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Nanoparticle size and combined toxicity of TiO2 and DSLS (surfactant) contribute to lysosomal responses in digestive cells of mussels exposed to TiO2 nanoparticles

Alba Jimeno-Romero、Miriam Oron、Miren P. Cajaraville 等 5 位作者2016-05-31Nanotoxicology

The aim of this investigation was to understand the bioaccumulation, cell and tissue distribution and biological effects of disodium laureth sulfosuccinate (DSLS)-stabilised TiO2 nanoparticles (NPs) in marine mussels, Mytilus galloprovincialis. Mussels were exposed in vivo to 0.1, 1 and 10 mg Ti/L either as TiO2 NPs (…

Nanoparticles: synthesis and applicationsEnvironmental Toxicology and EcotoxicologyGeochemistry and Elemental Analysis

Absolute Intramolecular Distance Measurements with Angstrom-Resolution Using Anomalous Small-Angle X-ray Scattering

Thomas Zettl、Rebecca S. Mathew、Sönke Seifert 等 6 位作者2016-05-31Nano Letters

Accurate determination of molecular distances is fundamental to understanding the structure, dynamics, and conformational ensembles of biological macromolecules. Here we present a method to determine the full distance distribution between small (∼7 Å radius) gold labels attached to macromolecules with very high-precis…

DNA and Nucleic Acid ChemistryX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

The Enhancement on Proton Conductivity of Stable Polyoxometalate‐Based Coordination Polymers by the Synergistic Effect of MultiProton Units

Jing Li、Xue‐Li Cao、Yuan Yuan Wang 等 9 位作者2016-05-31Chemistry - A European Journal

Two novel polyoxometalate (POM)-based coordination polymers, namely, [Co(bpz)(Hbpz)][Co(SO4 )0.5 (H2 O)2 (bpz)]4 [PMo(VI) 8 Mo(V) 4 V(IV) 4 O42 ]⋅13 H2 O (NENU-530) and [Ni2 (bpz)(Hbpz)3 (H2 O)2 ][PMo(VI) 8 Mo(V) 4 V(IV) 4 O44 ]⋅8 H2 O (NENU-531) (H2 bpz=3,3',5,5'-tetramethyl-4,4'-bipyrazole), were isolated by hydroth…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Biocompatible polyhydroxyalkanoates/bacterial cellulose composites: Preparation, characterization, and in vitro evaluation

Ioana Chiulan、Denis Mihaela Panaitescu、Adriana Nicoleta Frone 等 8 位作者2016-05-31Journal of Biomedical Materials Research Part A

Biocompatible composites play a critical role as scaffolds in tissue engineering. Novel biocomposites made from poly(3-hydroxybutyrate) (PHB), polyhydroxyalkanoate (PHA) and bacterial cellulose (BC) in different concentrations were prepared by solution casting and their thermal and mechanical behavior as well as bioco…

Advanced Cellulose Research Studiesbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Increasing the production of (R)-3-hydroxybutyrate in recombinant Escherichia coli by improved cofactor supply

Mariel Pérez-Zabaleta、Gustav Sjöberg、Mónica Guevara-Martínez 等 7 位作者2016-05-31Microbial Cell Factories

BACKGROUND: In a recently discovered microorganism, Halomonas boliviensis, polyhydroxybutyrate production was extensive and in contrast to other PHB producers, contained a set of alleles for the enzymes of this pathway. Also the monomer, (R)-3-hydroxybutyrate (3HB), possesses features that are interesting for commerci…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesMicrobial Metabolic Engineering and Bioproduction

Sirtuin-dependent reversible lysine acetylation of glutamine synthetases reveals an autofeedback loop in nitrogen metabolism

Di You、Bin‐Cheng Yin、Zhi-Hai Li 等 7 位作者2016-05-31Proceedings of the National Academy of Sciences

In cells of all domains of life, reversible lysine acetylation modulates the function of proteins involved in central cellular processes such as metabolism. In this study, we demonstrate that the nitrogen regulator GlnR of the actinomycete Saccharopolyspora erythraea directly regulates transcription of the acuA gene (…

Fungal and yeast genetics researchEnzyme Structure and FunctionPolyamine Metabolism and Applications

Toward High-Performance Poly(l-lactide) Fibers via Tailoring Crystallization with the Aid of Fibrillar Nucleating Agent

Huixian Zhang、Hongwei Bai、Zhenwei Liu 等 5 位作者2016-05-31ACS Sustainable Chemistry & Engineering

As a sustainable alternative to conventional petrochemical-based polymers, biobased and biodegradable poly( l -lactide) (PLLA) exhibits tremendous application potential in the textile industry due to its attractive elastic recovery, moisture regain, and flammability. However, the commercial adoption of PLLA textile fi…

Advanced Sensor and Energy Harvesting Materialsbiodegradable polymer synthesis and propertiesAdditive Manufacturing and 3D Printing Technologies

Prolonging the plasma circulation of proteins by nano-encapsulation with phosphorylcholine-based polymer

Linlin Zhang、Yang Liu、Gan Liu 等 8 位作者2016-05-31Nano Research

Short in vivo circulation is a major hindrance to the widespread adoption of protein therapeutics. Protein nanocapsules generated by encapsulating proteins with a thin layer of phosphorylcholine-based polymer via a two-step encapsulation process exhibited significantly prolonged plasma half-life. Furthermore, by const…

Polymer Surface Interaction StudiesProtein purification and stabilityMicrofluidic and Bio-sensing Technologies

Fractal dimensions of wave functions and local spectral measures on the Fibonacci chain

Nicolas Macé、Anuradha Jagannathan、Frédéric Piéchon2016-05-31Physical review. B./Physical review. B

We present a theoretical framework for understanding the wave functions and spectrum of an extensively studied paradigm for quasiperiodic systems, namely the Fibonacci chain. Our analytical results, which are obtained in the limit of strong modulation of the hopping amplitudes, are in good agreement with published num…

Theoretical and Computational PhysicsGraph theory and applicationsQuasicrystal Structures and Properties

Structure, Electronic Properties, and Electrochemical Behavior of a Boron-Doped Diamond/Quartz Optically Transparent Electrode

Naihara Wächter、Catherine A. Munson、Romana Jarošová 等 7 位作者2016-05-31ACS Applied Materials & Interfaces

The morphology, microstructure, chemistry, electronic properties, and electrochemical behavior of a boron-doped nanocrystalline diamond (BDD) thin film grown on quartz were evaluated. Diamond optically transparent electrodes (OTEs) are useful for transmission spectroelectrochemical measurements, offering excellent sta…

Diamond and Carbon-based Materials ResearchForce Microscopy Techniques and ApplicationsElectronic and Structural Properties of Oxides

Effect of carbon nanotubes on electromagnetic interference shielding of carbon fiber reinforced polymer composites

Shen Gong、Zheng Zhu、Mohammad Arjmand 等 6 位作者2016-05-31Polymer Composites

This paper investigated the effect of carbon nanotubes (CNTs) on the electromagnetic interference shielding of carbon fiber reinforced polymer (CFRP) composites. The CNT/CFRP composites were fabricated by dry spray deposition of CNT on surfaces of carbon fiber prepregs and then out‐of‐autoclave curing process. The int…

Electromagnetic wave absorption materialsAdvanced Antenna and Metasurface Technologies

Insulating Nature of Strongly Correlated Massless Dirac Fermions in an Organic Crystal

Dong Liu、Kyohei Ishikawa、Ryosuke Takehara 等 6 位作者2016-05-31Physical Review Letters

Through resistivity measurements of an organic crystal hosting massless Dirac fermions with a charge-ordering instability, we reveal the effect of interactions among massless Dirac fermions on the charge transport. A low-temperature resistivity upturn appears robustly irrespective of the pressure and is enhanced while…

Quantum and electron transport phenomenaTopological Materials and PhenomenaOrganic and Molecular Conductors Research

Superlubricity in quasicrystalline twisted bilayer graphene

Elad Koren、Urs Duerig2016-05-31Physical review. B./Physical review. B

The unique atomic positions in quasicrystals lead to peculiar self-similarity and fractal-like structural morphology. Accordingly, many of the material properties are supposed to manifest exceptional characteristics. In this Rapid Communication, we explain through numerical simulations the fundamental and peculiar asp…

