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Sustainable Materials and Chemical Processes for Additive Manufacturing

Eva Sanchez‐Rexach、Trevor G. Johnston、Coralie Jehanno 等 5 位作者2020-08-03Chemistry of Materials

Additive manufacturing (AM) is energizing the fields of chemistry and materials science to develop new inks for new applications within fields such as aerospace, robotics, and healthcare. AM enables the fabrication of innumerable 3D geometries that cannot be easily produced by other means. In spite of the great promis…

biodegradable polymer synthesis and propertiesAdditive Manufacturing and 3D Printing Technologies3D Printing in Biomedical Research

Single Atoms of Iron on MoS2 Nanosheets for N2 Electroreduction into Ammonia

Hongyang Su、Lanlan Chen、Yizhen Chen 等 9 位作者2020-08-03Angewandte Chemie International Edition

Abstract Efforts have been devoted to achieving a highly efficient artificial synthesis of ammonia (NH3). Reported herein is a novel Fe‐MoS2 catalyst with Fe atomically dispersed onto MoS2 nanosheets, imitating natural nitrogenase, to boost N2 electroreduction into NH3 at room temperature. The Fe‐MoS2 nanosheets exhib…

Catalytic Processes in Materials ScienceAmmonia Synthesis and Nitrogen ReductionNanomaterials for catalytic reactions

SERS‐Active MIL‐100(Fe) Sensory Array for Ultrasensitive and Multiplex Detection of VOCs

Jinghao Fu、Zhen Zhong、Dan Xie 等 10 位作者2020-08-03Angewandte Chemie International Edition

Abstract The application of metal–organic frameworks (MOFs) as SERS‐active platforms in multiplex volatile organic compounds (VOCs) detection is still unexplored. Herein, we demonstrate that MIL‐100 (Fe) serves as an ideal SERS substrate for the detection of VOCs. The limit of detection (LOD) of MIL‐100(Fe) for toluen…

Gold and Silver Nanoparticles Synthesis and ApplicationsGas Sensing Nanomaterials and SensorsAdvanced Chemical Sensor Technologies

Adding a Third Component with Reduced Miscibility and Higher LUMO Level Enables Efficient Ternary Organic Solar Cells

Ruijie Ma、Tao Liu、Zhenghui Luo 等 20 位作者2020-08-03ACS Energy Letters

It is widely known that the miscibility between donor and acceptor is a crucial factor that affects the morphology and thus device performance of nonfullerene organic solar cells (OSCs). In this Letter, we show that incorporating a third component with lower miscibility and higher lowest unoccupied molecular orbital (…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Recent Advances in Cs2AgBiBr6‑Based Halide Double Perovskites as Lead-Free and Inorganic Light Absorbers for Perovskite Solar Cells

Xiaoqing Yang、Wei Wang、Ran Ran 等 5 位作者2020-08-03Energy & Fuels

Abstract Although lead-based inorganic–organic perovskite solar cells (PSCs) have delivered the highest power conversion efficiency (PCE) to date of 25.2%, the toxic nature of lead and poor stability are the biggest hurdles for the commercialization of PSCs. Lead-free halide double perovskite Cs2AgBiBr6 has received i…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesConducting polymers and applications

Fracture Toughness Tests on Western RPV Steels Using Small Scale Specimen Technique

Florian Obermeier、E. Altstadt、Hieronymus Hein 等 4 位作者2020-08-03OpenAlex

Abstract In order to ensure continued safe operation of European nuclear reactors, it is necessary to solve specific issues that arise from irradiation induced reactor pressure vessel (RPV) embrittlement under long term operation. This requires an extension of the RPV surveillance programs to cover longer operation ti…

Fatigue and fracture mechanicsNuclear Materials and PropertiesNuclear and radioactivity studies

