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Band Alignment at Heteroepitaxial Perovskite Oxide Interfaces. Experiments, Methods, and Perspectives

Alessio Giampietri、Giovanni Drera、L. Sangaletti2017-05-10Advanced Materials Interfaces

Recent advances in the growth of epitaxial oxide thin films have fostered a steady increase of research on perovskite oxide heterojunctions, which are now produced with unprecedented quality. Applications of these ultra‐thin interfaces in the field of electronics, photon harvesting, photovoltaics and photocatalysis st…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Enhanced Photoluminescence of Monolayer WS2 on Ag Films and Nanowire–WS2–Film Composites

Fei Cheng、Alex D. Johnson、Yutsung Tsai 等 7 位作者2017-05-10ACS Photonics

Monolayer transition metal dichalcogenides (TMDCs), due to their structural similarity to graphene, emerge as a promising alternative material of integrated optoelectronic devices. Recently, intense research efforts have been devoted to the combination of atomically thin TMDCs with metallic nanostructures to enhance t…

Perovskite Materials and Applications2D Materials and ApplicationsPlasmonic and Surface Plasmon Research

Plasmon-Induced Nanolocalized Reduction of Diazonium Salts

Van‐Quynh Nguyen、Yong Ai、Pascal Martin 等 4 位作者2017-05-10ACS Omega

Surface grafting from diazonium solutions triggered by localized surface plasmon has been investigated. An organic layer that is 20-30 nm thick is easily grafted onto gold nanoparticles (AuNPs) by visible-light illumination in a few minutes without any reducing agent or molecular photocatalyst. Grafting depends on the…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesMolecular Junctions and Nanostructures

Stabilization of Foam Lamella Using Novel Surface-Grafted Nanocellulose-Based Nanofluids

Bing Wei、Li Hao、Qinzhi Li 等 8 位作者2017-05-10Langmuir

To solve the potential risk of present oilfield chemistries to subterranean environment, our group contributes to the development of "green" petroleum production processes. This proof-of-concept research studied the well-defined nanocellulose-based nanofluids, i.e., original (NC), AMPS grafted (NC-KY), and AMPS and hy…

Advanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical ApplicationsPickering emulsions and particle stabilization

Hybrid supercapacitors for reversible control of magnetism

Alan Molinari、Philipp M. Leufke、Christian Reitz 等 7 位作者2017-05-10Nature Communications

Abstract Electric field tuning of magnetism is one of the most intensely pursued research topics of recent times aiming at the development of new-generation low-power spintronics and microelectronics. However, a reversible magnetoelectric effect with an on/off ratio suitable for easy and precise device operation is ye…

Supercapacitor Materials and FabricationMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Water‐Soluble Polymers with Strong Photoluminescence through an Eco‐Friendly and Low‐Cost Route

Zhaoyan Guo、Yue Ru、Wenbo Song 等 6 位作者2017-05-10Macromolecular Rapid Communications

Photoluminescence (PL) of nonconjugated polymers brings a favorable opportunity for low-cost and nontoxic luminescent materials, while most of them still exhibit relatively weak emission. Strong PL from poly[(maleic anhydride)-alt-(vinyl acetate)] (PMV) from low-cost monomer has been found in organic solvents, yet the…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsCarbon and Quantum Dots Applications

Biocatalytic Self‐Assembly Cascades

Jugal Kishore Sahoo、Charalampos G. Pappas、Ivan R. Sasselli 等 5 位作者2017-05-10Angewandte Chemie International Edition

The properties of supramolecular materials are dictated by both kinetic and thermodynamic aspects, providing opportunities to dynamically regulate morphology and function. Herein, we demonstrate time-dependent regulation of supramolecular self-assembly by connected, kinetically competing enzymatic reactions. Starting…

Supramolecular Chemistry and ComplexesSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Filtration and Electrochemical Disinfection Performance of PAN/PANI/AgNWs-CC Composite Nanofiber Membrane

Junjie Wen、Xiaojun Tan、Yongyou Hu 等 5 位作者2017-05-10Environmental Science & Technology

The removal and inactivation of waterborne pathogens from drinking water are important for human health. Here, a polyacrylonitrile/polyaniline/silver nanowires-carbon fiber cloth (PAN/PANI/AgNWs-CC) composite nanofiber membrane was fabricated using a simple and rapid coelectrospinning process, and an electrical device…

Membrane Separation TechnologiesConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Synthesis of n-type Mg2Si/CNT Thermoelectric Nanofibers

Keiko Kikuchi、Kodai YAMAMOTO、Naoyuki Nomura 等 4 位作者2017-05-10Nanoscale Research Letters

Magnesium silicide (Mg 2 Si)/carbon nanotube (CNT) thermoelectric nanofibers for use as a flexible thermoelectric material were successfully synthesized through the combined processes of the sol-gel method, magnesiothermic reduction, and liquid-solid phase reaction. In the resulting product, each CNT was coated with M…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Expansion and Ionic Conductivity

Poly(amino acid)‐Based Gel Fibers with pH Responsivity by Coaxial Reactive Electrospinning

Kristóf Molnár、Angéla Jedlovszky‐Hajdú、Miklós Zrı́nyi 等 5 位作者2017-05-10Macromolecular Rapid Communications

Electrospinning is a well-known technique for the preparation of scaffolds for biomedical applications. In this work, a continuous electrospinning method for gel fiber preparation is presented without a spinning window. As proof of concept, the preparation of poly(aspartic acid)-based hydrogel fibers and their propert…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

A Bistable Microelectromechanical System Actuated by Spin‐Crossover Molecules

Maria Dolores Manrique-Juarez、Fabrice Mathieu、Victoria Shalabaeva 等 10 位作者2017-05-10Angewandte Chemie International Edition

Abstract We report on a bistable MEMS device actuated by spin‐crossover molecules. The device consists of a freestanding silicon microcantilever with an integrated piezoresistive detection system, which was coated with a 140 nm thick film of the [Fe(HB(tz) 3 ) 2 ] (tz=1,2,4‐triazol‐1‐yl) molecular spin‐crossover compl…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMolecular Junctions and Nanostructures

Large polarization gradients and temperature-stable responses in compositionally-graded ferroelectrics

Anoop R. Damodaran、Shishir Pandya、Yubo Qi 等 16 位作者2017-05-10Nature Communications

Abstract A range of modern applications require large and tunable dielectric, piezoelectric or pyroelectric response of ferroelectrics. Such effects are intimately connected to the nature of polarization and how it responds to externally applied stimuli. Ferroelectric susceptibilities are, in general, strongly tempera…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Poly(Ionic Liquid)‐Derived Carbon with Site‐Specific N‐Doping and Biphasic Heterojunction for Enhanced CO2 Capture and Sensing

Jiang Gong、Markus Antonietti、Jiayin Yuan2017-05-10Angewandte Chemie

Abstract CO 2 capture is a pressing global environmental issue that drives scientists to develop creative strategies for tackling this challenge. The concept in this contribution is to produce site‐specific nitrogen doping in microporous carbon fibers. Following this approach a carbon/carbon heterojunction is created…

Ionic liquids properties and applicationsCO2 Reduction Techniques and CatalystsCovalent Organic Framework Applications

Thermodynamics and Mechanisms of the Interactions between Ultrasmall Fluorescent Gold Nanoclusters and Human Serum Albumin, γ-Globulins, and Transferrin: A Spectroscopic Approach

Miao-Miao Yin、Ping Dong、Wenqi Chen 等 7 位作者2017-05-10Langmuir

Noble metal nanoclusters (NCs) show great promise as nanoprobes for bioanalysis and cellular imaging in biological applications due to ultrasmall size, good photophysical properties, and excellent biocompatibility. In order to achieve a comprehensive understanding of possible biological implications, a series of spect…

