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Tailoring Pseudo-Zwitterionic Bifunctionalized Silica Nanoparticles: From Colloidal Stability to Biological Interactions

Francine R. Scheffer、Camila P. Silveira、Jonder Morais 等 5 位作者2020-08-07Langmuir

Zwitterionic molecules are known to resist nonspecific protein adsorption and have been proposed as an alternative to the widely used polyethylene glycol. Recently, zwitterionic-like nanoparticles were created from the coimmobilization of positive and negative ligands, resulting in surfaces that also prevent protein c…

Nanoparticle-Based Drug DeliveryPolymer Surface Interaction StudiesBlood properties and coagulation

Determination of the plutonium content and O/M ratio of (U,Pu)O2-x using Raman spectroscopy

Laetitia Medyk、D. Manara、Jean‐Yves Colle 等 8 位作者2020-08-07Journal of Nuclear Materials

Oxygen stoichiometry in (U,Pu)O2-x nuclear fuels, while of prime interest, is still difficult to be determined at the micrometric scale. It has been recently evidenced that Raman microscopy is a promising tool to characterize (U,Pu)O2-x samples at a microscopic scale by probing the oxygen sublattice. Its use for deter…

Nuclear reactor physics and engineeringRadioactive element chemistry and processingNuclear Materials and Properties

Efficient and robust signal sensing by sequences of adiabatic chirped pulses

Genko T. Genov、Yachel Ben-Shalom、Fedor Jelezko 等 5 位作者2020-08-07Physical Review Research

We propose a scheme for sensing of an oscillating field in systems with large inhomogeneous broadening and driving field variation by applying sequences of phased, adiabatic, chirped pulses. These act as a double filter for dynamical decoupling, where the adiabatic changes of the mixing angle during the pulses rectify…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchAdvanced Fiber Laser Technologies

Core Loss Modeling and Calculation for Trapezoidal Magnetic Flux Density Waveform

Sobhi Barg、Kent Bertilsson2020-08-07IEEE Transactions on Industrial Electronics

This article proposes a novel approach in order to understand the different kinds of core loss of the trapezoidal flux waveform. The proposed approach is based on the theory of magnetism and assessed with the experimental results to show that the total loss is composed of two terms: the effective triangular loss durin…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Field Sensors Techniques

Real-Space Studies of Plasmon-Induced Dissociation Reactions with an STM

Emiko Kazuma2020-08-07Bulletin of the Chemical Society of Japan

Abstract Molecular bond dissociation and formation reactions induced by localized surface plasmons of metal nanostructures are promising reactions in terms of the effective utilization of sunlight. The plasmon has a potential not only to enhance photochemical reactions but also to enable efficient novel reaction pathw…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchMolecular Junctions and Nanostructures

Formation of Fire Retardant Properties in Elastic Silica Coatings for Textile Materials

Olga Skorodumova、Olena Tarakhno、Olena Chebotaryova 等 5 位作者2020-08-07Materials science forum

The influence of the degree of homogeneity of the SiO2 sol on the duration of the induction period and the quality of fire-resistant coatings on textile materials was studied. The prospects of using IR spectroscopy as an express method for studying the phase composition of a gel coating, the degree of completion of th…

Glass properties and applicationsFlame retardant materials and propertiesMaterial Properties and Applications

Enabling Narrow Emission Line Widths in Colloidal Nanocrystals through Coalescence Growth

James Cassidy、Cole Ellison、Jacob Bettinger 等 6 位作者2020-08-07Chemistry of Materials

With continuing progress in the chemical synthesis of colloidal semiconductor nanocrystals (NC), one property that remains elusive to the rational design is the ensemble photoluminescence (PL) line width. Given the growing demand for NC-based light-emitting materials, substantial research effort has been dedicated to…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Improvement of Fire Resistance of Polymeric Materials at their Filling with Aluminosilicates

Oleksandr Blyznyuk、Alexey Vasilchenko、Artem Ruban 等 4 位作者2020-08-07Materials science forum

Effect of content of synthetic aluminosilicates in medium-density polyethylene on the fire hazard characteristics and mechanical properties of compositions is investigated. It has been shown that during decomposition of the filler with the release of water, its effectiveness depends not only on the endothermic effect…

Flame retardant materials and propertiesMaterial Properties and ApplicationsEnvironmental and Industrial Safety

The Missing Link in the Magnetism of Hybrid Cobalt Layered Hydroxides: The Odd–Even Effect of the Organic Spacer

Víctor Oestreicher、Diego Hunt、Christian Dölle 等 7 位作者2020-08-07Chemistry - A European Journal

Abstract A dramatic change in the magnetic behaviour, which solely depends on the parity of the organic linker molecules, has been found in a family of layered CoII hydroxides covalently functionalized with dicarboxylic molecules. These layered hybrid materials have been synthesized at room temperature using a one‐pot…

Supercapacitor Materials and FabricationPorphyrin and Phthalocyanine ChemistryLayered Double Hydroxides Synthesis and Applications

Effect of phase formation due to holding time of vacuum brazed AISI 304L/NiCrSiB joints on corrosion fatigue properties

Johannes Otto、Milena Penyaz、Anke Schmiedt-Kalenborn 等 7 位作者2020-08-07Journal of Materials Research and Technology

Whether in turbine components or exhaust gas heat exchangers, vacuum-brazed nickel-based joints are subjected to varying cyclical loads during their applications, often in corrosive environments. The microstructure of the brazed seam, which is determined by the alloy composition and the brazing process parameters, is…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metals

Protein Microgel-Stabilized Pickering Liquid Crystal Emulsions Undergo Analyte-Triggered Configurational Transition

Abhijit Dan、Shikha Aery、Shuning Zhang 等 6 位作者2020-08-07Langmuir

Abstract Herein, we report a novel approach that involves Pickering stabilization of micometer-sized liquid crystal (LC) droplets with biocompatible soft materials such as a whey protein microgel (WPM) to facilitate the analysis of analyte-induced configurational transition of the LC droplets. The WPM particles were a…

Proteins in Food SystemsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Applications of Mesoporous Silica-Encapsulated Gold Nanorods Loaded Doxorubicin in Chemo-photothermal Therapy

Nghiem Thi Ha Lien、Anh D. Phan、Bui Khanh 等 10 位作者2020-08-07ACS Omega

High Resolution Image Download MS PowerPoint Slide We investigate the chemo-photothermal effects of gold nanorods (GNRs) coated using mesoporous silica (mSiO 2 ) loading doxorubicin (DOX). When the mesoporous silica layer is embedded by doxorubicin drugs, a significant change in absorption spectra enables to quantify…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsNanoplatforms for cancer theranostics

Searching for New Ferroelectric Materials Using High-Throughput Databases: An Experimental Perspective on BiAlO 3 and BiInO 3

Megha Acharya、Stephanie A. Mack、Abel Fernández 等 10 位作者2020-08-07Chemistry of Materials

Recent advances in high-throughput computational workflows are expanding the realm of materials for a range of applications. Here, we report the experimental evaluation of two such predicted candidate ferroelectric perovskite oxides: BiAlO 3 and BiInO 3 . Attempts were made to synthesize polar BiAlO 3 and BiInO 3 usin…

Magnetic and transport properties of perovskites and related materialsMachine Learning in Materials ScienceElectronic and Structural Properties of Oxides

Triggering Supramolecular Hydrogelation Using a Protein–Peptide Coassembly Approach

Rashmi Jain、Vijay Kumar Pal、Sangita Roy2020-08-07Biomacromolecules

In recent years, the molecular self-assembly approach has witnessed a sudden surge in coassembly strategy to achieve extensive control over accessing diverse nanostructures and functions. To this direction, peptide-peptide coassembly has been explored to some extent in the literature, but protein-peptide coassembly is…