Correlation Between Thermal Desorption Spectrum Features and Creep Damage

Yu Zhou、Zhichao Fan、Xuedong Chen 等 6 位作者2020-08-03OpenAlex

Abstract The analysis of the spectrum features of thermal desorption spectroscopy (TDS) using the desorption-rate profile against temperature is widely applied to investigate the hydrogen kinetics including diffusion and trapping in metallic materials, which is related to hydrogen embrittlement. Recently the TDS spect…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsMaterial Properties and Failure Mechanisms

High Flux Reactor Continued Safe Operation: Time Limited Ageing Analyses

L. Stefanini、F. Wilde2020-08-03OpenAlex

Abstract The High Flux Reactor (HFR) is a multipurpose nuclear reactor located in Petten, the Netherlands. With its 45 MWth it is one of the most powerful and versatile research reactors in the world. Its main roles are material irradiation and medical isotopes production. The output of the reactor in terms of medical…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesGraphite, nuclear technology, radiation studies

Alloying Effect of Silver on Zirconia Support Manipulated Palladium Catalyst for Methane Combustion

Mengmeng Chu、Fan Cai、Xiaohong Cao 等 7 位作者2020-08-03Catalysts

PdAg/ZrO2 alloy catalysts calcined at different temperatures were employed to elucidate the effect of support-metal interaction (SMI) on methane combustion. Combustion activity was depressed when the sample was calcined at an elevated temperature from 500 °C to 700 °C. However, calcination at 850 °C enhanced the benef…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Fatigue Assessment of Dented Pipeline Specimens

J. L. F. Freire、V. E. L. Paiva、G. L. G. Gonzáles 等 7 位作者2020-08-03Volume 1: Codes and Standards

Abstract This paper reports results from an investigation program launched with the objective of assessing fatigue lives of actual pipeline specimens with dents. Nine pipeline 3m-length specimens were constructed with low carbon steel pipes API 5L Gr. B. The specimens had 323mm diameter and 6.35mm wall thickness. The…

Fatigue and fracture mechanicsHydrogen embrittlement and corrosion behaviors in metalsStructural Integrity and Reliability Analysis

Rubber-ceramic composites applicable in flexible antennas

Abdullah G. Al‐Sehemi、Ahmed A. Al‐Ghamdi、Nikolay Dishovsky 等 8 位作者2020-08-03Journal of Polymer Engineering

Abstract Glass ceramics from the CaO–P2O5–SiO2 system were synthesized. They were characterized by XRD, SEM and EDX methods. It was found that they contain two crystalline [Whitlockite, Ca3 (PO4)2 and Hydroxylapatite, Ca5 (PO4)3 (OH)] and one residual amorphous phase. The ceramics are composed of porous aggregates of…

Ferroelectric and Piezoelectric MaterialsDielectric materials and actuatorsMicrowave Dielectric Ceramics Synthesis

Enhancing the Activity and Stability of CuO/OMS-2 Catalyst for CO Oxidation at Low Temperature by Modification with Metal Oxides

Nguyễn Nhật Huy、Bích Thảo Nguyễn Thị、Thao Giang Nguyen Le 等 7 位作者2020-08-03International Journal of Chemical Engineering

In this study, mixed oxides of Mn-Cu and Fe-Cu on OMS-2 support having an octahedral structure were synthesized by the refluxing and impregnation methods. The characteristics of the materials were analyzed by XRD, FTIR, SEM, EDX, and H2-TPR. In the CO oxidation test, CuFeOx/OMS-2 had slightly higher catalytic activity…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsCopper-based nanomaterials and applications

INCEFA-PLUS Project: Review of the Test Programme

Matthias Bruchhausen、Alec McLennan、R. Cicero 等 7 位作者2020-08-03Volume 1: Codes and Standards

Abstract The European Project INCEFA-PLUS (INcreasing Safety in NPPs by Covering gaps in Environmental Fatigue Assessment) characterizes environmentally assisted fatigue of stainless steels in light water reactor environments. The project includes a major test programme during which more than 200 fatigue tests have be…

Fatigue and fracture mechanicsFusion materials and technologiesGraphite, nuclear technology, radiation studies

Evaluation of Material Compatibility for Hydrogen Applications Using Performance Factors Obtained by In-Situ SP Test

Hyung-Seop Shin、Juho Yeo、Nick Anthony V. Custodio 等 5 位作者2020-08-03OpenAlex

Abstract Recently, a simple screening technique based on the quantitative evaluation of the hydrogen embrittlement (HE) sensitivity of the metallic materials using an in-situ small-punch (SP) test method was developed by the author group. The in-situ SP test can be easily carried out even under a high-pressure hydroge…

Fatigue and fracture mechanicsHydrogen embrittlement and corrosion behaviors in metalsHigh Temperature Alloys and Creep

Effective aspect ratio of helices in shear flow

Brian Rost、Justin T. Stimatze、David A. Egolf 等 4 位作者2020-08-03Physical review. E

We report the results of simulations of rigid colloidal helices suspended in a shear flow, using dissipative particle dynamics for a coarse-grained representation of the suspending fluid, as well as deterministic trajectories of non-Brownian helices calculated from the resistance tensor derived under the slender-body…

Material Dynamics and PropertiesRheology and Fluid Dynamics StudiesPickering emulsions and particle stabilization

Diatoms constrain forensic burial timelines: case study with DB Cooper money

Thomas G. Kaye、Mark Meltzer2020-08-03Scientific Reports

Diatoms are found universally in waters around the world. Some diatom species such as Asterionella formosa have a broad variation in seasonal abundance leading to the possibility that diatoms could constrain the time of year when an object was immersed in water. Here we apply this technique to the cold case of DB Coop…

Geology and Paleoclimatology ResearchMarine Biology and Ecology ResearchDiatoms and Algae Research

Superhydrophobic Hair-Like Nanowire Membrane for the Highly Efficient Separation of Oil/Water Mixtures

Xinzuo Fang、Yufan Liu、Sheng Lei 等 4 位作者2020-08-03Journal of Nanomaterials

Water pollution caused by oil leakage and oily wastewater has become a serious environmental problem. Therefore, it is important to develop an efficient material to remove oil from water. Given the cost and efficiency, the membrane with superhydrophobicity is the most used material for the separation of oil/water mixt…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Aroma Finishing and Pigment Printing of Thai Silk Fabric by 1-Step All-In Printing Process

Jantip Setthayanond、Phussadee Lim2020-08-03Materials science forum

In this study, a combined aroma finishing and pigment printing process was investigated in order to develop 1-step, all-in aroma finishing/pigment printing process for Thai silk. Lemongrass oil microcapsules, an aroma finishing agent, was applied on silk by screen printing process and the properties of the printed fab…

Skin Protection and AgingDyeing and Modifying Textile FibersSilk-based biomaterials and applications

Effects of Strain and Kinetics on the H2O2-Assisted Reconstruction of Ag?Au?Ag Nanorods

Hui Hao、Yinliang Yang、Yinliang Yang 等 9 位作者2020-08-03Langmuir

Abstract Morphology of Ag nanocrystals (NCs) is essential to the NC application in catalysis, optics, and as antibacterial agents. Therefore, it is important to develop synthetic methods and understand the evaluation of NC morphology in different chemical environments. In this study, we report interesting findings of…

ZnO doping and propertiesGold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applications

Fracture Toughness Characterization in the Transition and Ductile Regime of an A508 Type Weld Metal With the Mini-CT Geometry Before and After Irradiation

M. Lambrecht、Rachid Chaouadi、I. Uytdenhouwen 等 4 位作者2020-08-03Volume 1: Codes and Standards

Abstract The mini-CT geometry is being adopted worldwide for application to measure the fracture toughness properties. This geometry is particularly adapted for irradiated materials given the limited space available for irradiation in high flux material test reactors such as the BR2 reactor. A series of twenty (20) mi…

Fatigue and fracture mechanicsFusion materials and technologiesNon-Destructive Testing Techniques