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Etch selectivity during plasma-assisted etching of SiO2 and SiNx: Transitioning from reactive ion etching to atomic layer etching

Ryan J. Gasvoda、Zhonghao Zhang、Scott Wang 等 5 位作者2020-08-04Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Continued downscaling of semiconductor devices has placed stringent constraints on all aspects of the fabrication process including plasma-assisted anisotropic etching. To address manufacturing challenges associated with atomic-scale control, material selectivity, etch fidelity, and increasingly complex device archite…

Semiconductor materials and devicesPlasma Diagnostics and ApplicationsElectronic and Structural Properties of Oxides

Ethylene Dehydroaromatization over Ga‐ZSM‐5 Catalysts: Nature and Role of Gallium Speciation

Yunwen Zhou、Hari Thirumalai、Scott K. Smith 等 8 位作者2020-08-04Angewandte Chemie International Edition

Bifunctional catalysis in zeolites possessing both Brønsted and Lewis acid sites offers unique opportunities to tailor shape selectivity and enhance catalyst performance. Here, we examine the impact of framework and extra-framework gallium species on enriched aromatics production in zeolite ZSM-5. We compare three dis…

Metal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials ScienceZeolite Catalysis and Synthesis

Moisture Diagnosis of Transformer Oil-Immersed Insulation With Intelligent Technique and Frequency-Domain Spectroscopy

Jiefeng Liu、Xianhao Fan、Chaohai Zhang 等 8 位作者2020-08-04IEEE Transactions on Industrial Informatics

Moisture is one of the critical factors to determine the service life of transformers. The moisture inside the transformer oil-immersed insulation could be quantified with feature parameters. This article proposes and develops a genetic algorithm support vector machine (GA-SVM) model to carry out the moisture diagnosi…

High voltage insulation and dielectric phenomenaPower Quality and HarmonicsPower Transformer Diagnostics and Insulation

On the Factors Governing Austenite Stability: Intrinsic versus Extrinsic

Binbin He2020-08-04Materials

In this review, we separate the different governing factors on austenite stability into intrinsic and extrinsic factors, depending on the domain defined by austenite grain boundaries. The different measuring techniques on the effectiveness of the governing factors in affecting the austenite stability are discussed. On…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Understanding the Degradation of Spiro‐OMeTAD‐Based Perovskite Solar Cells at High Temperature

Ganbaatar Tumen‐Ulzii、Chuanjiang Qin、Toshinori Matsushima 等 7 位作者2020-08-04Solar RRL

Organic–inorganic halide perovskites are promising as the light absorber of solar cells because of their efficient solar power conversion. An issue frequently occurring in perovskite solar cells (PSCs) with a hole transport layer of N,N ‐di(4‐methoxyphenyl)amino]‐9,9′‐spirobifluorene (spiro‐OMeTAD) is a quick performa…

Perovskite Materials and ApplicationsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Highly Enhanced Full Solar Spectrum‐Driven Photocatalytic CO2 Reduction Performance in Cu2–xS/g‐C3N4 Composite: Efficient Charge Transfer and Mechanism Insight

Lisha Jiang、Kai Wang、Xiaoyong Wu 等 4 位作者2020-08-04Solar RRL

An efficient full solar spectrum ultraviolet–visible–near infrared (UV–vis–NIR) light‐driven Cu2–xS/g‐C3N4 composite photocatalyst is reported, which is fabricated by a facile solvothermal process for CO2 photoreduction into CO and CH4, as confirmed by product analysis and 13C isotopic test. The composite exhibits sup…

Advanced Photocatalysis TechniquesCO2 Reduction Techniques and CatalystsElectronic and Structural Properties of Oxides

Electrochemical Production of Sustainable Hydrocarbon Fuels from CO 2 Co-electrolysis in Eutectic Molten Melts

Ossama Al-Juboori、Farooq Sher、Ushna Khalid 等 5 位作者2020-08-04ACS Sustainable Chemistry & Engineering

