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Lability of spin state of Fe(III) complexes with tetradentate Schiff’s bases

Т. А. Иванова、Л. В. Мингалиева、I. V. Ovchinnikov 等 6 位作者2016-07-01Russian Journal of General Chemistry

[FeLX 2 ]Y [L = N,N '-ethylenebis(salicylimine) (salen), N,N '-ethylenebis(acetylacetonylimine) (acen), or N,N '-ethylenebis(3-methyloxysalicylimine) (vanen); X = imidazole or N -methylimidazole; Y = BF 4 , ClO 4 , or BPh 4 ] compounds have been prepared and studied by means of EPR and magnetic susceptibility measurem…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Corrosion Properties of AISI 4140 Industrial Steels Coated with Aniline in Different Storage Conditions

İsmail Hakkı Karahan2016-07-01Acta Physica Polonica A

Polyaniline (PANI) was successfully deposited by means of cyclic voltammetry technique from 0.10 M aniline containing 0.30 M oxalic acid and 1 g/l H3BO3 solution on AISI 4140 steel electrode. In this investigation nominate scan rates 25, 50, 75, and 100 mV/s have been examined. PANI film was characterized using optica…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Field emission microscopy study of freestanding carbon nanotube array

Yonghai Sun、Yunhan Li、John T. W. Yeow2016-07-01OpenAlex

In carbon nanotube (CNT) arrays, unequal current contribution from each emitter to the overall emission current would lead to non-uniform field emission (FE) performance and emitter failure. Therefore, we propose a novel field emission microscopy (FEM) method that allows us to visualize and record the FE performance o…

Carbon Nanotubes in CompositesGraphene research and applicationsMechanical and Optical Resonators

Preparation of TiB<sub>2</sub> Ultrafine Powders by Carbothermal Reduction

Jin Cheng Yu、Li Ma、Yujun Zhang 等 5 位作者2016-07-01Key engineering materials

TiO 2 , B 2 O 3 , H 3 BO 3 , B 4 C and carbon black were used as the raw materials to prepare TiB 2 powders by carbothermal reduction method. The influence of different content of carbon black (13.6~14.8 wt%) on products was discussed. The effects of different boron sources and holding time (10~50 min) on the microstr…

Advanced ceramic materials synthesisBoron and Carbon Nanomaterials ResearchAdvanced materials and composites

The influence of the surface structure of polyaniline films on the adsorption of influenza A viruses and antibodies to them

А. А. Исакова、A. V. Indenbom、O. D. Yakobson 等 7 位作者2016-07-01Protection of Metals and Physical Chemistry of Surfaces

Adsorption of influenza A viruses and their antibodies on golden surfaces, thin films of polyaniline and polyaniline complex with polysulfonic acids, has been studied. The composition of interpolymer complexes was found to influence both the surface relief of synthesized films and the adsorption efficiency. Moreover,…

Conducting polymers and applicationsRNA Interference and Gene DeliveryAnalytical Chemistry and Sensors

Sigma phase detection in duplex stainless steel by induced magnetic field

Eric Mariano Da Silva、Walter Fialho、H F B M Silva 等 6 位作者2016-07-01Journal of Physics Conference Series

Duplex stainless steels when subjected to temperatures above 600 ° C have its tenacity decreased by the formation of sigma phase. This phase has high hardness and is rich in chromium and reduces the matrix of this element. In this study, field line density measurements, obtained in the reversibility region of magnetic…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing Techniques

Electronic structure of UO2.12 calculated in the coherent potential approximation taking into account strong electron correlations and spin-orbit coupling

M. A. Korotin、Z. V. Pchelkina、N. A. Skorikov 等 5 位作者2016-07-01The Physics of Metals and Metallography

Based on the coherent potential approximation, the method of calculating the electronic structure of nonstoichiometric and hyperstoichiometric compounds with strong electron correlations and spin-orbit coupling has been developed. This method can be used to study both substitutional and interstitial impurities, which…

Nuclear reactor physics and engineeringRadioactive element chemistry and processingNuclear Materials and Properties

Embrittlement and conditions of the optimization of magnetic properties in the amorphous alloy Co69Fe3.7Cr3.8Si12.5B11 in the absence of a viscous–brittle transition

I. B. Kekalo、P. S. Mogil’nikov2016-07-01The Physics of Metals and Metallography

The influence of the holding time upon annealing on the temperature of the viscous–brittle transition (temperature of embrittlement) T f in a cobalt-based amorphous alloy of the composition Co69Fe3.7Cr3.8Si12.5B11 with a very low saturation magnetostriction λs (<10–7) has been studied. It has been established that the…

Microstructure and Mechanical Properties of SteelsMetallic Glasses and Amorphous AlloysMagnetic Properties and Applications

Atomic Layers: Tellurium‐Assisted Epitaxial Growth of Large‐Area, Highly Crystalline ReS2 Atomic Layers on Mica Substrate (Adv. Mater. 25/2016)

Fangfang Cui、Cong Wang、Xiaobo Li 等 14 位作者2016-07-01Advanced Materials

H. Xu, J. Zhang, and co-workers synthesize anisotropic 2D-layered rhenium disulfide with high crystal quality and uniform monolayer thickness. As described on page 5019, tellurium-assisted epitaxial growth on a mica substrate is chosen to generate such structures.