Gold and Silver Nanoparticles Synthesis and ApplicationsProtein Interaction Studies and Fluorescence AnalysisNanocluster Synthesis and Applications

Tuning of Interlayer Coupling in Large-Area Graphene/WSe 2 van der Waals Heterostructure via Ion Irradiation: Optical Evidences and Photonic Applications

Yang Tan、Xiaobiao Liu、Zhiliang He 等 7 位作者2017-05-10ACS Photonics

van der Waals (vdW) heterostructures are receiving great attentions due to their intriguing properties and potentials in many research fields. The flow of charge carriers in vdW heterostructures can be efficiently rectified by the interlayer coupling between neighboring layers, offering a rich collection of functional…

Graphene research and applications2D Materials and ApplicationsNanowire Synthesis and Applications

Pseudohalide‐Exchanged Quantum Dot Solids Achieve Record Quantum Efficiency in Infrared Photovoltaics

Bin Sun、Oleksandr Voznyy、Hairen Tan 等 16 位作者2017-05-10Advanced Materials

Application of pseudohalogens in colloidal quantum dot (CQD) solar-cell active layers increases the solar-cell performance by reducing the trap densities and implementing thick CQD films. Pseudohalogens are polyatomic analogs of halogens, whose chemistry allows them to substitute halogen atoms by strong chemical inter…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsAdvanced Semiconductor Detectors and Materials

Long-Range Lattice Engineering of MoTe2 by a 2D Electride

Sera Kim、Sera Kim、Seunghyun Song 等 14 位作者2017-05-10Nano Letters

Doping two-dimensional (2D) semiconductors beyond their degenerate levels provides the opportunity to investigate extreme carrier density-driven superconductivity and phase transition in 2D systems. Chemical functionalization and the ionic gating have achieved the high doping density, but their effective ranges have b…

Advanced Photocatalysis Techniques2D Materials and ApplicationsMXene and MAX Phase Materials

Conjugated Polyelectrolytes as Water Processable Precursors to Aqueous Compatible Redox Active Polymers for Diverse Applications: Electrochromism, Charge Storage, and Biocompatible Organic Electronics

James F. Ponder、Anna M. Österholm、John R. Reynolds2017-05-10Chemistry of Materials

An organic soluble precursor polymer was prepared by direct (hetero)arylation polymerization of 3,4-ethylenedioxythiophene (EDOT) with a solubilizing, 3,4-propylenedioxythiophene (ProDOT) derivative bearing ester-functionalized side chains. Chemical defunctionalization of the polymer, using base to hydrolyze the ester…

Conducting polymers and applicationsPolyoxometalates: Synthesis and ApplicationsPolydiacetylene-based materials and applications

Cellulose Nanocrystals/Polyacrylamide Composites of High Sensitivity and Cycling Performance To Gauge Humidity

Tao Lu、Hui Pan、Jun Ma 等 8 位作者2017-05-10ACS Applied Materials & Interfaces

Cellulose nanocrystals (CNCs) have attracted much interest due to their unique optical property, rich resource, environment friendliness, and templating potentials. CNCs have been reported as novel photonic humidity sensors, which are unfortunately limited by the dissolution and unideal moisture absorption of CNCs. We…

Advanced Cellulose Research StudiesPolysaccharides and Plant Cell WallsElectrowetting and Microfluidic Technologies

SERS Detection of Biomolecules by Highly Sensitive and Reproducible Raman-Enhancing Nanoparticle Array

Tzu‐Yi Chan、Ting‐Yu Liu、Kuan-Syun Wang 等 10 位作者2017-05-10Nanoscale Research Letters

This paper describes the preparation of nanoarrays composed of silver nanoparticles (AgNPs: 20-50 nm) for use as surface-enhanced Raman scattering (SERS) substrates. The AgNPs were grown on porous anodic aluminum oxide (AAO) templates by electrochemical plating, and the inter-channel gap of AAO channels is between 10…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesBiosensors and Analytical Detection