Materials Literature
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A honeycomb-like three-dimensional graphene-based aerogel applied to remove pollutants was assembled via a mild, easy-to-operate hydrothermal synthesis method.
The oxygen evolution reaction (OER) is a vital proton donor for various clean energy technologies. Here, we synthesized IrOx-decorated ultrathin NiFe-LDH nanosheets (thickness 1-2 nm) by a one-step co-precipitation method. The IrOx was uniformly dispersed on the surface of ultrathin NiFe-LDH nanosheets, greatly increa…
Here, we have successfully synthesized hierarchical structure by boronizing Ni x Co y MoO 4 nanosheets. Benefitting from the synergistic effect among Ni 3 B, Ni(BO 2 ) 2 and Ni x Co y MoO 4 in hybrid architectures, the electrode material possesses higher energy storage performance.
Supramolecular block copolymers (SBCs) have received considerable interest in polymer chemistry, materials science, biomedical engineering and nanotechnology owing to their unique structural and functional advantages, such as low cytotoxicity, outstanding biodegradability, smart environmental responsiveness, and so fo…
Regenerated silk fibroin (RSF) features excellent biocompatibility and high-strength mechanical properties. However, traditional RSF-based materials can hardly be applied in 3D printing, which has shown great potential in producing artificial implants. In this work, we report a 3D printable RSF hydrogel formed by a we…
The benzocoumarin dyes fluoresce negligibly in aqueous media but very strongly in cells, whereas representative conventional dyes display contrasting behaviour; the distinct emission behaviour of the fluorophores in organic solutions, in aqueous media, and in cell convinces the uniqueness of the cellular environment.…
Two-dimensional transition metal carbide (Ti 3 C 2 T x MXene) film as a novel electrode material for electrogenerated chemiluminescence of tris(2,2′-bipyridine)ruthenium( ii ) and peroxydisulfate.
TiO2 nanoparticles (nano-TiO2) are widely used in the world, and a considerable amount of nano-TiO2 is released into the environment, with toxic effects on organisms. In the various species of higher plants, growth, including seed germination, root elongation, and biomass accumulation, is affected by nano-TiO2. Howeve…
In this paper, new upconversion (UC) phosphors for Yb3+-Er3+- and Yb3+-Ho3+-doped Gd9.33(SiO4)6O2 (GSO) were designed via a solid-state reaction method. The phase purity of the samples was examined using XRD patterns. In Yb3+-Er3+ -doped GSO, the characteristic emission peaks of Er3+ appear upon 980 nm excitation, and…
This paper reports the syntheses, crystal structures and magnetic properties of spin crossover (SCO) salts of formulae [Mn(naphth-sal-N-1,5,8,12)]SbF6 (1), [Mn(naphth-sal-N-1,5,8,12)]AsF6 (2), [Mn(naphth-sal-N-1,5,8,12)]PF6·1/2CH3OH (3) and [Mn(naphth-sal-N-1,5,8,12)]ClO4 (4), where (naphth-sal-N-1,5,8,12)2- (2,2'-((1…
We report a redox-responsive Pickering emulsion stabilized by a selenium-based surfactant and alumina nanoparticles, in which separation of oil phase without residual surfactant and recycling of the Pickering emulsifiers from aqueous phase is possible after demulsification.
In the modern era, the escalation of heavy metal discharges, especially from the industrial sector, is causing an enormous threat to nature. This article explores the dual sensing of heavy metals (Cr6+ and Fe3+) using a naturally formed microcline based sensor. A nano-sized microcline (M) was obtained via a facile top…
Fe 3 O 4 @O 2 PO 2 (CH 2 ) 2 NH 3 + CF 3 CO 2 − as a retrievable nanocatalyst with magnetic properties was applied for the one pot preparation of terpyridines with good yields and short reaction times via a cooperative vinylogous anomeric based oxidation mechanism.
This work investigated the effect of thermal treatment in an autoclave on the chemical, physical, and morphological properties of lignocellulosic fibers from açaí (Euterpe oleracea Mart), and the behavior of this treated fiber in polypropylene (PP) matrix composites with polypropylene-graft-maleic anhydride (PPgMA) as…
Novel Janus-like 2D TiMoCO 2 MXene alloys with high performance vis-IR water-splitting photocatalytic and thermoelectric capabilities.
compared with conventional transition metal dichalcogenides (TMDs) and are potential competitors in the thermoelectric field.
The first metallasilsesquioxane of a divalent lanthanide was synthetized and structurally characterized. The dinuclear Yb( ii ) complex effects the two electrons reduction of azobenzene, and the selective CO 2 reduction to CO and carbonate.
Herein we report the synthesis, characterization, photophysical and photocytotoxicity studies of a new class of curcumin-based lanthanide(iii) complexes of general molecular formula [La(1,10-phen)2(L)(NO3)2] (1-4), where L = 1-phenylbutane-1,3-dione (L1, 1), 1-(anthracen-9-yl)butane-1,3-dione (L2, 2), 1-(3a1,5a1-dihyd…
Enhanced Gd-doped ceria electrostriction: This study uncovers new anisotropic properties in thin films, enhancing the effect along with the 〈100〉 directions by one order of magnitude and proposing a new microscopic model to explain such findings.
Surface-enhanced infrared absorption (SEIRA) can dramatically enhance the vibrational signals of analyte molecules owing to the interaction between plasmons and molecular vibrations. It has huge potential for applications in various detection and diagnostic fields. High-aspect-ratio rod-like metal nanostructures have…