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Guest Transition Metals in Host Inorganic Nanocapsules: Single Sites, Discrete Electron Transfer, and Atomic Scale Structure

Eynat Haviv、Bo Chen、Raanan Carmieli 等 8 位作者2020-08-03Journal of the American Chemical Society

Abstract Host?guest solution chemistry with a wide range of organic hosts is an important and established research area, while the use of inorganic hosts is a more nascent area of research. In the recent past in a few cases, Keplerate-type molybdenum oxide-based porous, spherical clusters, shorthand notation {Mo132},…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications

Low-Voltage, Dual-Gate Organic Transistors with High Sensitivity and Stability toward Electrostatic Biosensing

Mark Nikolka、Dimitrios Simatos、Amir M. Foudeh 等 6 位作者2020-08-03ACS Applied Materials & Interfaces

High levels of performance and stability have been demonstrated for conjugated polymer thin-film transistors in recent years, making them promising materials for flexible electronic circuits and displays. For sensing applications, however, most research efforts have been focusing on electrochemical sensing devices. He…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Propyne Hydrogenation over a Pd/Cu(111) Single-Atom Alloy Studied using Ambient Pressure Infrared Spectroscopy

Mohammed K. Abdel‐Rahman、Michael Trenary2020-08-03ACS Catalysis

The hydrogenation of propyne (C 3 H 4 ) to propene (C 3 H 6 ) using a Pd/Cu(111) single-atom alloy (SAA) has been studied using polarization-dependent reflection absorption infrared spectroscopy. This method allows for simultaneous monitoring of reactants and products in the gas phase and species adsorbed on the surfa…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysts for Methane Reforming

Resistance to serine in Bacillus subtilis : identification of the serine transporter YbeC and of a metabolic network that links serine and threonine metabolism

Anika Klewing、Byoung‐Mo Koo、Larissa Krüger 等 8 位作者2020-08-03Environmental Microbiology

The Gram-positive bacterium Bacillus subtilis uses serine not only as a building block for proteins but also as an important precursor in many anabolic reactions. Moreover, a lack of serine results in the initiation of biofilm formation. However, excess serine inhibits the growth of B. subtilis. To unravel the underly…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismBiochemical and Molecular Research

K2Sb(P2O7)F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance

Yalan Deng、Ling Huang、Xuehua Dong 等 8 位作者2020-08-03Angewandte Chemie

Abstract Discovering new functional genes, designing perfect crystal structures, and developing high‐performance materials are the goals being pursued by scientists. Herein, the first antimony pyrophosphate, K2Sb(P2O7)F, possessing an optimal layered structure, is reported, where the perfect structural arrangement ind…

Luminescence Properties of Advanced MaterialsHigh-pressure geophysics and materialsCrystal Structures and Properties

Leakage Current Reduction in β-Ga 2 O 3 Schottky Barrier Diodes by CF 4 Plasma Treatment

Haoxun Luo、Huaxing Jiang、Zimin Chen 等 9 位作者2020-08-03IEEE Electron Device Letters

This letter reports on the suppression of reverse leakage current (Ir) in β-Ga2O3Schottky barrier diodes (SBDs) through Schottky barrier modification by a low power CF4-plasma treatment prior to Schottky metal deposition. Revealed by an X-ray photoelectron spectroscopy (XPS) analysis, the fluorine-plasma treatment bro…

ZnO doping and propertiesGa2O3 and related materialsElectronic and Structural Properties of Oxides

Preparation, characterization and antimicrobial activity evaluation of electrospun PCL nanofiber composites of resveratrol nanocrystals

Alptuğ Karaküçük、Serdar Tort2020-08-03Pharmaceutical Development and Technology

The objective of this study was to develop resveratrol nanocrystals to solve low water solubility issues of resveratrol and adsorb them to the polycaprolactone nanofibers. Nanocrystals were prepared by microfluidization. Particle size, polydispersity index and zeta potential values were evaluated as dependent variable…

Nerve injury and regenerationElectrospun Nanofibers in Biomedical ApplicationsSirtuins and Resveratrol in Medicine

Microscopic pairing mechanism, order parameter, and disorder sensitivity in moiré superlattices: Applications to twisted double-bilayer graphene

Rhine Samajdar、Mathias S. Scheurer2020-08-03Physical review. B./Physical review. B

Starting from a continuum-model description, we develop a microscopic weak-coupling theory for superconductivity in twisted double-bilayer graphene. We study both electron-phonon and entirely electronic pairing mechanisms. In each case, the leading superconducting instability transforms under the trivial representatio…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Area and thickness dependence of Auger recombination in nanoplatelets

John P. Philbin、Alexandra Brumberg、Benjamin T. Diroll 等 7 位作者2020-08-03The Journal of Chemical Physics

The ability to control both the thickness and the lateral dimensions of colloidal nanoplatelets offers a test-bed for area and thickness dependent properties in 2D materials. An important example is Auger recombination, which is typically the dominant process by which multiexcitons decay in nanoplatelets. Herein, we u…

Quantum Dots Synthesis And PropertiesNonlinear Optical Materials ResearchNear-Field Optical Microscopy

Novel Carbon Quantum Dots/Silver Blended Polysulfone Membrane with Improved Properties and Enhanced Performance in Tartrazine Dye Removal

Jin Yee Gan、Woon Chan Chong、Lan Ching Sim 等 7 位作者2020-08-03Membranes

This study produced a novel polysulfone (PSF) membrane for dye removal using lemon-derived carbon quantum dots-grafted silver nanoparticles (Ag/CQDs) as membrane nanofiller. The preparation of CQDs was completed by undergoing hydrothermal treatment to carbonize the pulp-free lemon juice into CQD solution. The CQD solu…

