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Structure–Function Correlation: Engineering High Quantum Yields in Down-Shifting Nanophosphors

D. A. Hardy、Rodney A. Tigaa、James R. McBride 等 5 位作者2019-11-27Journal of the American Chemical Society

Lanthanides are routinely incorporated into quantum dots to act as down-shifting and up-converting phosphors in display and lighting applications due to their high photoluminescence quantum yields (PLQY). Recent efforts in the field have demonstrated that trivalent lanthanide, Ln(III), incorporated into ZnAl 2 O 4 spi…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsAmmonia Synthesis and Nitrogen Reduction

Structural Orderin Cellulose Thin Films Preparedfrom a Trimethylsilyl Precursor

Andrew O. F. Jones、Roland Resel、Benedikt Schrode 等 10 位作者2019-11-27Biomacromolecules

Biopolymer cellulose is investigated in terms of the crystallographic order within thin films. The films were prepared by spin-coating of a trimethylsilyl cellulose precursor followed by an exposure to HCl vapors; two different source materials were used. Careful precharacterization of the films was performed by infra…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Ultrasensitive Electrochemical Immunosensor Reveals the Existence of Silk Products on the Maritime Silk Road

Jin Li、Hailing Zheng、Yujie He 等 11 位作者2019-11-27ACS Sensors

The Maritime Silk Road was the major trade route between eastern and western civilizations in the Middle Ages. However, hardly any silk products have been found along the transoceanic trade route. Thus, the extrasensitive detection of silk relic traces has tremendous importance in research regarding the Maritime Silk…

Aquaculture disease management and microbiotaSilk-based biomaterials and applicationsIdentification and Quantification in Food

Controlling the spin-selective absorption with two-dimensional chiral plasmonic gratings

Wenxing Liu、Liren Mei、Yunhui Li 等 7 位作者2019-11-27Optics Letters

Spin-selective absorption in a two-dimensional (2D) chiral plasmonic grating is observed by excitation of chiral-dependent plasmonic cavity resonance. For the proposed structures, the incident right-handed circularly polarized light is absorbed with nearly 100% efficiency, whereas the incident left-handed circularly p…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchOrbital Angular Momentum in Optics

Nanosized silver, but not titanium dioxide or zinc oxide, enhances oxidative stress and inflammatory response by inducing 5-HETE activation in THP-1 cells

Wing-Lam Poon、Jetty Chung‐Yung Lee、Kin Sum Leung 等 6 位作者2019-11-27Nanotoxicology

Bioactive, oxygenated metabolites of polyunsaturated fatty acids (PUFAs) are important indicators of inflammation and oxidative stress but almost nothing is known about their interactions with nanomaterials (NMs). To investigate the effects of nano-sized materials (n-TiO2, n-ZnO, n-Ag) and their bulk-sized or ionic (b…

Nanoparticles: synthesis and applicationsHeavy Metal Exposure and ToxicityTrace Elements in Health

ZnO Nanowire Field Effect Transistor for Biosensing: A Review

Nonofo M.J. Ditshego2019-11-27Journal of nano research

The last 19 years have seen intense research made on zinc oxide (ZnO) material mainly due to the ability of converting the natural n-type material into p-type. For a long time, the p-type state was impossible to attain and maintain. The review focuses on ways of improving the doped ZnO material which acts as a channel…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsNanowire Synthesis and Applications

Two π‐Electrons Make the Difference: From BODIPY to BODIIM Switchable Fluorescent Dyes

Hadi Dolati、Lisa C. Haufe、Lars Denker 等 7 位作者2019-11-27Chemistry - A European Journal

Abstract (aza‐)BODIPY dyes (boron dipyrromethene dyes) are well‐established fluorophores due to their large quantum yields, stability, and diversity, which led to promising applications including imaging techniques, sensors, organic (opto)electronic materials, or biomedical applications. Although the control of the op…

Molecular Sensors and Ion DetectionNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

Keto-salicylaldehyde azine: asymmetric substituent effect on their optical properties via electron-donating group insertion

Jialin Tong、Kexin Zhang、Jing Wang 等 8 位作者2019-11-27Journal of Materials Chemistry C

Asymmetric substitution effect at K-terminal or S-terminal in KSA-based derivatives plays a key role in their AIE performance and metal ion responsiveness <italic>via</italic> simple intrinsic electronic structure tunings.

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Spray‐dry synthesis of β ‐Cu 1.8 Zn 0.2 V 2 O 7 ceramic fine particles showing giant negative thermal expansion

K. Takenaka、M. Sato、Masaya Mitamura 等 6 位作者2019-11-27Journal of the American Ceramic Society

Abstract We used spray‐dry method to synthesize fine powder of β ‐Cu 1.8 Zn 0.2 V 2 O 7 showing large negative thermal expansion (NTE) linearly to temperature over a wide temperature range. The NTE of β ‐Cu 1.8 Zn 0.2 V 2 O 7 is produced by microstructures consisting of voids and anisotropic thermal deformation of cry…

Layered Double Hydroxides Synthesis and ApplicationsMicrowave Dielectric Ceramics SynthesisThermal Expansion and Ionic Conductivity

New Insight on the Study of the Kinetic of Biobased Polyurethanes Synthesis Based on Oleo-Chemistry

Julien Peyrton、Clémence Chambaretaud、Luc Avérous2019-11-27Molecules

Nowadays, polyols are basic chemicals for the synthesis of a large range of polymers, such as polyurethane foams (PUF), which are produced with several other compounds, such as polyisocyanates. During the last decades, the oleo-chemistry has developed several routes from glycerides to polyols for the polyurethanes (PU…

