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Solvent Effect on the Regulation of Urea Hydrolysis Reactions by Copper Complexes

Caio B. Castro、Rafael G. Silveira、Felippe Mariano Colombari 等 6 位作者2020-06-02Chemistry

Abiotic allosterism is most commonly observed in hetero-bimetallic supramolecular complexes and less frequently in homo-bimetallic complexes. The use of hemilabile ligands with high synthetic complexity enables the catalytic center by the addition or removal of allosteric effectors and simplicity is unusually seen in…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Experimental Study of Hydration/Dehydration Behaviors of Metal Sulfates M2(SO4)3 (M = Sc, Yb, Y, Dy, Al, Ga, Fe, In) in Search of New Low-Temperature Thermochemical Heat Storage Materials

Kunihiko Shizume、Naoyuki Hatada、Tetsuya Uda2020-06-02ACS Omega

High Resolution Image Download MS PowerPoint Slide To identify potential low-temperature thermochemical heat storage (TCHS) materials, hydration/dehydration reactions of M 2 (SO 4 ) 3 (M = Sc, Yb, Y, Dy, Al, Ga, Fe, In) are investigated by thermogravimetry (TG). These materials have the same rhombohedral crystal struc…

Phase Change Materials ResearchAdsorption and Cooling SystemsThermal Expansion and Ionic Conductivity

Induction Motor Thermal Analysis Based on Lumped Parameter Thermal Network

Pedro Cabral、Amel Adouni2020-06-02KnE Engineering

Many industry applications required the use of the induction motors. In such envirenement the electrical machines are facing of many stressed operating conditions. One of the critical creteria which decide the choice of the induction motor is the thermal behaviour under different mode operation. In this paper a study…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsInduction Heating and Inverter Technology

Dibenzoanthradiquinone Building Blocks for the Synthesis of Nitrogenated Polycyclic Aromatic Hydrocarbons

José Ignacio Homobono Martínez、Juan P. Mora‐Fuentes、Marco Carini 等 6 位作者2020-06-02Organic Letters

A straightforward method for the synthesis of two dibenzo[ a, h ]anthracene-5,6,12,13-diquinone building blocks is reported. To showcase their usefulness, a series of dibenzo[ a, h ]anthracene nitrogenated derivatives have been synthesized that show different optoelectronic, redox, and charge transport properties, ill…

Organic Electronics and PhotovoltaicsLuminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic Compounds

Microstructure and Electrical Property of Ex-Situ and In-Situ Copper Titanium Carbide Nanocomposites

Nguyễn Hoàng Việt、Nguyen Thi Hoang Oanh2020-06-02Metals

In this study, ex-situ Cu-TiC nanocomposites of 1, 3 and 5 vol. % TiC and in-situ Cu-TiH2-C nanocomposites (corresponding to 5 vol. % TiC) were prepared using ball milling and spark plasma sintering methods. Powder mixtures were milled for 4 h at 400 rpm. As-milled Cu-TiC composite powders were consolidated under an a…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

A comparative study of materials assembled from recombinant K31 and K81 and extracted human hair keratins

Rachael N. Parker、Alexis Trent、Kristina L Roth Stefaniak 等 5 位作者2020-06-02Biomedical Materials

Natural biopolymers have found success in tissue engineering and regenerative medicine applications. Their intrinsic biocompatibility and biological activity make them well suited for biomaterials development. Specifically, keratin-based biomaterials have demonstrated utility in regenerative medicine applications incl…

Skin Protection and AgingDyeing and Modifying Textile FibersSilk-based biomaterials and applications

Making Waves

Paul Westerhoff、Julie B. Zimmerman、Jennifer A. Field 等 4 位作者2020-06-02Environmental Science & Technology

ADVERTISEMENT RETURN TO ISSUECommentNEXTMaking WavesPaul WesterhoffPaul WesterhoffSustainable Engineering and The Built Environment, Arizona State University, Tempe, Arizona 85287, United StatesMore by Paul Westerhoff, Julie Beth Zimmerman*Julie Beth ZimmermanDepartment of Chemical & Environmental Engineering and Yale…