Because of the heavy reliance of people on limited fossil fuels as energy resources, global warming has increased to severe levels because of huge CO 2 emission into the atmosphere. To mitigate this situation, a green method is presented here for the conversion of CO 2 /H 2 O into sustainable hydrocarbon fuels via ele…

Advancements in Solid Oxide Fuel CellsChemical Looping and Thermochemical ProcessesMolten salt chemistry and electrochemical processes

Search for non-Abelian Majorana braiding statistics in superconductors

Carlo Beenakker2020-08-04SciPost Physics Lecture Notes

This is a tutorial review of methods to braid non-Abelian anyons (Majorana zero-modes) in topological superconductors. That ``Holy Grail'' of topological quantum information processing has not yet been reached in the laboratory, but there now exists a variety of platforms in which one can search for the Majorana braid…

Topological Materials and PhenomenaQuantum Mechanics and Non-Hermitian PhysicsChemical and Physical Properties of Materials

Narrow-Bandgap Mixed Lead/Tin-Based 2D Dion–Jacobson Perovskites Boost the Performance of Solar Cells

Weijun Ke、Cong Chen、Ioannis Spanopoulos 等 10 位作者2020-08-04Journal of the American Chemical Society

The advent of the two-dimensional (2D) family of halide perovskites and their demonstration in 2D/three-dimensional (3D) hierarchical film structures broke new ground toward high device performance and good stability. The 2D Dion–Jacobson (DJ) phase halide perovskites are especially attractive in solar cells because o…

Perovskite Materials and ApplicationsConducting polymers and applications

Raising the COx Methanation Activity of a Ru/γ‐Al2O3 Catalyst by Activated Modification of Metal–Support Interactions

Shilong Chen、Ali M. Abdel‐Mageed、Michael Dyballa 等 9 位作者2020-08-04Angewandte Chemie International Edition

Abstract Ru/Al2O3 is a highly stable, but less active catalyst for methanation reactions. Herein we report an effective approach to significantly improve its performance in the methanation of CO2/H2 mixtures. Highly active and stable Ru/γ‐Al2O3 catalysts were prepared by high‐temperature treatment in the reductive rea…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCarbon dioxide utilization in catalysis

Rational Design of Triplet Sensitizers for the Transfer of Excited State Photochemistry from UV to Visible

Luke D. Elliott、Surajit Kayal、Michael W. George 等 4 位作者2020-08-04Journal of the American Chemical Society

Time Dependent Density Functional Theory has been used to assist the design and synthesis of a series thioxanthone triplet sensitizers. Calculated energies of the triplet excited state ( E T ) informed both the type and position of auxochromes placed on the thioxanthone core, enabling fine-tuning of the UV–vis absorpt…

Radical Photochemical ReactionsPhotochromic and Fluorescence ChemistryOxidative Organic Chemistry Reactions

Organic Photovoltaic Cells for Indoor Applications: Opportunities and Challenges

Yong Cui、Ling Hong、Jianhui Hou2020-08-04ACS Applied Materials & Interfaces

With the growing development of the Internet of Things, organic photovoltaic (OPV) cells are highly desirable for indoor applications because of the unique features of light weight, flexibility, and coloration. Emission spectra of the commonly used indoor light sources are much narrower with lower light intensity as c…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Identifying the nature of the active sites in methanol synthesis over Cu/ZnO/Al2O3 catalysts

Daniel Laudenschleger、Holger Ruland、Martin Muhler2020-08-04Nature Communications

Abstract The heterogeneously catalysed reaction of hydrogen with carbon monoxide and carbon dioxide (syngas) to methanol is nearly 100 years old, and the standard methanol catalyst Cu/ZnO/Al 2 O 3 has been applied for more than 50 years. Still, the nature of the Zn species on the metallic Cu 0 particles (interface sit…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCO2 Reduction Techniques and Catalysts

State-of-the-Art Review of Microbial-Induced Calcite Precipitation and Its Sustainability in Engineering Applications

