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Fluorescence-Enabled Self-Reporting for Redox Flow Batteries

Lily A. Robertson、Ilya A. Shkrob、Garvit Agarwal 等 9 位作者2020-08-07ACS Energy Letters

Monitoring battery health is challenging. Self-reporting enables the rapid health assessment of redox flow batteries (RFBs) and provides insight into degradation mechanisms of electrochemically active molecules (redoxmers). Here we introduce fluorescence as an orthogonal property to probe this chemistry in situ . An e…

Perovskite Materials and ApplicationsConducting polymers and applicationsAdvanced battery technologies research

Hydrothermal Synthesis of Flake-Flower NiO and Its Gas Sensing Performance to CO

Guochao Qian、Qingjun Peng、Dexu Zou 等 5 位作者2020-08-07Frontiers in Materials

In this work, flake-flower NiO was successfully prepared via a facile hydrothermal method. The microstructure of the synthesized sample was characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). We find that the hierarchical flake-flower structu…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Hydrogen Production via Model Diesel Steam Reforming over a High-Performance Ni/Ce 0.75 La 0.25 O 2−δ -γ-Al 2 O 3 Catalyst with Oxygen Vacancies

Qiangqiang Xue、Binhang Yan、Meng Chen 等 5 位作者2020-08-07Industrial & Engineering Chemistry Research

Hydrogen-rich syngas production via diesel steam reforming (DSR) is of great interest because of the high H 2 /CO ratio and available external heat sources. In this study, catalysts (particle size ( d p ) = 3–5 mm) containing 10 wt % Ni were prepared through wet impregnation, and their performance was evaluated in a s…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Hydrodesulfurization Studies

Accurate Temperature Estimation for Each Gate of GaN HEMT With n-Gate Fingers

Amgad A. Al‐Saman、Yi Pei、E. A. Ryndin 等 4 位作者2020-08-07IEEE Transactions on Electron Devices

An analytical approach based on the thermoelectrical analogy to calculate the maximum channel temperature of multifinger AlGaN/GaN HEMT transistor is presented. The model is capable of predicting the maximum channel temperature, including the impact of the nonlinearity of thermal conductivity for every single gate wit…

GaN-based semiconductor devices and materialsSilicon Carbide Semiconductor TechnologiesThermal properties of materials

Immobilization of Au nanoparticles on poly(glycidyl methacrylate)‐functionalized magnetic nanoparticles for enhanced catalytic application in the reduction of nitroarenes and Suzuki reaction

Ali Pourjavadi、Mohammad Kohestanian、Nahid Keshavarzi2020-08-07Applied Organometallic Chemistry

We report a novel strategy for the synthesis of magnetic nanocomposite for highly efficient catalysis. Poly(glycidyl methacrylate) (PGMA) chains were grafted to the surface of magnetic nanoparticles (MNPs) through surface‐initiated reversible addition‐fragmentation chain transfer polymerization. Then, the oxirane ring…

Advanced Photocatalysis TechniquesNanocluster Synthesis and ApplicationsNanomaterials for catalytic reactions

Evaluation of Chemical Bonding in Actinyl(VI/V) Oxo-Crown-Ether Complexes for Actinide Series from Uranium to Curium

Peng Zhang、Yaxing Wang、Ping Zhang 等 5 位作者2020-08-07Inorganic Chemistry

The separation and management of nuclear waste is one of the problems that needs to be solved urgently, so finding a new radiation-proof and durable extractant to deal with nuclear waste is a difficult but desirable task. Since the successful isolation of the first pentavalent plutonium crown ether complex recently (W…

Radioactive element chemistry and processingNuclear Materials and PropertiesChemical Synthesis and Characterization

Oxy-Steam Reforming of Natural Gas on Ni Catalysts—A Minireview

Magdalena Mosińska、M. I. Szynkowska、Paweł Mierczyński2020-08-07Catalysts

Nowadays, the reforming of natural gas is the most common of hydrogen or syngas generation process. Each reforming process leads to the achievement of specific goals and benefits related to investment costs. The disadvantage of the reforming process is the need to preclean it mostly from the sulfur and nitrogen compou…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Hydrodesulfurization Studies