Nanoparticles: synthesis and applicationsMicrobial Fuel Cells and BioremediationElectrochemical Analysis and Applications

Contributions to Optical Properties and Efficiencies of Methyl–Ammonium Lead, Tin, and Germanium Iodide Perovskites

C. Tablero2020-06-02The Journal of Physical Chemistry C

Methyl–ammonium lead, tin, and germanium iodide perovskites are very interesting compounds for photovoltaics because they present a high absorption capacity for solar radiation. The microscopic contributions to the absorption coefficients and efficiencies of these perovskites are analyzed and quantified. To achieve th…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Enhanced Hydromagnesite Process for CO2 Sequestration by Desilication of Serpentine Ore in NaOH Solution

Xiaojuan Zhang、Yan Zeng、Zhibao Li2020-06-02Industrial & Engineering Chemistry Research

A new CO 2 fixation process was highly enhanced by desilication of serpentine ore with concentrated NaOH solution and NH 3 recycling. In the process, desilicated serpentine containing up to 83 wt % MgO after leaching is treated by NH 4 Cl solution, from which MgCl 2 solution and NH 3 gas are generated and are used to…

Carbon Dioxide Capture TechnologiesCO2 Sequestration and Geologic InteractionsLayered Double Hydroxides Synthesis and Applications

Couette flows of a thixotropic yield-stress material: Performance of a novel fluidity-based constitutive model

Ivan R. Siqueira、Matteo Pasquali、Paulo R. de Souza Mendes2020-06-02Journal of Rheology

We present a theoretical and computational study of thixotropic yield-stress materials in cylindrical Couette flows using a novel fluidity-based constitutive model introduced by de Souza Mendes et al. [J. Nonnewtion. Fluid Mech. 261, 1–8 (2018)]. The model relies on measurable rheological properties to couple the equa…

Material Dynamics and PropertiesRheology and Fluid Dynamics StudiesPickering emulsions and particle stabilization

Engineering a Ga-Gradient by One-Step Sputtering to Achieve Over 15% Efficiency of Cu(In,Ga)Se2 Flexible Solar Cells without Post-selenization

Yu‐Hsiang Wang、Pin‐Han Ho、Wei‐Chih Huang 等 7 位作者2020-06-02ACS Applied Materials & Interfaces

A one-step sputtering process using a quaternary target has been demonstrated to be a simple route to form Cu(In,Ga)Se 2 (CIGSe) absorber without post-selenization; however, the lack of a Ga-grading structure in the CIGSe absorber confines its efficiency. Here, we demonstrate a one-step cosputtering process to control…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Three-Dimensional “Star of David”-Shaped Fullerene (C60) Microstructures: Controlled Synthesis, Photoluminescence, and Photoelectrochemical Properties

Ning Chen、Yilong Hu、Ting Xu 等 4 位作者2020-06-02ACS Applied Electronic Materials

Fullerene micro-/nanostructures with controllable dimensions and explicit morphologies have been widely studied, but such architectures without definitely exposed facets have rarely been reported because of the difficulties in regulating the diffusion behaviors of fullerene molecules at the interfaces. Herein, assumin…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

The spectrum of the atomic orbital overlap matrix and the locality of the virtual electronic density matrix

Ida‐Marie Høyvik2020-06-02Molecular Physics

It is well known that near-linear dependencies in the atomic orbital (AO) basis will impede electronic-structure calculations since the inverse AO overlap matrix will be ill-defined. However, small eigenvalues will also impact the locality of the virtual density matrix. The virtual density matrix is relevant for devel…

Advanced Chemical Physics StudiesMolecular Junctions and NanostructuresMachine Learning in Materials Science

High pressure buried gas pipeline leakage temperature drop testing and theory analysis

Zhaoming Zhou、Jinsong Tan、Jia Zhang 等 5 位作者2020-06-02Numerical Heat Transfer Part A Applications

Great damages to environment will be caused once high pressure buried pipeline leakage leaks occurs. Distributed temperature sensing (DTS) is a good monitoring method of temperature change. Gas from buried pipe leaks is monitored by changes caused by the Joule-Thomson (J-T) effect. In this work, the temperature variat…

