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Synthesis and Properties of Linear-Type S-Bridged RhIIINiIIRhIII Trinuclear Complexes with 2-Aminoethanethiolate (aet) or l -Cysteinate ( l -cys). Crystal Structure of [Ni{Rh(aet)3}2](NO3)2

Takumi Konno、Ken‐ichi Okamoto1995-02-01Bulletin of the Chemical Society of Japan

Abstract The reaction of fac(S)-[Rh(aet)3] with Ni2+ at room temperature gave a linear-type S-bridged RhIIINiIIRhIII trinuclear complex, [Ni{Rh(aet)3}2]2+ (1). A similar reaction of ΔLll-fac(S)-[Rh(l-cys-N,S)3]3− with Ni2+ produced the corresponding trinuclear complex with l-cys ligands, ΔLllΔLll-[Ni{Rh(l-cys-N,S)3}2]…

Metal complexes synthesis and propertiesMagnetism in coordination complexesOrganometallic Compounds Synthesis and Characterization

The System Development of Electrically Heated Catalyst (EHC) for the LEV and EU-III Legislation

B. Pfalzgraf、Erhard Otto、Alexandra Wirth 等 6 位作者1995-02-01SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">Future requirements of the legislative body in the USA and Europe, towards the reduction of exhaust emissions of motor vehicles, forces the automobile industry to improve its technology continually. An electrically heated catalyst, abbreviated EHC, offers a very high potential for…

Catalytic Processes in Materials Science

A new anhydrous amphibole from the Hoskins Mine, Grenfell, New South Wales, Australia; description and crystal structure of ungarettiite, NaNa 2 (Mn (super 2+) 2 Mn (super 3+) 3 )Si 8 O 22 O 2

F. C. Hawthorne、Roberta Oberti、E. Cannillo 等 7 位作者1995-02-01American Mineralogist

Other| February 01, 1995 A new anhydrous amphibole from the Hoskins Mine, Grenfell, New South Wales, Australia: Description and crystal structure of ungarettiite, NaNa2(Mn22+Mn33+)Si8O22O2 Frank C. Hawthorne; Frank C. Hawthorne CNR Centro di Studio per la Cristallochimica e la Cristallografia, Pavia, Italy Search for…

Geological and Geochemical AnalysisCrystal Structures and PropertiesAdvanced Condensed Matter Physics

Tautomerism of Neutral and Protonated 6-Thioguanine in the Gas Phase and in Aqueous Solution. An ab Initio Study

Cristóbal Alhambra、F. Javier Luque、Joan Estelrich 等 4 位作者1995-02-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTautomerism of Neutral and Protonated 6-Thioguanine in the Gas Phase and in Aqueous Solution. An ab Initio StudyC. Alhambra, F. J. Luque, J. Estelrich, and Modesto OrozcoCite this: J. Org. Chem. 1995, 60, 4, 969–976Publication Date (Print):February 1, 1995Publication History…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryChemical Reaction Mechanisms

Internal Stresses and the Martensite Start Temperature in Alumina‐Zirconia Composites: Effects of Composition and Microstructure

K.B. Alexander、Paul Becher、Xun‐Li Wang 等 4 位作者1995-02-01Journal of the American Ceramic Society

n alumina‐based composites containing ceria‐stabilized tetragonal zirconia, the martensite start temperature ( M s ) of the tetragonal‐to‐monoclinic zirconia phase transformation exhibits a grain size dependence that becomes increasingly pronounced as the zirconia content decreases. Neutron diffraction experiments con…

Advanced ceramic materials synthesisIntermetallics and Advanced Alloy PropertiesAdvanced materials and composites

Inorganic Overgrowth of Aragonite on Molluscan Nacre Examined by Atomic Force Microscopy

Roscoe Giles、S. Manne、Stephen Mann 等 6 位作者1995-02-01Biological Bulletin

The nacre (mother-of-pearl) that forms the irridescent inner layers of mollusc shells is a highly ordered microlaminate composite of aragonite crystals and biopolymers with a strength and fracture resistance that far exceed those of the mineral crystals themselves. The processes governing the biofabrication of this ma…

Paleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation Techniques

Living Carbocationic Sequential Block Copolymerization of Isobutylene with .alpha.-Methylstyrene

Dawei Li、Rudolf Faust1995-02-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLiving Carbocationic Sequential Block Copolymerization of Isobutylene with .alpha.-MethylstyreneDawei Li and Rudolf FaustCite this: Macromolecules 1995, 28, 5, 1383–1389Publication Date (Print):February 1, 1995Publication History Published online1 May 2002Published inissue 1…

Organometallic Complex Synthesis and CatalysisAdvanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

Anomalous-diffusion model of ionic transport in oxide glasses

David L. Sidebottom、P. F. Green、Richard K. Brow1995-02-01Physical review. B, Condensed matter

The power-law frequency dependence of both the conductivity, \ensuremath{\sigma}(\ensuremath{\omega}), and permittivity, \ensuremath{\varepsilon}(\ensuremath{\omega}), of ion-conducting materials suggests that self-similar or scale-invariant behavior influences the transport of ions at high frequencies. Using an anoma…

Material Dynamics and PropertiesGlass properties and applicationsTheoretical and Computational Physics

Twist Grain Boundary Phases in Binary Mixtures

W. Kuczyński、H. Stegemeyer1995-02-01Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals

Two twist grain boundary phases (TGB-A and TGB-C*) have been observed in binary mixtures exhibiting a NAC multicritical point. The observed TGB phases are of very high thermal stability - for some concentrations the temperature range of their existence was as large as 40 K. Optical properties and textures has been inv…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPhase-change materials and chalcogenides

Low-Temperature Reactions of Atomic Cobalt with CH2N2, CH4, CH3D, CH2D2, CHD3, CD4, H2, D2, and HD

W. E. Billups、Sou-Chan Chang、Robert H. Hauge 等 4 位作者1995-02-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLow-Temperature Reactions of Atomic Cobalt with CH2N2, CH4, CH3D, CH2D2, CHD3, CD4, H2, D2, and HDW. E. Billups, Sou-Chan Chang, Robert H. Hauge, and John L. MargraveCite this: J. Am. Chem. Soc. 1995, 117, 4, 1387–1392Publication Date (Print):February 1, 1995Publication Hist…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

On the Formation of Tetracoordinate Boron in Rubidium Borate Glasses

Randall E. Youngman、Josef W. Zwanziger1995-02-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOn the Formation of Tetracoordinate Boron in Rubidium Borate GlassesR. E. Youngman and J. W. ZwanzigerCite this: J. Am. Chem. Soc. 1995, 117, 4, 1397–1402Publication Date (Print):February 1, 1995Publication History Published online1 May 2002Published inissue 1 February 1995h…

Glass properties and applicationsThermodynamic and Structural Properties of Metals and Alloys

Electrochemical response of poly(vinylferrocenium)‐coated Pt electrods to some anions in aqueous media

Handan Gülce、Haluk Özyörük、Adalet Elçin Yıldız1995-02-01Electroanalysis

Abstract The electrooxidation behavior of iodide, thiocyanate, and cyanide on poly(vinylferrocenium)‐coated Pt electrodes was investigated using cyclic voltammetry and differential pulse anodic stripping voltammetry. IR and UV spectroscopic data, and differential scanning calorimetry (DSC) measurements indicated that…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

X-Ray Diffraction from Mesophases of Some Stilbazole Complexes of Silver(I); Monodomain Determination of a Thermotropic Cubic Phase

Duncan W. Bruce、Bertrand Donnio、Sarah Hudson 等 7 位作者1995-02-01Journal de Physique II

A family of mesomorphic bis(alkoxystilbazole) silver(I) dodecylsulphate and octylsulphate complexes has been studied by X-ray scattering in their various mesophases. In particular, many of the complexes exhibit a thermotropic cubic mesophase and, for one example, a monodomain was obtained allowing the space group to b…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsNonlinear Optical Materials Research