Hot Deformation Characteristic and Strain Dependent Constitutive Flow Stress Modelling of Ti + Nb Stabilized Interstitial Free Steel

Sumit Ghosh、Mahesh C. Somani、Daria Setman 等 4 位作者2020-08-07Metals and Materials International

Abstract An effort has been made to establish a relation between Zener–Hollomon parameter, flow stress and dynamic recrystallization (DRX). In this context, the plastic flow behavior of Ti + Nb stabilized interstitial free (IF) steel was investigated in a temperature range of 650–1100 °C and at constant true strain ra…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsMetallurgy and Material Forming

Fluorination Enhances NIR‐II Fluorescence of Polymer Dots for Quantitative Brain Tumor Imaging

Ye Liu、Jinfeng Liu、Dandan Chen 等 14 位作者2020-08-07Angewandte Chemie

Abstract Here, we describe a fluorination strategy for semiconducting polymers for the development of highly bright second near‐infrared region (NIR‐II) probes. Tetrafluorination yielded a fluorescence QY of 3.2 % for the polymer dots (Pdots), over a 3‐fold enhancement compared to non‐fluorinated counterparts. The flu…

Nanoplatforms for cancer theranosticsLuminescence and Fluorescent MaterialsPolydiacetylene-based materials and applications

Anisotropic Gas Separation in Oriented ZIF‐95 Membranes Prepared by Vapor‐Assisted In‐Plane Epitaxial Growth

Xixi Ma、Wan Zheng、Yanhong Li 等 6 位作者2020-08-07Angewandte Chemie

Abstract Control of the microstructure grain orientation, grain boundaries and thickness are crucial for MOF membranes. We report a novel synthesis strategy to prepare highly c‐oriented ZIF‐95 membranes through vapor‐assisted in‐plane epitaxial growth. In a mixed DMF/water vapor atmosphere, in‐plane epitaxial growth o…

Metal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas TransportMXene and MAX Phase Materials

Na3V2O2(PO4)2F Cathode for High‐Performance Quasi‐Solid‐State Sodium‐Ion Batteries with a Wide Workable Temperature Range

Jie Li、Guangyuan Du、Tianbei Huang 等 8 位作者2020-08-07Energy Technology

Solid‐state batteries have attracted significant attention due to their safety, but most studies focus on room‐temperature performance. Herein, the electrochemical performance of quasi‐solid‐state sodium‐ion batteries (SIBs) based on the perfluorosulfonate‐based polymer electrolyte (PFSA‐Na) and Na3V2O2(PO4)2F (NVOPF)…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Low Temperature Synthesis of Photocatalytic Mesoporous TiO2 Nanomaterials

Massimo Dell’Edera、Francesca Petronella、Alessandra Truppi 等 13 位作者2020-08-07Catalysts

We report the synthesis of mesoporous TiO2 nanostructures based on the decomposition of TiOSO4 in aqueous alkaline solution at room temperature, followed by mild thermal treatment (110 °C) in an oven and suitable to yield up to 40 g of product per batch. The duration of the thermal treatment was found to be crucial to…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCatalytic Processes in Materials Science

Following In Situ the Evolution of Morphology and Optical Properties during Printing of Thin Films for Application in Non-Fullerene Acceptor Based Organic Solar Cells

Kerstin S. Wienhold、Christian L. Weindl、Shanshan Yin 等 8 位作者2020-08-07ACS Applied Materials & Interfaces

In situ printing gives insight into the evolution of morphology and optical properties during slot-die coating of active layers for application in organic solar cells and enables an upscaling and optimization of the thin film deposition process and the photovoltaic performance. Active layers based on the conjugated po…

Organic Electronics and PhotovoltaicsThin-Film Transistor TechnologiesConducting polymers and applications

Role of hydrochloric acid treated HZSM-5 zeolite in Sm2Ti2O7/nHZSM-5 composite for photocatalytic degradation of ofloxacin