Md Mizanur Rahman、Reena N. Hora、Isaac Ahenkorah 等 6 位作者2020-08-04Sustainability

Microbial-induced calcite precipitation (MICP) is a promising new technology in the area of Civil Engineering with potential to become a cost-effective, environmentally friendly and sustainable solution to many problems such as ground improvement, liquefaction remediation, enhancing properties of concrete and so forth…

Corrosion Behavior and InhibitionMicrobial Applications in Construction MaterialsGrouting, Rheology, and Soil Mechanics

Bifunctional Surface Engineering on SnO2 Reduces Energy Loss in Perovskite Solar Cells

Eui Hyuk Jung、Bin Chen、Koen Bertens 等 10 位作者2020-08-04ACS Energy Letters

Tin oxide (SnO 2 ) has recently emerged as a promising electron transport layer for perovskite solar cells (PSCs) in light of the material’s optical and electronic properties and its low-temperature processing. However, SnO 2 films are prone to surface defect formation, which results in energy loss in PSCs. We report…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Efficient Lone-Pair-Driven Luminescence: Structure?Property Relationships in Emissive 5s2 Metal Halides

Kyle M. McCall、Viktoriia Morad、Bogdan M. Benin 等 4 位作者2020-08-04ACS Materials Letters

Abstract Low-dimensional metal halides have been the focus of intense investigations in recent years following the success of hybrid lead halide perovskites as optoelectronic materials. In particular, the light emission of low-dimensional halides based on the 5s2 cations Sn2+ and Sb3+ has found utility in a variety of…

Perovskite Materials and Applications2D Materials and ApplicationsSolid-state spectroscopy and crystallography

Plasmonic nanowire coupled to zero-dimensional nanostructures: A brief review

Sunny Tiwari、Chetna Taneja、G. V. Pavan Kumar2020-08-04arXiv (Cornell University)

Metal nanowires and nanoparticles that facilitate surface plasmons are of contemporary interest in nanophotonics, thermoplasmonics and optoelectronics. They facilitate not only subwavelength light propagation and localization capabilities, but also provide an excellent platform for opto-thermal effects confined to vol…

Gold and Silver Nanoparticles Synthesis and ApplicationsMetamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon Research

Decentralized PID Controller Design for SOFC-GT

Tooran Emami、Alex Tsai、David Tucker2020-08-04OpenAlex

Abstract This paper presents a performance of a 300 kW Solid Oxide Fuel Cell Gas Turbine (SOFC-GT) pilot power plant simulator under an area of selection of the Proportional Integral Derivative (PID) controller coefficients that satisfies the stability, gain and phase margins. The performance of turbine speed and the…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Analysis Crystal Structure of La0.7Ba(1-xSrx)0.3MnO3 by Sol-Gel Method

Juli Hartati、Sitti Ahmiatri Saptari、Arif Tjahjono2020-08-04Al-Fiziya Journal of Materials Science Geophysics Instrumentation and Theoretical Physics

Abstrak.Penelitian tentang struktur kristal bahan La0.7(Ba1-xSrx)MnO3 menggunakan metode sol-gel telah berhasil dilakukan. Bahan-bahan dasar yang digunakan dicampur di atas hot plate diaduk sambil ditetesi ammonia solution sehingga mencapai pH 7, selanjutnya didiamkan sampai diperoleh bentuk gel. Gel dikeringkan pada…

Magnetic and transport properties of perovskites and related materialsX-ray Diffraction in Crystallography

Evaluation of Transition Temperature in Reactor Pressure Vessel Steels 6using the Fracture Energy Transition Curve from a Small Punch Test

Taekyung Lee、Seokmin Hong、Jongmin Kim 等 5 位作者2020-08-04대한금속재료학회지

The small punch (SP) test is one of the small specimen test techniques, and standardization of the SP test method for evaluating the mechanical properties of metallic materials is in progress. In this study, the impact transition temperature of reactor pressure vessel steels (RPV) in nuclear power plants was estimated…

Fatigue and fracture mechanicsFusion materials and technologiesNuclear Materials and Properties