Metal-mediated crystallization of amorphous silicon in silicon-silver layered systems

Toyohiko J. Konno、Robert Sinclair1995-02-01Philosophical Magazine B

We report on the crystallization behaviour of amorphous Si(a-Si) in a-Si/Ag/a-Si trilayer and a-Si/Ag multilayer systems using in situ transmission electron microscopy (TEM) and differential scanning calorimetry. The crystallization temperature of a-Si in these Si/Ag layered systems is 385–415°C, about 200°C lower tha…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceSemiconductor materials and interfaces

Optical and electrical properties of Ag-As-S glasses

M. Ohto、Mikitaka Itoh、Keiji Tanaka1995-02-01Journal of Applied Physics

Physical properties of Ag2S-As2S3 glassy alloys have been studied as a function of the Ag atomic concentration x. With an increase in x, the optical-absorption edge exhibits a red shift, while the steepness of the Urbach tail changes little. In the glasses with x≥15, the electrical conductivity is governed by Ag+ ioni…

Glass properties and applicationsChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Polyurethane Cationomers with Pendant Trimethylammonium Groups. 1. Fourier Transform Infrared Temperature Studies

Richard J. Goddard、Stuart L. Cooper1995-02-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolyurethane Cationomers with Pendant Trimethylammonium Groups. 1. Fourier Transform Infrared Temperature StudiesR. J. Goddard and S. L. CooperCite this: Macromolecules 1995, 28, 5, 1390–1400Publication Date (Print):February 1, 1995Publication History Published online1 May 2…

Polymer composites and self-healingSynthesis and properties of polymersPhotopolymerization techniques and applications

Octameric enolase from the hyperthermophilic bacterium Thermotoga maritima: Purification, characterization, and image processing

Hartmut Schurig、Kerstin Rutkat、Rainer Jaenicke 等 4 位作者1995-02-01Protein Science

Enolase (2-phospho-D-glycerate hydrolase; EC 4.2.1.11) from the hyperthermophilic bacterium Thermotoga maritima was purified to homogeneity. The N-terminal 25 amino acids of the enzyme reveal a high degree of similarity to enolases from other sources. As shown by sedimentation analysis and gel-permeation chromatograph…

Advanced Proteomics Techniques and ApplicationsEnzyme Structure and FunctionS100 Proteins and Annexins

Mn-Salen Catalyzed Asymmetric Epoxidation of Conjugated Trisubstituted Olefins

Tsutomu Fukuda、Ryo Irie、Tsutomu Katsuki1995-02-01Synlett

All articles of this category Epoxidation of trisubstituted olefins using Mn-salen complex ( 1 ) as a catalyst proceeds with high enantioselectivity and the sense of asymmetric induction observed in this reaction could be rationalized mainly by electronic repulsion between salen-benzene ring and unsaturated olefinic s…

Porphyrin and Phthalocyanine ChemistryPolyoxometalates: Synthesis and ApplicationsOrganic Chemistry Cycloaddition Reactions

Alcohol/methylaluminum diphenolate systems as novel, versatile initiators for synthesis of narrow molecular weight distribution polyester and polycarbonate

Masaki Akatsuka、Takuzo Aida、Shohei Inoue1995-02-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAlcohol/methylaluminum diphenolate systems as novel, versatile initiators for synthesis of narrow molecular weight distribution polyester and polycarbonateMasaki Akatsuka, Takuzo Aida, and Shohei InoueCite this: Macromolecules 1995, 28, 4, 1320–1322Publication Date (Print):F…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesFiber-reinforced polymer composites

Requirements on bacterial polyesters as future substitute for conventional plastics for consumer goods

Urs.J. Hänggi1995-02-01FEMS Microbiology Reviews

Bacterial polyesters such as polyhydroxybutyrate (PHB) or polyhydroxyalkanoates (PHAs) have to pass the following requirements to be accepted on a large scale: (i) they have to fulfil an urgent market need: (ii) they require that new and efficient composting systems are installed in urban areas; (iii) they have to com…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution