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Breathing Metal–Organic Polyhedra Controlled by Light for Carbon Dioxide Capture and Liberation

Yao Jiang、Peng Tan、Shi‐Chao Qi 等 8 位作者2020-08-05CCS Chemistry

Open AccessCCS ChemistryRESEARCH ARTICLE1 Jun 2021Breathing Metal–Organic Polyhedra Controlled by Light for Carbon Dioxide Capture and Liberation Yao Jiang†, Peng Tan†, Shi-Chao Qi, Chen Gu, Song-Song Peng, Fan Wu, Xiao-Qin Liu and Lin-Bing Sun Yao Jiang† State Key Laboratory of Materials-Oriented Chemical Engineering…

Metal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Self-Assembly in MaterialsCovalent Organic Framework Applications

Cost-effective clean ammonia production using membrane-assisted autothermal reforming

Schalk Cloete、Mohammed N. Khan、Shareq Mohd Nazir 等 4 位作者2020-08-05Chemical Engineering Journal

Ammonia is a widely produced industrial chemical, primarily for use in the fertilizer industry. Recently, interest has also grown in ammonia as a carbon-free energy carrier because it is easier to store and transport than hydrogen. However, ammonia is primarily produced from natural gas with a considerable carbon foot…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingAmmonia Synthesis and Nitrogen Reduction

Large Damping-Like Spin–Orbit Torque in a 2D Conductive 1T-TaS 2 Monolayer

Sajid Husain、Xin Chen、Rahul Gupta 等 12 位作者2020-08-05Nano Letters

High Resolution Image Download MS PowerPoint Slide A damping-like spin-orbit torque (SOT) is a prerequisite for ultralow-power spin logic devices. Here, we report on the damping-like SOT in just one monolayer of the conducting transition-metal dichalcogenide (TMD) TaS 2 interfaced with a NiFe (Py) ferromagnetic layer.…

Magnetic properties of thin films2D Materials and ApplicationsAdvanced Memory and Neural Computing

Synthesis, characterization, powder X-ray diffraction analysis, thermal stability, antioxidant properties and enzyme inhibitions of M(II)-Schiff base ligand complexes

Kenan Buldurun、Nevin Turan、Ercan Bursal 等 8 位作者2020-08-05Journal of Biomolecular Structure and Dynamics

The Schiff base ligand ((E)-6-methyl-2-(2,3,4-trimethoxybenzylideneamino)-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carbonitrile) and its cobalt(II) and palladium(II) complexes were successfully prepared. The structure of the compounds was elucidated by various techniques (NMR, FT-IR, powder X-ray diffraction, microanalys…

Metal complexes synthesis and propertiesThermal and Kinetic AnalysisFree Radicals and Antioxidants

Computational methods for exploring protein conformations

Jane R. Allison2020-08-05Biochemical Society Transactions

Proteins are dynamic molecules that can transition between a potentially wide range of structures comprising their conformational ensemble. The nature of these conformations and their relative probabilities are described by a high-dimensional free energy landscape. While computer simulation techniques such as molecula…

Protein Structure and DynamicsMass Spectrometry Techniques and ApplicationsEnzyme Structure and Function

The Rotenone Models Reproducing Central and Peripheral Features of Parkinson’s Disease

Ikuko Miyazaki、Masato Asanuma2020-08-05NeuroSci

Parkinson’s disease (PD) is a complex, multi-system, neurodegenerative disorder; PD patients exhibit motor symptoms (such as akinesia/bradykinesia, tremor, rigidity, and postural instability) due to a loss of nigrostriatal dopaminergic neurons, and non-motor symptoms such as hyposmia, autonomic disturbance, depression…

Parkinson's Disease Mechanisms and TreatmentsNerve injury and regenerationConducting polymers and applications

The Na⋅⋅⋅B Bond in NaBH3−: A Different Type of Bond

Cina Foroutan‐Nejad2020-08-05Angewandte Chemie International Edition

Abstract A newly introduced Na−B bond in NaBH3−has been a challenge for the chemical bonding community. Here, a series of MBH3−(M=Li, Na, K) species and NaB(CN)3−are studied within the context of quantum chemical topology approaches. The analyses suggest that M–B interaction cannot be classified as an ordinary covalen…

Crystallography and molecular interactionsHydrogen Storage and MaterialsInorganic Fluorides and Related Compounds

Characterization and potential applications of different powder volcanic ash

Shoroog Alraddadi、Hasan Assaedi2020-08-05Journal of King Saud University - Science

In this study, the crystalline phase, microstructure, chemical composition, and morphology of the powder of volcanic ashes from three different places have been investigated. The raw materials were initially milled and the particle size was decreased to approximately 74 µm. X-ray diffraction (XRD), chemical analysis (…

Recycling and utilization of industrial and municipal waste in materials productionClay minerals and soil interactionsCoal and Its By-products

Ultrathin porous graphitic carbon nanosheets activated by alkali metal salts for high power density lithium‐ion capacitors

Yuqing Dai、Guangchao Li、Xinhai Li 等 7 位作者2020-08-05Rare Metals

Abstract Graphitic carbons with reasonable pore volume and appropriate graphitization degree can provide efficient Li + /electrolyte‐transfer channels and ameliorate the sluggish dynamic behavior of battery‐type carbon negative electrode in lithium‐ion capacitors (LICs). In this work, onion‐like graphitic carbon mater…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Preparation and Evaluation of Intraperitoneal Long-Acting Oxaliplatin-Loaded Multi-Vesicular Liposomal Depot for Colorectal Cancer Treatment

S. ABUZAR、Eun Jung Park、Yeji Seo 等 6 位作者2020-08-05Pharmaceutics

Colorectal cancer with peritoneal metastasis has a poor prognosis because of inadequate responses to systemic chemotherapy. Cytoreductive surgery followed by intraperitoneal (IP) chemotherapy using oxaliplatin has attracted attention; however, the short half-life of oxaliplatin and its rapid clearance from the periton…

Nanoparticle-Based Drug DeliveryHernia repair and managementIntraperitoneal and Appendiceal Malignancies

CO 2 Reforming of Methane over a Highly Dispersed Ni/Mg–Al–O Catalyst Prepared by a Facile and Green Method

Yu Guo、Yifan Li、Yanxiao Ning 等 8 位作者2020-08-05Industrial & Engineering Chemistry Research

A novel Ni/Mg–Al–O catalyst has been successfully synthesized by the cation–anion double hydrolysis (CADH) method for carbon dioxide (CO 2 ) reforming of methane. Compared with the Ni/MgO–Al 2 O 3 catalyst prepared by the conventional co-impregnation method, the Ni/Mg–Al–O catalyst exhibited enhanced initial activity…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis for Biomass Conversion

Phosphorus‐Based Electrocatalysts: Black Phosphorus, Metal Phosphides, and Phosphates

Xin Li、John Wang2020-08-05Advanced Materials Interfaces

Abstract Enormous progresses have been made in developing advanced energy conversion and storage technologies, which inevitably require high‐performance electrocatalysts. Recently, phosphorus (P)‐based materials have drawn tremendous attention as a class of promising electrocatalysts and presented intrinsic electroche…

Electrocatalysts for Energy ConversionAdvanced Photocatalysis TechniquesMXene and MAX Phase Materials

Grating coupled SPR sensors using off the shelf compact discs and sensitivity dependence on grating period

Siqi Long、Jianjun Cao、Yueke Wang 等 7 位作者2020-08-05Sensors and Actuators Reports

Grating coupled surface plasmon resonance (GCSPR) sensors with wavelength modulation are widely used in many fields, but the low sensitivity holds their practical applications. Here we theoretically analyze the sensitivity limit of GCSPR sensors, provide design methods to reach the maximum sensitivity and the way to i…

Plasmonic and Surface Plasmon ResearchPhotonic and Optical DevicesOptical Coatings and Gratings

