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Single-Molecular Catalysis Identifying Activation Energy of the Intermediate Product and Rate-Limiting Step in Plasmonic Photocatalysis

Wei Li、Junjian Miao、Tianhuan Peng 等 8 位作者2020-03-17Nano Letters

Plasmon-mediated photocatalysis provides a novel strategy for harvesting solar energy. Identification of the rate-determining step and its activation energy in plasmon-mediated photocatalysis plays critical roles for understanding the contribution of hot carriers, which facilitates rational designation of catalysts wi…

Advanced Photocatalysis TechniquesGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniques

Aperiodic Sunflower-Like Metasurface for Diffusive Scattering and RCS Reduction

Mustafa K. Taher Al‐Nuaimi、Wei Hong、William G. Whittow2020-03-17IEEE Antennas and Wireless Propagation Letters

This letter presents the design of aperiodic sunflower-like metasurface for circularly polarized (CP) wave diffusion and radar cross-section (RCS) reduction using Pancharatnam-Berry (PB) meta-atoms. The distribution of the PB meta-atoms across the metasurface aperture is nonuniform and has a distribution inspired by s…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Design of Dendritic Large-Pore Mesoporous Silica Nanoparticles with Controlled Structure and Formation Mechanism in Dual-Templating Strategy

Zhaoyang Guo、Liting Wu、Yan Wang 等 14 位作者2020-03-17ACS Applied Materials & Interfaces

Dendritic large-pore mesoporous silica nanoparticles (DLMSN) is an important biodegradable drug carrier due to its high porosity, which can be prepared by coassembly of a major template and an auxiliary template in aqueous solution, followed by hydrolysis of tetraethyl orthosilicate (TEOS). The auxiliary template is k…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisDendrimers and Hyperbranched Polymers

Plasmonic Nanoparticles in Dielectrics Synthesized by Ion Beams: Optical Properties and Photonic Applications

Rang Li、Chi Pang、Ziqi Li 等 4 位作者2020-03-17Advanced Optical Materials

Abstract The zero‐dimensional metallic nanoparticles (NPs) have attracted tremendous attention in various areas owing to the collective oscillation of electron gas that couples with electromagnetic field, known as localized surface plasmon resonance (LSPR). In practical applications, the tailoring of LSPR effect is of…

Gold and Silver Nanoparticles Synthesis and ApplicationsNonlinear Optical Materials Studies

Novel Quaternary Ammonium-Functionalized Covalent Organic Frameworks/Poly(2,6-dimethyl-1,4-phenylene oxide) Hybrid Anion Exchange Membranes with Enhanced Ion Conductivity and Stability

Jia Chen、Mingming Guan、Kai Li 等 4 位作者2020-03-17ACS Applied Materials & Interfaces

Abstract Here we report a new hybrid anion exchange membrane with enhanced hydroxide conductivity and excellent chemical and dimensional stability by incorporating quaternary ammonium (QA)-functionalized covalent organic framework into brominated poly­(2,6-dimethyl-1,4-phenylene oxide) (BPPO). N,N,N′,N′ -Tetramethyl-1…

Metal-Organic Frameworks: Synthesis and ApplicationsFuel Cells and Related MaterialsCovalent Organic Framework Applications

Controlling Exciton and Valley Dynamics in Two-Dimensional Heterostructures with Atomically Precise Interlayer Proximity

Hongzhi Zhou、Yida Zhao、Weijian Tao 等 6 位作者2020-03-17ACS Nano

Abstract Two-dimensional (2D) materials and heterostructures with strong excitonic effect and spin/valley properties have emerged as an exciting platform for optoelectronic and spin/valleytronic applications. There, precise control of the exciton transformation process (including intralayer to interlayer exciton trans…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Technical note: Fundamental aspects of ice nucleation via pore condensation and freezing including Laplace pressure and growth into macroscopic ice

Claudia Marcolli2020-03-17Atmospheric chemistry and physics

Abstract. Pore condensation and freezing (PCF) is an ice nucleation mechanism that explains ice formation at low ice supersaturation. It assumes that liquid water condenses in pores of solid aerosol particles below water saturation, as described by the Kelvin equation, followed by homogeneous ice nucleation when tempe…