Polymer composites and self-healingSynthetic Organic Chemistry MethodsCarbon dioxide utilization in catalysis

Materials synthesis, neutron powder diffraction, and first-principles calculations of (MoxSc1−x)2AlC i−MAX phase used as parent material for MXene derivation

Aurelija Mockutė、Quanzheng Tao、Martin Dahlqvist 等 8 位作者2019-11-27Physical Review Materials

Research on low-dimensional materials has increased drastically in the last decade, with the discovery of two-dimensional transition metal carbides and nitrides (MXenes) produced by atom-selective chemical etching of laminated parent ${M}_{n+1}A{X}_{n}$ (MAX) phases. Here, we apply density functional theory and subseq…

2D Materials and ApplicationsAluminum Alloys Composites PropertiesMXene and MAX Phase Materials

A Multifunctional Lipid Incorporating Active Targeting and Dual-Control Release Capabilities for Precision Drug Delivery

Chenyu Liu、Kai K. Ewert、Weihe Yao 等 7 位作者2019-11-27ACS Applied Materials & Interfaces

-nitro-benzyl ester lipid. As designed, the liposomes formed by Fa-ONB combine active targeting and dual trigger release capabilities, which help to improve drug efficacy and reduce the toxicity of traditional liposomes. We first verified that both pH-induced hydrolysis and light treatment were able to cleave the Fa-O…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryNanoplatforms for cancer theranostics

Johari-Goldstein relaxation in glass electrets

P. Lunkenheimer、F. Humann、D. Reuter 等 6 位作者2019-11-27Physical Review Materials

We investigate the dielectric response in the glass-electret state of two dipolar glass-forming materials. This unusual polar glassy state of matter is produced when a dipolar liquid is supercooled under the influence of a high electric dc field, which leads to partial orientational order of the molecules carrying a d…

Material Dynamics and PropertiesGlass properties and applicationsChemical and Physical Properties of Materials

Electron Mobility in Molybdenum Disulfide: From Bulk to Monolayer

K. L. Kovalenko、S. I. Kozlovskiy、N. N. Sharan2019-11-27physica status solidi (b)

Herein, the low‐field mobility in bulk, multilayer, and monolayer of molybdenum disulfide (MoS 2 ) is calculated using a quantum kinetic approach. Analytical expressions are obtained for mobility of 3D and 2D electrons for scattering by out‐of‐plane flexural and in‐plane acoustic phonons (deformation potential and pie…

Graphene research and applications2D Materials and ApplicationsQuantum and electron transport phenomena

Application of dissolvable Mg/Al layered double hydroxides as an adsorbent for the dispersive solid phase extraction of gold nanoparticles prior to their determination by atomic absorption spectrometry

Tatiana G. Choleva、Dimosthenis L. Giokas2019-11-27Analytical Methods

In this work, dissolvable layered double hydroxides (LDHs) were used for the first time for the extraction and preconcentration of metallic nanoparticles from water samples.

Catalytic Processes in Materials ScienceLayered Double Hydroxides Synthesis and ApplicationsNanomaterials for catalytic reactions

Decorated Tetrathiafulvalene‐Based Ligands: Powerful Chemical Tools for the Design of Single‐Molecule Magnets

Olivier Cador、Boris Le Guennic、Lahcène Ouahab 等 4 位作者2019-11-27European Journal of Inorganic Chemistry

This Minireview covers the design and characterization of coordination lanthanide complexes involving TTF‐based ligands. The specific design of TTF‐based ligands allowed the isolation of complexes with magnetic properties such as Single‐Molecule Magnets (SMMs) behavior and the studies of magnetic modulations due to su…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research

Optoelectronic Properties of Fluorine and Cobalt Co-Doped Tin Oxide Thin Films Deposited by Chemical Spray Pyrolysis

Naoual Houaidji、Mejda Ajili、Baghdadi Chouial 等 10 位作者2019-11-27Journal of nano research

Transparent conducting Cobalt-fluorine co-doped tin oxide (SnO 2 : (Co, F)) thin filmswere deposited onto preheated glass substrates using the chemical spray pyrolysis method. The ([Co 2+ ]/[Sn 4+ ]) atomic concentration ratio (y)in the spray solution was varied between 0 and 5 at. %. The structural, electrical, optic…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Cucurbit[8]uril-Derived Graphene Hydrogels

Vijay Kumar Rana、Anthony Tabet、Julian A. Vigil 等 10 位作者2019-11-27ACS Macro Letters

The scalable production of uniformly distributed graphene (GR)-based composite materials remains a sizable challenge. While GR-polymer nanocomposites can be manufactured at a large scale, processing limitations result in poor control over the homogeneity of hydrophobic GR sheets in the matrices. Such processes often r…

Graphene research and applicationsSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Triggered Drug Release From Hybrid Thermoresponsive Nanoparticles Using Near Infrared Light

Isabel Ortiz de Solorzano、Martín Prieto、Gracia Mendoza 等 5 位作者2019-11-27Nanomedicine

Aim: Developing hybrid poly(N-isopropylacrylamide)-based nanogels decorated with plasmonic hollow gold nanoparticles for on-demand drug delivery and their physico-chemical characterization, bupivacaine loading and release ability upon light irradiation, and in vitro cell viability. Materials & methods: Hollow gold nan…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsNanoplatforms for cancer theranostics