Stabilizing Atomically Dispersed Catalytic Sites on Tellurium Nanosheets with Strong Metal–Support Interaction Boosts Photocatalysis

Li Shi、Xiaohui Ren、Qi Wang 等 11 位作者2020-08-05Small

Abstract The utilization of appropriate supports for constructing single‐atom‐catalysts is of vital importance to achieve high catalytic performances, as the strong mutual interactions between the atomically dispersed metal atoms and supports significantly influence their electronic properties. Herein, it is reported…

Electrocatalysts for Energy ConversionAdvanced Photocatalysis TechniquesCatalytic Processes in Materials Science

Learning reaction coordinates via cross-entropy minimization: Application to alanine dipeptide

Yusuke Mori、Kei-ichi Okazaki、Toshifumi Mori 等 5 位作者2020-08-05The Journal of Chemical Physics

We propose a cross-entropy minimization method for finding the reaction coordinate from a large number of collective variables in complex molecular systems. This method is an extension of the likelihood maximization approach describing the committor function with a sigmoid. By design, the reaction coordinate as a func…

Protein Structure and DynamicsComputational Drug Discovery MethodsMachine Learning in Materials Science

Synergistic Adsorption Mechanism of Anionic and Cationic Surfactant Mixtures on Low-Rank Coal Flotation

Rui Zhang、Yaowen Xing、Yangchao Xia 等 9 位作者2020-08-05ACS Omega

Mixed surfactants have a prominent synergistic effect and show advantages in many aspects. In this work, the effects of a mixture of dodecyltrimethylammonium bromide (DTAB) and sodium dodecyl sulfate (SDS) on the flotation of low-rank coal were studied from the wetting rate, contact angle, surface tension, and zeta po…

Minerals Flotation and Separation TechniquesIron oxide chemistry and applicationsPickering emulsions and particle stabilization

Bound States in the Continuum in the Visible Emerging from out-of-Plane Magnetic Dipoles

Shunsuke Murai、Diego R. Abujetas、Gabriel W. Castellanos 等 6 位作者2020-08-05ACS Photonics

Bound states in the continuum (BICs) are electromagnetic modes with a dispersion inside the light cone and infinite lifetimes. This exceptional property has led to intensive research and the demonstration of BICs in the gigahertz, teraherz, and near-infrared, up to the visible region. In this study, we design and expe…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic and Optical Devices

State-of-the-Art Electrode Materials for Sodium-Ion Batteries

A. Mauger、C. Julien2020-08-05Materials

Sodium-ion batteries (SIBs) were investigated as recently as in the seventies. However, they have been overshadowed for decades, due to the success of lithium-ion batteries that demonstrated higher energy densities and longer cycle lives. Since then, the witness a re-emergence of the SIBs and renewed interest evidence…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

3D Reduced Graphene Oxide Scaffolds with a Combinatorial Fibrous-Porous Architecture for Neural Tissue Engineering

André F. Girão、Joana P.M. Sousa、Ana Lucía Dominguez 等 12 位作者2020-08-05ACS Applied Materials & Interfaces

Graphene oxide (GO) assists a diverse set of promising routes to build bioactive neural microenvironments by easily interacting with other biomaterials to enhance their bulk features or, alternatively, self-assembling toward the construction of biocompatible systems with specific three-dimensional (3D) geometries. Her…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsGraphene and Nanomaterials Applications

Positively Charged Polysulfonamide Nanocomposite Membranes Incorporating Hydrophilic Triazine-Structured COFs for Highly Efficient Nanofiltration

Heyun Wang、Hao Wang、Haoji Jiang 等 8 位作者2020-08-05ACS Applied Nano Materials

Abstract Although covalent organic frameworks (COFs) have attracted extensive attention in recent years due to their unique advantages, the use of triazine-structured COFs in the nanofiltration (NF) membrane separation processes for acid wastewater containing heavy metal ions has not been explored. We selected hydroph…

Membrane Separation TechnologiesMembrane Separation and Gas TransportCovalent Organic Framework Applications