Materials Literature
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The photocyclization quantum yield of 2,2′-dimethyl-3,3′-(perfluorocyclopentene-1,2-diyl)bis(benzo[b]thiophene-6-sulfonate) is found to increase in aqueous solution after the addition of β- and γ-cyclodextrin, in which a photoreactive antiparallel conformation of diarylethene is favourably included.
LaNiO 3 thin films have been deposited in an atomic layer epitaxy (ALE) reactor, using La(thd) 3 , Ni(thd) 2 and ozone as reactants, thereby proving the feasibility of the ALE technique to produce films of ternary oxides. Depositions were made on Corning glass in the temperature range 150–450 °C. The growth conditions…
Abstract The syntheses, crystal structures, and physical properties of some recently discovered layered ternary and quaternary chalcogenides are reviewed. One component of these systems is an alkali metal or thallium; another is a d‐, f‐, or p‐ block metal.
The electrochemically triggered rearrangement of a copper catenate is monitored by EPR spectroscopy; the initially generated tetrahedral copper(II) complex (with higher g-factor components and lower metal hyperfine splitting) is converted to a stable five-coordinate copper(II) species, within a few minutes at room tem…
Three mixed-valence polyoxovanadates, Na 12 H 2 [V 18 O 44 (N 3 )]·30H 2 O 1, K 8.5 H 2.5 [V 18 O 42 (PO 4 )]·19H 2 O 2 and H 15 [V 12 B 32 O 84 Na 4 ]·13H 2 O 3 have been photochemically synthesized and characterized by X-ray single-crystal analysis and magnetic susceptibility measurements. The [V 18 O 44 (N 3 )] 14-…
Abstract The morphological features of ZnO crystallites influenced by solution basicity under hydrothermal conditions have been studied from the standpoint of the incorporation of the growth units. A crystal chemistry approach is developed to understand and thus to control a desirable morphology of the crystallites. T…
A novel approach for the synthesis of 5,5′-directly linked metal-free bis-porphyrins is reported; McMurry type coup-ling of dipyrroketones (e.g. 1) leads to 1,1,2,2-tetra(2-pyrrolyl)ethene 2, which after tetra-formylation (to give 3) and MacDonald macrocyclization with a 1,9-di-unsubstituted dihydrodipyrrin 4, affords…
Ferroresonance in electromagnetic voltage transformers, fed through circuit breaker grading capacitance, is studied using nonlinear dynamics methods. The magnetising characteristic of a typical 100 VA voltage transformer is represented by a single-valued two-term polynomial of the order seven. The system exhibits thre…
Electronic structure calculations of cubic ${\mathrm{SrTiO}}_{3}$ and ${\mathrm{SrHfO}}_{3}$ are presented. The full-potential linear augmented-plane-wave method is used and exchange-correlation effects are treated by the local-density approximation. The tendency to ferroelectricity of both compounds is explored and c…
The solid superacid-catalyzed depolymerization−liquefaction (DL) reactions of high-density polyethylene (HDPE), isotactic polypropylene (PPR), and cis -polybutadiene (PB) samples were systematically investigated as a function of processing conditions, i.e., temperature (350−450 °C), time (0.5−3.0 h), H 2 pressure (500…
The Diels–Alder reaction of β-sulfonylnitroethylene with cyclopentadiene, cyclohexadiene or substituted anthracenes followed by treatment with ethyl isocyanoacetate in the presence of DBU gives pyrroles fused with bicyclo[2.2.1]heptadiene and bicyclo[2.2.2]octadiene skeletons, or triptycene-types of pyrrole, respectiv…
A new type of three-dimensional open-framework copper chloride, prepared simply by the hydrothermal treatment of CuCl 2 ·H 2 O and en, is built up from unusual chloride bridged Cu 4 tetramers connected by CuCl 3/3 units and has voids in the framework that are filled with charge-compensating [Cu(en) 2 ] 2+ cations.
The biosynthesis of poly( l -alanylglycine) (poly(AG)) was performed in high cell density cultures of recombinant Escherichia coli . The purity of the material was determined by amino acid analysis, elemental analysis, and 1 H NMR spectroscopy. Fed batch fermentation increased the yield of recombinant protein from lev…
Extraordinary channel patterns have been observed in an oriented mesoporous silica film that is synthesized at the boundary between air and water. The basic channel designs comprise concentric circles, herringbones, fingerprints and hairpins. It is suggested that these patterns are spatio-temporal silicified recording…
The new ligand 4′-(4-anilino)-2,2′∶6′,2″-terpyridine (L 1 ) and a range of its transition-metal complexes have been prepared. The crystal and molecular structures of L 1 and [CuL 1 2 ][PF 6 ] 2 have been determined. Model reactions show that L 1 and its transition-metal complexes can be functionalised with suitable or…
An important and growing part of the textile industry consists of the medical and related healthcare and hygiene sectors. The extent of the growth is due to the constant improvements and innovations in both textile technology and medical procedures. The aim of this review is to highlight the specific medical and surgi…
The thermal conductivity of an AlN-and an alumina-particulate-filled epoxy resin was investigated as a function of their volume content ratios. AlN composite exhibited thermal conductivity of 7.15W/m·K at 68.5vol% filler content but that of alumina composite was lower than 2.68W/m·K even if the filler content was as m…
Fire fighters' protective clothing is designed to perform several functions. Of these, protection from heat and flame is one of the most important. Today's fire fighter protective clothing designs are based on years of field experience and research studies which addressed structural fires. Much of this work has concen…
Mesoporous zirconia is synthesized with anionic templates.
The synthesis of nanocrystalline zinc ferrite (ZnFe/sub 2/O/sub 4/) has been accomplished by a variety of chemical and mechanochemical techniques. An enhanced magnetization, 4-5 times that of bulk zinc ferrite, is observed for the nanoparticles regardless of the synthesis method. The hypothesis that the enhanced magne…