Material Dynamics and Propertiesnanoparticles nucleation surface interactionsThermal Radiation and Cooling Technologies

Fouling and Retention Mechanisms of Selected Cationic and Anionic Dyes in a Ti 3 C 2 T x MXene-Ultrafiltration Hybrid System

Sewoon Kim、Miao Yu、Yeomin Yoon2020-03-17ACS Applied Materials & Interfaces

MXenes, a very new family of nanostructured material, were applied in combination with an ultrafiltration (UF) membrane (MXene-UF) for removal of the selected dyes including methylene blue (MB) and methyl orange (MO) as the first attempt. The normalized flux of the MXene-UF (0.90 for MB and 0.92 for MO) indicated bett…

Membrane Separation TechnologiesMXene and MAX Phase MaterialsGraphene and Nanomaterials Applications

Engineering Phase Transformation of MoS2/RGO by N-doping as an Excellent Microwave Absorber

Huiqiao Guo、Lei Wang、Wenbin You 等 10 位作者2020-03-17ACS Applied Materials & Interfaces

As a hot two-dimensional (2D) material, molybdenum disulfide has been attracting extensive attention for electromagnetic wave response applications because of its unique structure. However, the electronic conductivity of nanostructured MoS 2 needs to be optimized urgently. Here, nitrogen-doped 1T@2H-MoS 2 /reduced gra…

Advancements in Battery Materials2D Materials and ApplicationsMXene and MAX Phase Materials

3-D Printed Swastika-Shaped Ultrabroadband Water-Based Microwave Absorber

Xiaofan Zhang、Yulu Zhang、Yanjun Fu 等 8 位作者2020-03-17IEEE Antennas and Wireless Propagation Letters

In this letter, a swastika-shaped ultrabroadband metamaterials absorber is proposed. The designed absorber can be fabricated with the polylactic acid by 3-D printing, and packaged after filling with water. The absorber can achieve greater than 90% absorption in the frequency band of 9.3-49.0 GHz, with a relative bandw…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Metal Nanoparticle–Microbe Interactions: Synthesis and Antimicrobial Effects

Mujeebur Rahman Khan、Katharina M. Fromm、Tanveer Fatima Rizvi 等 8 位作者2020-03-17Particle & Particle Systems Characterization

Abstract Metal nanoparticles (NPs), chalcogenides, and carbon quantum dots can be easily synthesized from whole microorganisms (fungi and bacteria) and cell‐free sterile filtered spent medium. The particle size distribution and the biosynthesis time can be somewhat controlled through the biomass/metal solution ratio.…

Nanoparticles: synthesis and applicationsCarbon and Quantum Dots ApplicationsAdvanced Nanomaterials in Catalysis

Green Silver Nanoparticles Formed by Phyllanthus urinaria, Pouzolzia zeylanica, and Scoparia dulcis Leaf Extracts and the Antifungal Activity

Dai Hai Nguyen、Jung Seok Lee、Ki Hun Park 等 7 位作者2020-03-17Nanomaterials

Phytoconstituents presenting in herbal plant broths are the biocompatible, regenerative, and cost-effective sources that can be utilized for green synthesis of silver nanoparticles. Different plant extracts can form nanoparticles with specific sizes, shapes, and properties. In the study, we prepared silver nanoparticl…

Nanoparticles: synthesis and applicationsGraphene and Nanomaterials ApplicationsPhytochemistry and Bioactivity Studies

Effective Separation of CO2 Using Metal‐Incorporated rGO Membranes

Xiaoheng Jin、Tobias Foller、Xinyue Wen 等 13 位作者2020-03-17Advanced Materials

Abstract Graphene‐based materials, primarily graphene oxide (GO), have shown excellent separation and purification characteristics. Precise molecular sieving is potentially possible using graphene oxide‐based membranes, if the porosity can be matched with the kinetic diameters of the gas molecules, which is possible v…

Graphene research and applicationsMembrane Separation and Gas TransportMuon and positron interactions and applications