Lili Yang、Kuiqi Wang、Yang Jiao 等 4 位作者2020-08-07Journal of Materials Research and Technology

NaZSM-5 was treated in hydrochloric acid solution to prepare HZSM-5. The Sm2Ti2O7/nHZSM-5 composites were synthesized via a sol-gel route. The concentration of the hydrochloric acid solution could greatly influence the properties of the Sm2Ti2O7/nHZSM-5 composites, and the composites were characterized to clarify the…

Advanced Photocatalysis TechniquesNuclear materials and radiation effectsChemical Synthesis and Characterization

Quantifying the thermodynamics of protein unfolding using 2D NMR spectroscopy

Rita Puglisi、Oliver Brylski、Caterina Alfano 等 6 位作者2020-08-07Communications Chemistry

A topic that has attracted considerable interest in recent years is the possibility to perform thermodynamic studies of proteins directly in-cell or in complex environments which mimic the cellular interior. Nuclear magnetic resonance (NMR) could be an attractive technique for these studies but its applicability has s…

Protein Structure and DynamicsEnzyme Structure and FunctionAdvanced NMR Techniques and Applications

Bulk and Interfacial Contributions to the Adhesion of Acrylic Emulsion-Based Pressure-Sensitive Adhesives

Qifeng Wang、William B. Griffith、Melinda L. Einsla 等 6 位作者2020-08-07Macromolecules

The performance of pressure-sensitive adhesives (PSAs) depends on the bulk viscoelastic properties of the adhesive material itself and on the surface with which it is placed into contact. In this work, a probe technique was used to quantify the adhesion and to develop a protocol to interrogate these bulk and interfaci…

Force Microscopy Techniques and ApplicationsAdhesion, Friction, and Surface InteractionsSilicone and Siloxane Chemistry

A novel hybrid organosolv-steam explosion pretreatment and fractionation method delivers solids with superior thermophilic digestibility to methane

Λεωνίδας Μάτσακας、Omprakash Sarkar、Stina Jansson 等 5 位作者2020-08-07Bioresource Technology

Rising environmental concerns and the imminent depletion of fossil resources have sparked a strong interest towards the production of renewable energy such as biomethane. Inclusion of alternative feedstock’s such as lignocellulosic biomass could further expand the production of biomethane. The present study evaluated…

Thermochemical Biomass Conversion ProcessesBiofuel production and bioconversionbiodegradable polymer synthesis and properties

Drosophila miR-87 promotes dendrite regeneration by targeting the transcriptional repressor Tramtrack69

Yasuko Kitatani、Akane Tezuka、Eri Hasegawa 等 9 位作者2020-08-07PLoS Genetics

To remodel functional neuronal connectivity, neurons often alter dendrite arbors through elimination and subsequent regeneration of dendritic branches. However, the intrinsic mechanisms underlying this developmentally programmed dendrite regeneration and whether it shares common machinery with injury-induced regenerat…

Neurobiology and Insect Physiology ResearchInvertebrate Immune Response MechanismsSilk-based biomaterials and applications

Numerical Modeling of Reinforced Concrete Slabs under Impact Loading

Enas Mabrook Mouwainea、AbdulMuttalib I. Said2020-08-07Key engineering materials

This paper aims to provide a numerical model able to represent the behavior of reinforced concrete slabs subjected to impact loads. The nonlinear finite element analysis adopted by ABAQUS/Explicit Software was used in this study. A parametric study was conducted to provide a comprehensive understanding of the behavior…

Structural Behavior of Reinforced ConcreteHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Investigation and study on the novel method of preparing Al-V alloy by electrode assisted heating

Li Wang、Heli Wan、Heng Xiong 等 8 位作者2020-08-07Journal of Materials Research and Technology

A novel method was developed to produce Al-V alloy electrode assisted heating (EAH) technology. The experimental results showed that the cracks in the alloy were significantly reduced and the distribution of the Al8V5 is significantly changed in the alloy. In the experiment, the products with heating time 0 and 10 min…

Aluminum Alloy Microstructure PropertiesAluminum Alloys Composites PropertiesAnodic Oxide Films and Nanostructures