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Modeling Particle Size and Clumping Effects in the IR Absorbance Spectra of Dilute Powders

Carlos Pecharromán、Juan Eugenio Iglesias1996-12-01Applied Spectroscopy

The calculation of the IR absorbance of a powdered crystalline, ionic material, diluted in an appropriate IR-transparent matrix in a known proportion, is in principle possible, provided that the size and shape distributions of the particles, as well as the optical parameters of the bulk material, and those of the matr…

Mesoporous Materials and CatalysisX-ray Diffraction in CrystallographyPigment Synthesis and Properties

Thermoluminescent Dosimetry Materials: Properties and Uses

Colin Jones1996-12-01Journal of Radiological Protection

This book will be invaluable to anyone who is interested in understanding the physics of thermoluminescence (TL). Intended for use by TL dosimetrists, research workers and students, it includes information on glow curves, emission spectra, the mechanisms of TL production, trapping parameters associated with TL signals…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator Technologies

Metal Ion and Exopolymer Interaction: A Surface Analytical Study

G. Chen、S. V. Kagwade、G. E. French 等 6 位作者1996-12-01CORROSION

Various concentrations of molybdate (MoO42−) were added to the protein-containing and deproteinated exopolymers of the marine bacterium Deleya marina. Interaction was investigated using x-ray photoelectron spectroscopy (XPS) and electron spin resonance (ESR). MoO42− reduction was observed exclusively in the deaerated…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metals

Control of polymer structure by chain transfer processes

Ezio Rizzardo、Yu Chong、Richard A. Evans 等 5 位作者1996-12-01Macromolecular Symposia

Abstract Chain transfer can be performed effectively by a mechanism of addition‐fragmentation with appropriately substituted allylic compounds, vinyl ethers and thionoesters. Selection of substituents allows the optimization of chain transfer activity and the preparation of macromonomers and other end‐functional polym…

Advanced Polymer Synthesis and CharacterizationSynthesis and properties of polymersPolymer Science and Applications

Substitutional disorder in a Fibonacci chain: Resonant eigenstates and instability of the spectrum

Gerardo G. Naumis、J. L. Aragón1996-12-01Physical review. B, Condensed matter

The effect of substitutional disorder in a Fibonacci chain is studied. In particular it is shown that the presence of a single impurity affects all the states of the unperturbed system, reducing the fractal dimension of the spectrum. Resonant eigenstates are also observed. The consequences of the instability of the sp…

Advanced Chemical Physics StudiesTheoretical and Computational PhysicsQuasicrystal Structures and Properties

Differences in mineral ratios between disaggregated and original clay fractions in some South African soils as affected by amendments

C. Bühmann、I. Rapp、MC Laker1996-12-01Soil Research

Conflicting information is available on the propensity different soil clays exhibit to dispersion. We therefore assessed the relative stability of the clay components of 12 soil samples, from various parts of South Africa, to predominantly physical disruption by a mild disruptive treatment [mechanical shaking for 5 mi…

Soil and Unsaturated FlowClay minerals and soil interactionsTherapeutic Uses of Natural Elements

Characterization of Soil Clay Minerals: Decomposition of X-Ray Diffraction Diagrams and High-Resolution Electron Microscopy

D. Righi、Françoise Elsass1996-12-01Clays and Clay Minerals

Abstract Fine clays (<0.1 μm) extracted from an acid soil developed in a granite saprolite from the Massif Central, France, were characterized by X-ray diffraction (XRD) using a curve decomposition program, and high-resolution transmission electron microscopy (HRTEM) associated with a method of impregnation of mois…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Functionalization of isotactic poly(propylene) with maleic anhydride in the solid phase

Milan Lazár、Ľ. Hrčková、Agnesa Fiedlerová 等 6 位作者1996-12-01Die Angewandte Makromolekulare Chemie

Abstract The influence of temperature and type of initiator on the grafting efficiency of maleic anhydride onto isotactic poly(propylene) powder under solid‐state reaction conditions was investigated. The level of bonded maleic anhydride was found to be about 20% higher using aliphatic peroxide, such as lauroyl peroxi…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisThermal and Kinetic Analysis

Energy Performance Analysis of Prototype Electrochromic Windows

R. Sullivan、M. Rubin、S. Selkowitz1996-12-01University of North Texas Digital Library (University of North Texas)

This paper presents the results of a study investigating the energy performance of three newly developed prototype electrochromic devices. The DOE-2.1 E energy simulation program was used to analyze the annual cooling, lighting, and total electric energy use and peak demand as a function of window type and size. The a…

Building Energy and Comfort OptimizationTransition Metal Oxide Nanomaterials

Molecular origin of ferroelectricity in induced smectic-C*liquid crystalline phases

M. A. Osipov、H. Stegemeyer、A. Sprick1996-12-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Based on recent experimental results, a molecular model of the ferroelectric ordering in the induced smectic-${C}^{*}$ phase is proposed in terms of a coupling between dipole and quadrupole ordering of chiral molecules. The analysis of the correlations between the value and sign of the spontaneous polarization and the…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Influence of Soil Chemical Properties on Adsorption and Oxidation of Phenolic Acids in Soil Suspension

Tomoyuki Makino、Yoshiaki Takahashi、Yasuhiro Sakurai 等 4 位作者1996-12-01Soil Science & Plant Nutrition

