chemical chaperones widely synthesized by Bacteria and some Archaea as cytoprotectants during osmotic stress and high- or low-growth temperature extremes. The function-preserving attributes of ectoines led to numerous biotechnological and biomedica…

Probiotics and Fermented FoodsMicrobial Metabolic Engineering and BioproductionEnzyme Structure and Function

Organic Resonance Materials: Molecular Design, Photophysical Properties, and Optoelectronic Applications

He Jiang、Yang Cao、Qingqing Yang 等 7 位作者2020-08-17The Journal of Physical Chemistry Letters

Organic optoelectronic molecules with resonance effects are a striking class of functional materials that have witnessed booming progress in recent years. Various resonances induced by particularly constructed molecular structures can effectively influence key photophysical processes to afford particular optoelectroni…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials