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Stability of the Frank–Kasper σ-phase in BABC linear tetrablock terpolymers

Meijiao Liu、Weihua Li、Feng Qiu 等 4 位作者2016-01-01Soft Matter

The phase behavior of B1AB2C tetrablock terpolymer melts is systematically studied using the self-consistent field theory, focusing on the emergence and stability of the complex Frank-Kasper σ-phase. Our study starts with an investigation of the stability region of the σ phase for a generic model of B1AB2C terpolymers…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Effective Utilization of the Electrostatic Repulsion for Improved Alignment of Electrospun Nanofibers

Yonghui Wu、Haipeng Li、Xinxin Shi 等 6 位作者2016-01-01Journal of Nanomaterials

Uniaxial alignment of electrospun fibers can provide a useful approach to develop novel functional nanomaterials for applications in a wide variety of fields. In this study, a polypropylene- (PP-) coated spinneret and a metal spinneret were utilized to carry out the single-fluid electrospinning processes. A metal rod…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Theoretical insights into the promotion effect of subsurface boron for the selective hydrogenation of CO to methanol over Pd catalysts

Panpan Wu、Bo Yang2016-01-01Physical Chemistry Chemical Physics

The activity and selectivity of methanol synthesis from syngas have been studied for decades from both experimental and theoretical aspects. In this work, CO hydrogenation to methanol on both Pd(211) and subsurface boron-modified Pd(211) surfaces is investigated based on density functional theory calculations. Methane…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Superparamagnetic Fe 3 O 4 /MWCNTs heterostructures for high frequency microwave absorption

Honglei Yuan、Yanling Xu、Huanxia Jia 等 4 位作者2016-01-01RSC Advances

Superparamagnetic Fe <sub>3</sub> O <sub>4</sub> nanocrystals anchored on multiwalled carbon nanotubes (MWCNTs) were fabricated using co-precipitating technique which nicely integrates the magnetic and dielectric components into a synergistic microwave absorber.

Metamaterials and Metasurfaces ApplicationsElectromagnetic wave absorption materialsAdvanced Antenna and Metasurface Technologies

How can nanomedicines overcome cellular-based anticancer drug resistance?

Dunja Sobot、Simona Mura、Patrick Couvreur2016-01-01Journal of Materials Chemistry B

Despite the great progress in the field of cancer research, complete remission of cancer patients is a rarely seen outcome in clinics. The failure of a plethora of promising anticancer drugs is mostly due to the insurgence of multidrug resistance (MDR) phenomena with various factors, both physio-pathological and cellu…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryNanoplatforms for cancer theranostics

Mechanistic understanding of calcium–phosphonate solid dissolution and scale inhibitor return behavior in oilfield reservoir: formation of middle phase

Ping Zhang、Dong Shen、Gedeng Ruan 等 5 位作者2016-01-01Physical Chemistry Chemical Physics

Phosphonates are an important class of mineral scale inhibitors used for oilfield scale control. By injecting the phosphonate into an oilfield reservoir, calcium-phosphonate precipitate will form and subsequently release the phosphonate into produced water for scale control. In this study, a systematic procedure is de…

Hydraulic Fracturing and Reservoir AnalysisDrilling and Well EngineeringCalcium Carbonate Crystallization and Inhibition

Pyrene appended thymine derivative for selective turn-on fluorescence sensing of uric acid in live cells

Prithidipa Sahoo、Himadri Sekhar Sarkar、Sujoy Das 等 6 位作者2016-01-01RSC Advances

A new ‘turn-ON’ fluorescent probe, pyrene appended thymine acetamide ( <bold>PTA</bold> ), with high sensitivity and selectivity for the detection of uric acid ( <bold>UA</bold> ) was developed and first time imaging of uric acid in living cells in water was achieved.