2D Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Geometrical modeling of a metallic mesh deformation of the parabolic reflector

Mikhail Stepanovych BUKHTYAK2016-07-01Mathematical Models and Computer Simulations

A geometrical model of the well-known “mattress” effect, which is similar to the one observed at the opening of an umbrella, is built. The main hypothesis is that the surface of metallic mesh of a parabolic reflector takes a form closed to the minimal surface in the isotropic case. The fact that, for the orthotropic m…

Material Properties and Applications

Preparation of Amorphous SiOC Ceramic Powders through Precursor Polymer Pyrolysis

Bo Ming、Hong Jie Wang、Jiang Bo Wen 等 6 位作者2016-07-01Key engineering materials

SiOC ceramic as anode material for lithium ion batteries has received extensive attention recently. In this work, polycarbosilane and polymethylhydrosiloxane were used as precursor polymers through a curing, pyrolysis and ball-milling progress to synthesize three kinds of ceramic powders with different components note…

Advancements in Battery MaterialsAdvanced ceramic materials synthesisCatalytic Processes in Materials Science

Water absorption behaviour in polyethylene boron nitride nanocomposites

Raed Ayoob、Thomas Andritsch、A. S. Vaughan2016-07-01OpenAlex

Polymer nanocomposites, when prepared and treated carefully, have the potential to offer many advantages over the current materials used in high voltage applications. Four materials have been prepared containing 2 wt%, 5 wt%, and 10 wt% of hexagonal boron nitride nanofiller, including an unfilled material based on a p…

High voltage insulation and dielectric phenomenaDielectric materials and actuatorsPolymer Nanocomposite Synthesis and Irradiation

Synthesis of Mesoporous Ceria by Using CTAB as Template

S. E. Borjas-García、A. Medina-Flores、L. Béjar 等 6 位作者2016-07-01Microscopy and Microanalysis

S E Borjas-García, A Medina-Flores, L Béjar, P Martínez-Torres, N Dasgupta-Schubert, J L Bernal; Synthesis of Mesoporous Ceria by Using CTAB as Template, M

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceMesoporous Materials and Catalysis

A new approach for optimal design of corona ring

Rafael Mendonça Rocha Barros、Edson Guedes da Costa、Tarso Vilela Ferreira 等 5 位作者2016-07-01OpenAlex

In this research several optimization methods were used to determine the optimal design for a corona ring. The following methods were utilized: Nelder-Mead, COBYLA and BOBYQA. In addition, a software based on the Finite Element Method was used to perform electric field simulations. Results show that the optimized coro…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationAerosol Filtration and Electrostatic Precipitation

Evolution of partial discharge of oil-paper insulation under long-term AC voltage

Ping Peng、Yanjie Cui、Shengchang Ji 等 6 位作者2016-07-01OpenAlex

Internal insulation defects of oil-immersed transformers are common because of flaws in both manufacturing and transportation process. Partial discharge (PD) activity caused by insulation defects may occur at rated voltage condition, leading to deterioration of material, which results in breakdown of insulation. Featu…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

Optical and photovoltaic properties of ZnS nanocrystals fabricated on Al:ZnO films using the SILAR technique

Masood Mehrabian2016-07-01Journal of Optical Technology

Hybrid solar cells with ITO/AZO/ZnS/P3HT/PCBM/Ag structure were fabricated so that, in the synthesis of the ZnS layer, the successive ion layer absorption and reaction (SILAR) technique was used. At first, Al-doped ZnO (AZO) layers with different molar concentrations of Al were deposited on ITO-glass substrates, and t…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Remote Plasma Cleaning and Radical Recombination Rates

Ronald Vane、Ewa Kosmowska2016-07-01Microscopy and Microanalysis

Ronald Vane, Ewa Kosmowska; Remote Plasma Cleaning and Radical Recombination Rates, Microscopy and Microanalysis, Volume 22, Issue S3, 1 July 2016, Pages 4

Catalytic Processes in Materials Science

Synthesis, characterization and hall effect studies of polystyrene/polyindole composites

Serpil Eşsiz、Bekir Sarı2016-07-01Russian Journal of Physical Chemistry B

In this study, polyindole (PIN) and polystyrene/polyindole (PS/PIN) composites were synthesized by chemical polymerization using FeCl3 as an oxidant agent. The conductivities of PIN and the composites were measured with a four-probe technique. The conductivity of PIN was determined as 5.1 × 10 –3 S cm –1 , whereas the…

Polymer Nanocomposites and PropertiesConducting polymers and applicationsSynthesis and properties of polymers