Relationships between abiotic oxidation and adsorption of phenolic acids added to soils and soil chemical properties were investigated by using 32 soil samples and ferulic, vanillic, and p-hydroxybenzoic acids. Soil properties studied were as follows: (as adsorption factors) contents of acid oxalate extractable Al (Al…

Radioactive element chemistry and processingPesticide and Herbicide Environmental StudiesClay minerals and soil interactions

Short-range order in some polymer melts from X-ray diffraction

J. D. Londono、A. Habenschuss、John G. Curro 等 4 位作者1996-12-01Journal of Polymer Science Part B Polymer Physics

Wide-angle X-ray diffraction measurements were performed on polymer melts of isotactic and syndiotactic polypropylene (IPP and SPP), poly(ethylenepropylene) (PEP), polystyrene (PS), polyisobutylene (PIB), and polyethylene (PE), to study the dependence of the short-range structure of polymer liquids on chain architectu…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Displacive phase transition in anorthoclase; the "plateau effect" and the effect of T1-T2 ordering on the transition temperature

Stuart A. Hayward、Ekhard K. H. Salje1996-12-01American Mineralogist

Other| December 01, 1996 Displacive phase transition in anorthoclase; the “plateau effect” and the effect of T1-T2 ordering on the transition temperature Stuart A. Hayward; Stuart A. Hayward University of Cambridge, Department of Earth Sciences, Cambridge, United Kingdom Search for other works by this author on: GSW G…

Enzyme Structure and FunctionCalcium Carbonate Crystallization and InhibitionCrystallization and Solubility Studies

Theory of Long-Range Interactions in Polymer Systems

A. N. Semenov1996-12-01Journal de Physique II

A mean-field theory of inhomogeneous polymer systems is developed in order to include the finite molecular weight effects. A general analytical expression for the conformational free energy providing a bridge between strong and weak segregation limits is derived. The general results are further employed to obtain the…

Material Dynamics and PropertiesTheoretical and Computational PhysicsRheology and Fluid Dynamics Studies

Designed Restructuring of Iodine with Microporous SiO2

Gernot Wirnsberger、Harald P. Fritzer、Alois Popitsch 等 5 位作者1996-12-01Angewandte Chemie International Edition in English

Templates for the arrangement of guest molecules—that is the role played by microporous crystalline SiO2 modifications in the insertion compounds presented. The electronic interactions between the guest species can be controlled by the dimensionalities of the void systems. When iodine is the guest component, this is d…

Metal-Organic Frameworks: Synthesis and ApplicationsZeolite Catalysis and SynthesisCovalent Organic Framework Applications

Damping Properties of Shape Memory Alloys During Phase Transformation

J. Van Humbeeck1996-12-01Journal de Physique IV (Proceedings)

A high damping capacity is considered as one of the important functional properties of shape memory alloys. Those properties are related to a thermoelastic martensitic transformation. As a consequence of this transformation, the internal friction or damping can be investigated for three different states : 1. during th…

Seismic Performance and AnalysisShape Memory Alloy TransformationsMagnetic Properties and Applications

Preparation, Structural Characteristics and Catalytic Properties of Large-Pore Rare Earth Element (Ce, La)/Al-Pillared Smectites

Ernst Booij、J. Theo Kloprogge、J.A.R. van Veen1996-12-01Clays and Clay Minerals

Abstract Ce/Al- and La/Al-pillared smectites were prepared by cation exchange of bentonite, saponite and laponite with hydrothermally treated (130–160 °C for 16–136 h) solutions containing mixtures of aluminumchlorohydrate (ACH) and Ce 3+ -/and La 3+ -salts. After calcination at 500 °C, the pillared products are chara…

Mesoporous Materials and CatalysisClay minerals and soil interactionsLayered Double Hydroxides Synthesis and Applications

Polyelectrolyte complexes. I. Synthesis and characterization of some insoluble polyanion-polycation complexes

Stela Dragan、Mariana Cristea、Cornelia Luca 等 4 位作者1996-12-01Journal of Polymer Science Part A Polymer Chemistry

The synthesis of some water-insoluble synthetic polyelectrolyte complexes formed between a weak polyanion and a strong polycation was followed. Sodium salts of poly(acrylic acid) and of some copolymers of acrylic acid with itaconic acid or maleic acid were used as anionic polymers. Cationic polyelectrolytes with quate…

Conducting polymers and applicationsAnalytical Chemistry and SensorsSynthesis and properties of polymers

FRAGMENTATION OF COLLIDING DISCS

FERENC KUN、Hans J. Herrmann1996-12-01International Journal of Modern Physics C

We study the phenomena associated with the low-velocity impact of two solid discs of equal size using a cell model of brittle solids. The fragment ejection exhibits a jet-like structure the direction of which depends on the impact parameter. We obtain the velocity and the mass distribution of the debris. Varying the r…

Laser-Plasma Interactions and DiagnosticsHigh-pressure geophysics and materialsHigh-Velocity Impact and Material Behavior

A Higher-Order Method for Dynamic Optimization of a Class of Linear Systems

Sunil K. Agrawal、Tawiwat Veeraklaew1996-12-01Journal of Dynamic Systems Measurement and Control

This paper deals with optimization of a class of linear dynamic systems with n states and m control inputs, commanded to move between two fixed states in a prescribed final time. This problem is solved conventionally using Lagrange’s multipliers and it is well known that the optimal solution satisfies 2n first-order l…

Heat Transfer and Mathematical ModelingStructural mechanics and materialsEducational Methods and Teacher Development