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Fabrication and multifunctional properties of ultrasmall water-soluble tungsten oxide quantum dots

Hua‐Ping Peng、Pan Liu、Danwei Lin 等 10 位作者2016-01-01Chemical Communications

A facile and green method has been demonstrated to synthesize ultrasmall tungsten oxide quantum dots (WOx QDs). The water-soluble WOx QDs present high luminescence stability, strong peroxidase-like activity, and excellent electrochemiluminescence properties. This work provides an eco-friendly strategy to prepare multi…

Advanced Photocatalysis TechniquesAdvanced Nanomaterials in CatalysisGa2O3 and related materials

Solid state NMR studies of gels derived from low molecular mass gelators

Nonappa Nonappa、Erkki Kolehmainen2016-01-01Soft Matter

Since its invention more than six decades ago, nuclear magnetic resonance (NMR) spectroscopy has evolved as an inevitable part of chemical as well as structural analysis of small molecules, polymers, biomaterials and hybrid materials. In the solution state, due to the increased viscosity of complex viscoelastic fluids…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPhotoreceptor and optogenetics research

A robust bilayer nanofilm fabricated on copper foam for oil–water separation with improved performances

Yabin Wang、Feng Lin、Jiaoyu Peng 等 6 位作者2016-01-01Journal of Materials Chemistry A

In this work, a facile approach of covalent layer-by-layer assembly was applied to fabricate a bilayer nanofilm which renders roughened copper foam superhydrophobic with robust performances.

Surface Modification and SuperhydrophobicityPickering emulsions and particle stabilizationElectrohydrodynamics and Fluid Dynamics

Twist-bend nematic phases of bent-shaped biaxial molecules

Wojciech Tomczyk、Grzegorz Paja̧k、Lech Longa2016-01-01Soft Matter

How can a change in molecular structure affect the relative stability and structural properties of the twist-bend nematic phase (NTB)? Here we extend the mean-field model(1) (C. Greco, G. R. Luckhurst and A. Ferrarini, Soft Matter, 2014, 10, 9318) for bent-shaped achiral molecules, to study the influence of arm molecu…

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsPlant Reproductive Biology

A controllable asymmetrical/symmetrical coating strategy for architectural mesoporous organosilica nanostructures

Xue Wang、Yapeng He、Chong Liu 等 6 位作者2016-01-01Nanoscale

We describe a facile and controllable asymmetrical/symmetrical coating strategy for the preparation of various novel periodic mesoporous organosilica (PMO) nanostructures, including Au&PMO Janus, Au@PMO yolk-shell and Au@PMO/mSiO2 yolk-double shell nanoparticles, by using Au@SiO2 nanoparticles as seeds. During this pr…

Photonic Crystals and ApplicationsMesoporous Materials and CatalysisAerogels and thermal insulation

Blue light emitting self-healable graphene quantum dot embedded hydrogels

Sagar Biswas、Dnyaneshwar B. Rasale、Apurba K. Das2016-01-01RSC Advances

Graphene quantum dot (GQD) embedded Amoc ( <italic>N</italic> -anthracenemethyloxycarbonyl) amino acid based hydrogels show self-healing properties and emit blue light.

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsAdvanced Materials and Mechanics

Plasmon-Exciton Resonant Energy Transfer: Across Scales Hybrid Systems

Mohamed El Kabbash、Alireza R. Rashed、Kandammathe Valiyaveedu Sreekanth 等 6 位作者2016-01-01Journal of Nanomaterials

The presence of an excitonic element in close proximity of a plasmonic nanostructure, under certain conditions, may lead to a nonradiative resonant energy transfer known as Exciton Plasmon Resonant Energy Transfer (EPRET) process. The exciton-plasmon coupling and dynamics have been intensely studied in the last decade…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchSpectroscopy and Quantum Chemical Studies

Exploitation of nanoparticle–protein corona for emerging therapeutic and diagnostic applications

Sara Palchetti、Daniela Pozzi、Morteza Mahmoudi 等 4 位作者2016-01-01Journal of Materials Chemistry B

Exposure of nanoparticles (NPs) to biological fluids (e.g., plasma, interstitial fluid, and cytoplasm) leads to the absorption of proteins on the NP surface, forming a protein corona (PC) that drastically influences the NP physicochemical properties. Herein, we highlight the emerging applications of PC towards its use…

Nanoparticle-Based Drug DeliveryPolymer Surface Interaction StudiesElectrostatics and Colloid Interactions