High voltage insulation and dielectric phenomenaWater Systems and OptimizationGeotechnical Engineering and Underground Structures

Effects of electropulsing on inclusion size and corrosion-resistance of 304 stainless steel

Danbin Jia、Liang‐Cai Zhong、Jingkun Yu 等 8 位作者2020-06-02Materials Science and Technology

Electropulsing has been imposed on molten AISI 304 stainless steel and its effects on the inclusion size and corrosion properties have been investigated. The average size of inclusions in electropulsing-treated samples was finer than that in untreated ones. A theoretical analysis shows that the mobility of solute atom…

Advanced Welding Techniques AnalysisHydrogen embrittlement and corrosion behaviors in metalsElectromagnetic Effects on Materials

Distinct spatiotemporal imaging of femtosecond surface plasmon polaritons assisted with the opening of the two-color quantum pathway effect

Zhenlong Zhao、Peng Lang、Yulu Qin 等 6 位作者2020-06-02Optics Express

Accurately capturing the spatiotemporal information of surface plasmon polaritons (SPPs) is the basis for expanding SPP applications. Here, we report spatio-temporal evolution imaging of femtosecond SPPs launched from a rectangular trench in silver film with a 400-nm light pulse assisted femtosecond laser interferomet…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchOptical Coatings and Gratings

Relationship between Energy Dosage and Apoptotic Cell Death by Modulated Electro-Hyperthermia

Patrick Hung-Ju Kao、Chia‐Hung Chen、Yuk‐Wah Tsang 等 13 位作者2020-06-02Scientific Reports

to the microenvironment. While investigational evidence has shown the unique ability of mEHT to elicit apoptosis in cancer cells, in vivo and in vitro, the same trait has not been observed with conventional HT. There is dissension as to what allows mEHT to elicit apoptosis despite heating to only mild temperatures, wi…

Ultrasound and Hyperthermia ApplicationsMicrobial Inactivation MethodsUltrasound and Cavitation Phenomena

Inhibitory effect of magnetic iron‐oxide nanoparticles on the pattern of expression of lanosterol 14 α ‐demethylase ( ERG11 ) in fluconazole‐resistant colonising isolate of Candida albicans

Mohammad Zare‐Khafri、Fahimeh Alizadeh、Sadegh Nouripour‐Sisakht 等 5 位作者2020-06-02IET Nanobiotechnology

Fluconazole‐resistant Candida albicans is a big scary reality. The authors assessed the antifungal effects of magnetic iron‐oxide nanoparticles on fluconazole‐resistant colonising isolate of C. albicans and determined the expression of ERG11 gene, protein sequence similarity and ergosterol content. C. albicans isolate…

Nanoparticles: synthesis and applicationsAntifungal resistance and susceptibilityParasitic Diseases Research and Treatment

Natural Radioactivity Levels and Estimation of Radiation Exposure in Agricultural Soils from Skopje City Region

Aleksandra Angjeleska、Elizabeta Dimitrieska-Stojković、Zehra Hajrulai-Musliu 等 5 位作者2020-06-02Macedonian Journal of Chemistry and Chemical Engineering

The aim of this study was to determine the activity concentrations of naturally occurring radioisotopes 226Ra, 232Th and 40K in 14 soil samples collected in the Skopje city surrounding, and to calculate the corresponding absorbed gamma dose rates. The radionuclides were measured applying a high purity Ge detector gamm…

Radioactivity and Radon MeasurementsRadioactive contamination and transferGraphite, nuclear technology, radiation studies

Designing Multi‐Level Resistance States in Graphene Ferroelectric Transistors

Morteza Hassanpour Amiri、Jonas Heidler、Kläus Müllen 等 5 位作者2020-06-02Advanced Functional Materials

Abstract Conventional memory elements code information in the Boolean “0” and “1” form. Devices that exceed bistability in their resistance are useful as memory for future data storage due to their enhanced memory capacity, and are also a necessity for contemporary applications such as neuromorphic computing. Here, wi…

Graphene research and applicationsAdvanced Memory and Neural ComputingFerroelectric and Negative Capacitance Devices