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Features of some Polymer Building Materials Behavior at Heating

Alexey Vasilchenko、Olexandr Danilin、Tatiana Lutsenko 等 5 位作者2020-08-07Materials science forum

The problems of reducing combustibility and increasing fire resistance of some polymer building materials are considered. And the toxicity of the gaseous products of their thermal degradation was evaluated both individually and in various combinations with each other. The features of thermal degradation and the loss o…

Flame retardant materials and propertiesStructural mechanics and materialsEnvironmental and Industrial Safety

Application of double network of gellan gum and pullulan for bone marrow stem cells differentiation towards chondrogenesis by controlling viscous substrates

Ain Park、Joo Hee Choi、Sumi Lee 等 6 位作者2020-08-07Journal of Tissue Engineering and Regenerative Medicine

Hydrogels have a large amount of water that provides a cartilage-like environment and is used in tissue engineering with biocompatibility and adequate degradation rates. In order to differentiate stem cells, it is necessary to adjust the characteristics of the matrix such as stiffness, stress-relaxing time, and microe…

Osteoarthritis Treatment and MechanismsProteoglycans and glycosaminoglycans researchSilk-based biomaterials and applications

Minimisation of Heating Time for Full Hardening in Hot Stamping Using Direct Resistance Heating

Tomoyoshi Maeno、K. Mori、Masato Sakagami 等 5 位作者2020-08-07Journal of Manufacturing and Materials Processing

To obtain enough hardness of the die-quenched products after hot stamping using direct resistance heating, the effects of the electrifying condition and initial microstructure of the quenchable steel sheet on hardness were examined in a hot bending experiment. The steel sheet was heated up to 900 °C in 3 to 10 s. The…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Characterization of a New M4 Metalloprotease With Collagen-Swelling Ability From Marine Vibrio pomeroyi Strain 12613

Yan Wang、Bai-Xue Liu、Junhui Cheng 等 11 位作者2020-08-07Frontiers in Microbiology

strain 12613 from Atlantic seawater and purified a protease VP9 from strain 12613. VP9 was identified as a metalloprotease of the M4 family. VP9 could hydrolyze casein and gelatin but not elastin and collagen. With gelatin as the substrate, VP9 showed the highest activity at 40°C and pH 6.0-8.0. It was stable at tempe…

Protein Hydrolysis and Bioactive PeptidesEnzyme Production and CharacterizationCollagen: Extraction and Characterization

The Crystallization Mechanism of Zr-Based Bulk Metallic Glass during Electron Beam Remelting

Xiaopeng Li、Zeyu Zhang、Yi Yang 等 6 位作者2020-08-07Materials

Bulk metallic glasses (BMGs) are promising for multifunctional and structural application in different industries. However, the limited size of BMGs hinders their further application. The welding of BMGs has shown the possibility of getting rid of the casting size limitation. The heat-affected zone (HAZ) and fusion zo…

Glass properties and applicationsMetallic Glasses and Amorphous AlloysPhase-change materials and chalcogenides

Fedorite from Murun Alkaline Complex (Russia): Spectroscopy and Crystal Chemical Features

Екатерина Канева、Roman Shendrik、Tatiana Radomskaya 等 4 位作者2020-08-07Minerals

Fedorite is a rare phyllosilicate, having a crystal structure characterized by SiO4-tetrahedral double layers located between continuous layers formed by edge-sharing (Ca,Na)-octahedra, and containing interlayer K, Na atoms and H2O molecules. A mineralogical-petrographic and detailed crystal-chemical study of fedorite…

Crystal Structures and PropertiesRadioactive element chemistry and processingMineralogy and Gemology Studies

Effect of grain boundary energy anisotropy on grain growth in ZK60 alloy using a 3D phase-field modeling*

Yu-hao SONG、Mingtao Wang、Jia Ni 等 5 位作者2020-08-07Chinese Physics B

A three-dimensional (3D) multiple phase field model, which takes into account the grain boundary (GB) energy anisotropy caused by texture, is established based on real grain orientations and Read–Shockley model. The model is applied to the grain growth process of polycrystalline Mg (ZK60) alloy to investigate the evol…

Magnesium Alloys: Properties and ApplicationsAluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomena

Inhibition of Phase Separation in Aerosolized Water-Soluble Polymer–Polymer Nanoparticles at Small Sizes and the Effects of Molecular Weight

Emily-Jean E. Ott、Miriam Arak Freedman2020-08-07The Journal of Physical Chemistry B

The effects of confinement on the phase separation behavior of polymer-polymer mixtures have been frequently studied in morphologies such as thin films and rods, but little research exists with respect to the nanoscale droplet size regime. This paper addresses the phase separation of water-soluble polymers in submicro…

Catalytic Processes in Materials SciencePhase Equilibria and Thermodynamicsnanoparticles nucleation surface interactions

Unconventional isotope effect on transition temperature in BiS2-based superconductor Bi4O4S3

Rajveer Jha、Yoshikazu Mizuguchi2020-08-07Applied Physics Express

We report the sulfur isotope effect on transition temperature ( T c ) in a BiS 2 -based superconductor Bi 4 O 4 S 3 . Polycrystalline samples of Bi 4 O 4 S 3 were prepared using 32 S and 34 S isotope chemicals. From magnetization analyses, the isotope exponent ( α S ) was estimated as −0.1 < α S < 0.1. Although the T…

Physics of Superconductivity and MagnetismIron-based superconductors researchChemical and Physical Properties of Materials

Magnetic-Domain-Wall-Induced Electrical Polarization in Rare-Earth Iron Garnet Systems: A First-Principles Study

Temuujin Bayaraa、Changsong Xu、Yali Yang 等 5 位作者2020-08-07Physical Review Letters

First-principles methods are employed to understand the existence of magnetic-domain-wall-induced electric polarization observed in rare-earth iron garnets. In contrast with previous beliefs, it is found that the occurrence of such polarization neither requires the local magnetic moments of the rare-earth ions nor non…

Multiferroics and related materialsPhotorefractive and Nonlinear OpticsMagneto-Optical Properties and Applications

Perylenetetracarboxylic Diimide as Diffusion‐Less Electrode Material for High‐Rate Organic Na‐Ion Batteries

Sebastian Liebl、Daniel Werner、Doğukan Hazar Apaydın 等 6 位作者2020-08-07Chemistry - A European Journal

Abstract In this work 3,4,9,10‐perylenetetracarboxylic diimide (PTCDI) is investigated as electrode material for organic Na‐ion batteries. Since PTCDI is a widely used industrial pigment, it may turn out to be a cost‐effective, abundant, and environmentally benign cathode material for secondary Na‐ion batteries. Among…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesConducting polymers and applications

Control of energy dissipation in sliding low-dimensional materials

Antonio Cammarata、Tomáš Polcar2020-08-07Physical review. B./Physical review. B

Frictional forces acting during the relative motion of nanosurfaces are the cause of energy loss and wear which limit an efficient assembly and yield of atomic-scale devices. In this research, we investigate the microscopic origin of the dissipative processes as a result of the frictional response, with the aim to con…

2D Materials and ApplicationsMolecular Junctions and NanostructuresForce Microscopy Techniques and Applications

Magnetism of Kesterite Cu2ZnSnS4 Semiconductor Nanopowders Prepared by Mechanochemically Assisted Synthesis Method

Katarzyna Lejda、Mariusz Drygaś、Jerzy F. Janik 等 6 位作者2020-08-07Materials

High energy ball milling is used to make first the quaternary sulfide Cu2ZnSnS4 raw nanopowders from two different precursor systems. The mechanochemical reactions in this step afford cubic pre-kesterite with defunct semiconducting properties and showing no solid-state 65Cu and 119Sn MAS NMR spectra. In the second ste…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Correlation among the Power Dissipation Efficiency, Flow Stress Course, and Activation Energy Evolution in Cr-Mo Low-Alloyed Steel

Petr Opěla、Ivo Schindler、Petr Kawulok 等 7 位作者2020-08-07Materials

In the presented research, conventional hot processing maps superimposed over the flow stress maps or activation energy maps are utilized to study a correlation among the efficiency of power dissipation, flow stress, and activation energy evolution in the case of Cr-Mo low-alloyed steel. All maps have been assembled o…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Metal–Sulfur Linkages Achieved by Organic Tethering of Ruthenium Nanocrystals for Enhanced Electrochemical Nitrogen Reduction

Muhammad Ibrar Ahmed、Chuangwei Liu、Yong Zhao 等 7 位作者2020-08-07Angewandte Chemie

Abstract Inspired by the metal–sulfur (M‐S) linkages in the nitrogenase enzyme, here we show a surface modification strategy to modulate the electronic structure and improve the N2 availability on a catalytic surface, which suppresses the hydrogen evolution reaction (HER) and improves the rate of NH3 production. Ruthe…

Advanced Photocatalysis TechniquesHydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen Reduction

Synthesis and Permselectivity of a Soluble Two-Dimensional Macromolecular Sheet by Solid–Solid Interfacial Polycondensation Followed by Chemical Exfoliation

Yanqing Qu、Xiaoyu Du、Kehan Cheng 等 9 位作者2020-08-07ACS Materials Letters

Two-dimensional (2D) network polymers with nano-sized pores are generally insoluble, and therefore, it is difficult to determine their molecular structures and to fabricate their membranes. Soluble 2D network polymer membranes with angstrom-sized pores and thicknesses have not been reported. Herein, novel soluble 2D m…

Graphene research and applicationsMembrane Separation and Gas TransportCovalent Organic Framework Applications

Triflic Acid-Promoted Adamantylation and tert -Butylation of Pyrene: Fluorescent Properties of Pyrene-Decorated Adamantanes and a Channeled Crystal Structure of 1,3,5-Tris(pyren-2-yl)adamantane

Anna Wrona‐Piotrowicz、Anna Makal、Janusz Zakrzewski2020-08-07The Journal of Organic Chemistry

Abstract Triflic acid-promoted 1-adamantylation and tert-butylation of pyrene at positions 2 and 2,7 along with the synthesis of compounds having one-, two-, and three-pyrenyl groups attached to the adamantane scaffold are disclosed. Fluorescent properties of these compounds and channeled crystal structure of the 1,3,…

Porphyrin and Phthalocyanine ChemistryFluorine in Organic ChemistryEicosanoids and Hypertension Pharmacology

Direct in-situ Measurement of Magnetic Loss in Power Electronic Circuits

Lifang Yi、Jinyeong Moon2020-08-07IEEE Transactions on Power Electronics

Timing skew between measurement channels can introduce an unacceptable error in power loss measurement and is difficult to quantify, rendering precise in-situ measurement of magnetic loss essentially unattainable. This article rams the issue head-on by presenting the mathematical model for the timing skew and developi…

Advanced DC-DC ConvertersSilicon Carbide Semiconductor TechnologiesMagnetic Properties and Applications

Geminal parahydrogen-induced polarization: accumulating long-lived singlet order on methylene proton pairs

Laurynas Dagys、Barbara Ripka、Markus Leutzsch 等 7 位作者2020-08-07Magnetic Resonance

Abstract. In the majority of hydrogenative parahydrogen-induced polarization (PHIP) experiments, the hydrogen molecule undergoes pairwise cis addition to an unsaturated precursor to occupy vicinal positions on the product molecule. However, some ruthenium-based hydrogenation catalysts induce geminal hydrogenation, lea…

Advanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallographyAtomic and Subatomic Physics Research

Traversing the Red–Green–Blue Color Spectrum in Rationally Designed Cupredoxins

Karl J. Koebke、Victor Sosa Alfaro、Tyler B. J. Pinter 等 8 位作者2020-08-07Journal of the American Chemical Society

Blue copper proteins have a constrained Cu(II) geometry that has proven difficult to recapitulate outside native cupredoxin folds. Previous work has successfully designed green copper proteins which could be tuned blue using exogenous ligands, but the question of how one can create a self-contained blue copper site wi…

Photosynthetic Processes and MechanismsEnzyme Structure and FunctionMetalloenzymes and iron-sulfur proteins