Glycosylation and Glycoproteins ResearchChemical Synthesis and AnalysisSupramolecular Self-Assembly in Materials

Electromagnetic shielding response of magnetite elastomeric composites: Source and filler content dependence

Andrés Orlando Garzón Posada、D.A. Landı́nez Téllez、J. Roa‐Rojas 等 4 位作者2020-08-07Journal of Materials Research and Technology

The structural and electromagnetic shielding properties of NBR rubber filled with magnetite (Fe3O4) were studied. Rubber composite materials with ore magnetite and synthetic magnetite have been produced separately in order to observe its differences. Samples have been fabricated using a rubber mill and different magne…

Electromagnetic wave absorption materialsRadiation Shielding Materials AnalysisAdvanced Energy Technologies and Civil Engineering Innovations

When Ultimate Adhesive Mechanism Meets Ultimate Anti‐Fouling Surfaces—Polydopamine Versus SLIPS: Which One Prevails?

Lizbeth Ofelia Prieto‐López、Petra Herbeck‐Engel、Li Yang 等 6 位作者2020-08-07Advanced Materials Interfaces

Abstract What happens when the extremely adhesive and versatile chemistry of polydopamine (PDA) is in contact with the extremely slippery surfaces known as slippery liquid‐infused porous substrates (SLIPS)? Inspired by the pitcher plant, SLIPS possess excellent repellence against a variety of complex liquids and have…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesMarine Biology and Environmental Chemistry

Light-Directed Growth/Etching of Gold Nanoparticles via Plasmonic Hot Carriers

Yinfeng Long、Shuangshuang Wang、Yunxia Wang 等 5 位作者2020-08-07The Journal of Physical Chemistry C

Plasmon-induced hot carriers can be used to control both the growth and the etching behavior of gold nanoparticles (Au NPs) with laser irradiation. Here, the Au NPs placed on Si substrate are irradiated with a continuous wave laser (641 nm) in the presence of HAuCl 4 solution. Irradiation results in growth/etching of…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchCopper-based nanomaterials and applications

Silane Treatment as an Effective Way of Improving the Reinforcing Activity of Carbon Nanofibers in Nitrile Rubber Composites

Bolesław Szadkowski、Anna Marzec、Przemysław Rybiński2020-08-07Materials

Two different silane treatment methods were used to improve the reinforcing activity of carbon nanofibers (CNF) in acrylonitrile-butadiene rubber (NBR) composites. The first method was chemical silanization with [3-(2-aminoethylamino)propyl]trimethoxysilane (APTS) in ethanol solution, preceded by oxidation of the CNF…

Polymer Nanocomposites and PropertiesConducting polymers and applicationsFiber-reinforced polymer composites

Effect of matrix crystallinity of carbon fiber reinforced polyamide 6 on static bending properties

Takenobu Sakai、Nur Safiah Binti Shamsudim、Ryota Fukushima 等 4 位作者2020-08-07Advanced Composite Materials

Recently, carbon fiber reinforced thermoplastics (CFRTP) have been widely used for various applications instead of carbon fiber reinforced thermosetting plastics (CFRP). Some matrix resins of CFRTP are crystalline polymers such as polyamide (PA), polyetheretherketone (PEEK), and polyimide. In this study, carbon fiber…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Facile Synthesis of Highly Porous N‑Doped Carbon Nanosheets with Silica Nanoparticles for Ultrahigh Capacitance Supercapacitors

Arthi Gopalakrishnan、Aimin Yu、Sushmee Badhulika2020-08-07Energy & Fuels

Abstract Low-cost, scalable, and abundant biomass-derived carbon materials have attracted considerable attention. Herein, we report on novel self-doped (nitrogen) porous carbon nanosheets by carbonization/activation of acorn shells as a biomass precursor for use in high-performance supercapacitors (SCs), which contain…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationAdvanced battery technologies research