Luminescence Spectroscopy and Origin of Luminescence Centers in Bi-Doped Materials

А. Krasnikov、E. Mihóková、M. Nikl 等 5 位作者2020-03-17Crystals

Bi-doped compounds recently became the subject of an extensive research due to their possible applications as scintillator and phosphor materials. The oxides co-doped with Bi3+ and trivalent rare-earth ions were proposed as prospective phosphors for white light-emitting diodes and quantum cutting down-converting mater…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesSolid-state spectroscopy and crystallography

Engineered ZnO and CuO Nanoparticles Ameliorate Morphological and Biochemical Response in Tissue Culture Regenerants of Candyleaf (Stevia rebaudiana)

Muhammad Arslan Ahmad、Rabia Javed、Muhammad Adeel 等 6 位作者2020-03-17Molecules

Sustainable production of secondary metabolites in medicinal plants by artificial culturing on the industrial scale has gained worldwide importance. Engineered nanoparticles (ENPs) play a pivotal role in the elicitation of compounds of medicinal value. This investigation explores the influence of ZnO and CuO ENPs on i…

Nanoparticles: synthesis and applicationsMedicinal Plants and Neuroprotection

Synthesis and Characterization of Nitrogen-doped Carbon Nanotubes Derived from g-C3N4

Klaudia Maślana、Ryszard J. Kaleńczuk、Beata Zielińska 等 4 位作者2020-03-17Materials

Here, nitrogen-doped carbon nanotubes (CNT-N) were synthesized using exfoliated graphitic carbon nitride functionalized with nickel oxides (ex-g-C3N4-NixOy). CNT-N were produced at 900 °C in two steps: (1) ex-g-C3N4-NixOy reduction with hydrogen and (2) ethylene assisted chemical vapor deposition (CVD). The detailed c…

Advanced Photocatalysis TechniquesGas Sensing Nanomaterials and SensorsMXene and MAX Phase Materials

“Waste to Wealth”: Lignin as a Renewable Building Block for Energy Harvesting/Storage and Environmental Remediation

Ding Wang、Sahng Ha Lee、Jin‐Hyun Kim 等 4 位作者2020-03-17ChemSusChem

Lignin is the second most earth-abundant biopolymer having aromatic unit structures, but it has received less attention than other natural biomaterials. Recent advances in the development of lignin-based materials, such as mesoporous carbon, flexible thin films, and fiber matrix, have found their way into applications…

Supercapacitor Materials and FabricationAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Discovery of Self-Assembling ?-Conjugated Peptides by Active Learning-Directed Coarse-Grained Molecular Simulation

Kirill Shmilovich、Rachael A. Mansbach、Hythem Sidky 等 7 位作者2020-03-17The Journal of Physical Chemistry B

Abstract Electronically active organic molecules have demonstrated great promise as novel soft materials for energy harvesting and transport. Self-assembled nanoaggregates formed from ?-conjugated oligopeptides composed of an aromatic core flanked by oligopeptide wings offer emergent optoelectronic properties within a…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

A powder metallurgy route to fabricate CNT-reinforced molybdenum-hafnium-carbon composites

Yong Wei、Laima Luo、Huai-Bing Liu 等 8 位作者2020-03-17Materials & Design

An efficient powder metallurgy route including wet dispersion, high energy ball milling (HEBM) and spark plasma sintering (SPS) was proposed to fabricate carbon nanotube reinforced molybdenum‑hafnium‑carbon (CNT-reinforced MHC) composites. To improve the dispersion efficiency of carbon nanotubes (CNTs) in the molybden…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Long-term storage of lipid-like nanoparticles for mRNA delivery

Pengxuan Zhao、Xucheng Hou、Jinyue Yan 等 8 位作者2020-03-17Bioactive Materials

Lipid-like nanoparticles (LLNs) have been extensively explored for messenger RNA (mRNA) delivery in various biomedical applications. However, the long-term storage of these nanoparticles is still a challenge for their clinical translation. In this study, we investigated a series of conditions for the long-term storage…

Nanoparticle-Based Drug DeliveryLipid Membrane Structure and BehaviorRNA Interference and Gene Delivery