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Recent advances of hollow-structured sulfur cathodes for lithium–sulfur batteries

Xia Huang、Tengfei Qiu、Xinghao Zhang 等 8 位作者2020-01-01Materials Chemistry Frontiers

This review summarises recent advances of hollow-structured sulfur cathodes for high performance lithium sulfur batteries, focusing on their synthesis, structure, electrochemical performance, advantages and challenges.

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesThermal Expansion and Ionic Conductivity

Facile simultaneous synthesis of tetraaniline nanostructures/silver nanoparticles as heterogeneous catalyst for the efficient catalytic reduction of 4-nitrophenol to 4-aminophenol

Sathish Mohan Botsa、Y. Pavan Kumar、K. Basavaiah2020-01-01RSC Advances

and ammonium persulphate (APS) as monomer, oxidizing agent in immiscible solvent toluene-water respectively. The structure and morphology of the as-prepared TAN and Ag NPs were investigated by UV-visible spectroscopy, Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), field emission scanning elec…

Electrochemical sensors and biosensorsConducting polymers and applicationsNanomaterials for catalytic reactions

Luminescent coordination polymers constructed using a mixed-ligand strategy for highly selective luminescence sensing of nitrobenzene, Fe 3+ and Cr 2 O 7 2− ions and photodegradation of rhodamine B

Jun‐Jie Wang、Fei-Fan Wu、Ning Su 等 8 位作者2020-01-01CrystEngComm

Using a mixed ligand strategy, ten new LCPs were constructed. They all display highly sensitive and selective luminescence sensing for NB, Cr 2 O 7 2− and Fe 3+ ions. Moreover, 3–10 also exhibit high photocatalytic activities toward the degradation of RhB.

Metal-Organic Frameworks: Synthesis and ApplicationsLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications

Efficient aggregation-induced delayed fluorescent materials based on bipolar carrier transport materials for the fabrication of high-performance nondoped OLEDs with very small efficiency roll-off

Yan Fu、Huijun Liu、Xiangyu Zhu 等 6 位作者2020-01-01Journal of Materials Chemistry C

The integration of bipolar carrier transport materials with an aggregation-induced delayed fluorescence unit generates robust luminescent materials, which lead to efficient nondoped OLEDs with high efficiency stability.

Organic Light-Emitting Diodes ResearchLuminescence and Fluorescent MaterialsLanthanide and Transition Metal Complexes

A versatile luminescent resonance energy transfer (LRET)-based ratiometric upconversion nanoprobe for intracellular miRNA biosensing

Liang Gong、Simin Liu、Song Ya 等 7 位作者2020-01-01Journal of Materials Chemistry B

Rational design and fabrication of bio-nanoprobes for intracellular miRNA biosensing are highly desired for early clinical diagnosis and prognosis. Herein, we have developed a versatile LRET-based ratiometric (LBRU) nanoprobe of NaYF4:Yb,Er@NaYF4@NH2-mSiO2/rhodamine B/C-DNA sandwich-structured nanocomposites for intra…

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

How organic ligands affect the phase transition and fluorescent stability of perovskite nanocrystals

Hongwei Ding、Hui Jiang、Xuemei Wang2020-01-01Journal of Materials Chemistry C

We have investigated the effect of excess ligands including oleylamine (OAm) and oleic acid (OA) on the transformation of CsPbBr 3 perovskite nanocrystals and have demonstrated that these ligands play a role like a double-sided sword.

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesSolid-state spectroscopy and crystallography

Fluorination of a polymer donor through the trifluoromethyl group for high-performance polymer solar cells

Chao Yao、Yanan Zhu、Kaichen Gu 等 8 位作者2020-01-01Journal of Materials Chemistry A

Polymer donor F0 is fluorinated to F1 through converting methyl group to trifluoromethyl group on side chains. F1 exhibits remarkably improved performance in polymer solar cells with a highest PCE of 13.5%.

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Good or evil: what is the role of water in crystallization of organometal halide perovskites?

Shuang Xiao、Kai Zhang、Shizhao Zheng 等 4 位作者2020-01-01Nanoscale Horizons

Perovskite solar cells (PSCs) have the potential to become one of the most cost-efficient photovoltaic devices. However, current fabrication methods of PSCs still require strict environment control and ultrahigh purity chemicals, which could prevent their large-scale commercialization. To tackle this challenge, the ro…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesSolid-state spectroscopy and crystallography

Elucidating sensing mechanisms of a pyrene excimer-based calix[4]arene for ratiometric detection of Hg( ii ) and Ag( i ) and chemosensor behaviour as INHIBITION or IMPLICATION logic gates

Julio Rodríguez-Lavado、A. Lorente、Erick Flores 等 7 位作者2020-01-01RSC Advances

This article reports the synthesis and characterisation of two lower rim calix[4]arene derivatives with thiourea as spacer and pyrene or methylene-pyrene as fluorophore.

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Development of tethered dual catalysts: synergy between photo- and transition metal catalysts for enhanced catalysis

Danfeng Wang、Robert Malmberg、Indrek Pernik 等 9 位作者2020-01-01Chemical Science

While dual photocatalysis-transition metal catalysis strategies are extensively reported, the majority of systems feature two separate catalysts, limiting the potential for synergistic interactions between the catalytic centres. In this work we synthesised a series of tethered dual catalysts allowing us to investigate…

Advanced Photocatalysis TechniquesRadical Photochemical ReactionsCovalent Organic Framework Applications

How do chemical patterns affect equilibrium droplet shapes?

Yanchen Wu、Fei Wang、Shaoping Ma 等 5 位作者2020-01-01Soft Matter

By utilizing a proposed analytical model in combination with the phase-field method, we present a comprehensive study on the effect of chemical patterns on equilibrium droplet morphologies. Here, three influencing factors, the droplet sizes, contact angles, and the ratios of the hydrophilic area to the hydrophobic are…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat Transfernanoparticles nucleation surface interactions

Bottom-up device fabrication via the seeded growth of polymer-based nanowires

Osama El-Zubir、Emily L. Kynaston、Jessica Gwyther 等 9 位作者2020-01-01Chemical Science

the seeded growth method known as "Living crystallisation-driven self-assembly'' and demonstrate that they are capable of spanning an interelectrode gap. Finally, a chemical oxidation step was used to transform the nanofibres into nanowires to generate a two-terminal device. This seeded growth approach of growing well…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsMolecular Junctions and Nanostructures

Amino-functional polyethers: versatile, stimuli-responsive polymers

Patrick Verkoyen、Holger Frey2020-01-01Polymer Chemistry

Amino-functional polyethers have emerged as a new class of “smart”, i.e. pH- and thermoresponsive materials. This review article summarizes the synthesis and applications of these materials, obtained from ring-opening of suitable epoxide monomers.

Carbon dioxide utilization in catalysisChemical Synthesis and ReactionsSynthesis and properties of polymers

Controllable synthesis of ultrasmall Pd nanocatalysts templated by supramolecular coordination cages for highly efficient reductive dehalogenation

Wei‐Ling Jiang、Ji-Chuang Shen、Zhiyong Peng 等 7 位作者2020-01-01Journal of Materials Chemistry A

A simple and efficient supramolecular coordination cage (SCC) template-strategy is developed to synthesize Pd nanocatalysts with controllable size and size distribution for highly efficient reductive dehalogenation.

Metal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesNanocluster Synthesis and Applications