Force Microscopy Techniques and ApplicationsQuasicrystal Structures and PropertiesAdvanced Mathematical Theories and Applications

Templating C 60 on MoS 2 Nanosheets for 2D Hybrid van der Waals p – n Nanoheterojunctions

Runfeng Chen、Cheng Lin、Huan Yu 等 10 位作者2016-05-31Chemistry of Materials

C 60 and single-layer MoS 2 nanocomposites were facilely prepared via a combined solvent transfer and surface deposition (STSD) method by templating C 60 aggregates on 2D MoS 2 nanosheets to construct hybrid van der Waals heterojunctions. The electronic property of the hybrid nanomaterials was investigated in a direct…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Hierarchical CuO Colloidosomes and Their Structure Enhanced Photothermal Catalytic Activity

Jie Xu、Xiaoman Li、Xuan Wu 等 7 位作者2016-05-31The Journal of Physical Chemistry C

Hierarchical CuO colloidosomes (hollow spheres) constructed by subunit of open-mouthed hollow spheres that consist of 2D nanoleaves are synthesized via a Pickering emulsion strategy. Cu 2 O particles were served as emulsifier particles to form the Pickering emulsions. Self-oxidation of Cu 2 O gave rise to the formatio…

Gold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applicationsPickering emulsions and particle stabilization

Free Vibration of Edge Cracked Functionally Graded Microscale Beams Based on the Modified Couple Stress Theory

Şeref Doğuşcan Akbaş2016-05-31International Journal of Structural Stability and Dynamics

In this study, the free vibration analysis of edge cracked cantilever microscale beams composed of functionally graded material (FGM) is investigated based on the modified couple stress theory (MCST). The material properties of the beam are assumed to change in the height direction according to the exponential distrib…

Composite Structure Analysis and OptimizationNumerical methods in engineeringNonlocal and gradient elasticity in micro/nano structures

Experimental and analytical behavior of sandwich composite beams: Comparison of natural and synthetic materials

Pedram Sadeghian、Dimo Hristozov、Laura Wroblewski2016-05-31Journal of Sandwich Structures & Materials

In this study, the flexural behavior of sandwich composite beams made of fiber-reinforced polymer (FRP) skins and light-weight cores are studied. The focus is on the comparison of natural and synthetic fiber and core materials. Two types of fiber materials, namely glass and flax fibers, as well as two types of core ma…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesCellular and Composite Structures

In vitro hemocompatibility and cytocompatibility of a three-layered vascular scaffold fabricated by sequential electrospinning of PCL, collagen, and PLLA nanofibers

Shaghayegh Haghjooy Javanmard、Jamal Anari、Anousheh Zargar Kharazi 等 4 位作者2016-05-31Journal of Biomaterials Applications

Aiming to mimic a blood vessel structurally, morphologically, and mechanically, a sequential electrospinning technique using a small diameter mandrel collector was performed and a three-layered tubular scaffold composed of nanofibers of polycaprolactone, collagen, and poly(l-lactic acid) as inner, intermediate, and ou…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Novel Aloe Vera fiber reinforced biodegradable composites—Development and characterization

Saurabh Chaitanya、Inderdeep Singh2016-05-31Journal of Reinforced Plastics and Composites

In the current research enterprise, behavior of novel bio-composites incorporating Aloe Vera fibers in biopolymer matrix (polylactic acid) has been experimentally examined in comparison to Sisal fiber reinforced bio-composites. These bio-composites were melt blended using single screw extruder prior to injection moldi…

Natural Fiber Reinforced CompositesMechanical Engineering and Vibrations Research

Resistivity of Rotated Graphite–Graphene Contacts

Tarun Chari、Rebeca Ribeiro-Palau、Cory R. Dean 等 4 位作者2016-05-31Nano Letters

Robust electrical contact of bulk conductors to two-dimensional (2D) material, such as graphene, is critical to the use of these 2D materials in practical electronic devices. Typical metallic contacts to graphene, whether edge or areal, yield a resistivity of no better than 100 Ω μm but are typically >10 kΩ μm. In thi…

Advancements in Battery MaterialsGraphene research and applicationsQuantum and electron transport phenomena