Carbon and Quantum Dots ApplicationsAdvanced Nanomaterials in CatalysisGraphene and Nanomaterials Applications

Fe III 48 ‐Containing 96‐Tungsto‐16‐Phosphate: Synthesis, Structure, Magnetism and Electrochemistry

Joydeb Goura、Bassem S. Bassil、Jasleen K. Bindra 等 7 位作者2020-08-03Chemistry - A European Journal

Abstract The 48‐Fe III ‐containing 96‐tungsto‐16‐phosphate, [Fe III 48 (OH) 76 (H 2 O) 16 (HP 2 W 12 O 48 ) 8 ] 36− ( Fe 48 ), has been synthesized and structurally characterized. This polyanion comprises eight equivalent {Fe III 6 P 2 W 12 } units that are linked in an end‐on fashion forming a macrocyclic assembly th…

Magnetism in coordination complexesPolyoxometalates: Synthesis and ApplicationsMetalloenzymes and iron-sulfur proteins

Patterning a Superhydrophobic Area on a Facile Fabricated Superhydrophilic Layer Based on an Inkjet-Printed Water-Soluble Polymer Template

Jiazhen Sun、Yang Li、Guangping Liu 等 8 位作者2020-08-03Langmuir

An elaborated surface with a superhydrophilic area and a superhydrophobic area was fabricated by inkjet printing a water-soluble polymer template on a superhydrophilic layer. Titanate was used to generate the superhydrophilic layer with an in situ reaction. A water-soluble polymer template was inkjet printed on the fa…

Surface Modification and SuperhydrophobicityNanomaterials and Printing TechnologiesElectrohydrodynamics and Fluid Dynamics

Relaxivity of manganese ferrite nanoparticles

Joop A. Peters2020-08-03Progress in Nuclear Magnetic Resonance Spectroscopy

Manganese ferrite nanoparticles are superparamagnetic and have very high saturation magnetization, which makes them candidates for application as MRI contrast agents. Because these nanoparticles are very effective enhancers of transverse relaxation, they are particularly suitable as negative (T2-weighted) contrast age…

Nanoparticle-Based Drug DeliveryMagnetic Properties and Synthesis of FerritesCharacterization and Applications of Magnetic Nanoparticles

Structural and Thermoelectric Properties of Black Arsenic–Phosphorus

Bhupendra Karki、Manthila Rajapakse、Gamini Sumanasekera 等 4 位作者2020-08-03ACS Applied Energy Materials

Abstract Here, we report the structural and temperature-dependent transport properties of AsxP1–x (x = 0, 0.2, 0.5, 0.83, and 1) alloys. It is observed that black phosphorous-related phonon modes in the alloy samples are redshifted with increasing arsenic concentration, while black arsenic-related modes in these sampl…

2D Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesThermal properties of materials

A Hybrid of FeS2 Nanoparticles Encapsulated by Two-Dimensional Carbon Sheets as Excellent Nanozymes for Colorimetric Glucose Detection

Wei Ding、Haibo Liu、Weiwen Zhao 等 8 位作者2020-08-03ACS Applied Bio Materials

Recently, the development of nanozymes with high catalytic performance is gaining more and more attention due to the ever-growing demands for their practical applications. The elaborate design of its morphology has demonstrated to be an effective approach to improve the performance of these nanozymes. Herein, a hybrid…

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsAdvanced Nanomaterials in Catalysis

In-place molecular preservation of cellulose in 5,000-year-old archaeological textiles

Corentin Reynaud、Mathieu Thoury、Alexandre Dazzi 等 10 位作者2020-08-03Proceedings of the National Academy of Sciences

The understanding of fossilization mechanisms at the nanoscale remains extremely challenging despite its fundamental interest and its implications for paleontology, archaeology, geoscience, and environmental and material sciences. The mineralization mechanism by which cellulosic, keratinous, and silk tissues fossilize…

Advanced Cellulose Research StudiesCultural Heritage Materials AnalysisBuilding materials and conservation

Identification of excess charge carriers in InP-based quantum-dot light-emitting diodes

Qiang Su、Heng Zhang、Shuming Chen2020-08-03Applied Physics Letters

InP-based quantum-dot light-emitting diodes (QLEDs) have recently attracted a lot of attention from academia and industry owing to their environment-friendly characteristics and have been hotly investigated as promising alternatives to toxic CdSe-based QLEDs. Although the performances of InP-QLEDs have been rapidly im…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Enhanced Passivation and Carrier Collection in Ink-Processed PbS Quantum Dot Solar Cells via a Supplementary Ligand Strategy

Xiaokun Yang、Ji Yang、Muhammad Ullah 等 10 位作者2020-08-03ACS Applied Materials & Interfaces

Solution-processed semiconductors have opened promising avenues for next-generation semiconductor and optoelectronic industries. Colloidal quantum dots (QDs) as one of the most typical materials are widely utilized for the design and development of light-emitting diodes, photodetectors, and solar cells. Recently, an e…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Acoustic phonon recycling for photocarrier generation in graphene-WS2 heterostructures

Ke Wei、Yizhen Sui、Zhongjie Xu 等 12 位作者2020-08-03Nature Communications

Abstract Electron-phonon scattering is the key process limiting the efficiency of modern nanoelectronic and optoelectronic devices, in which most of the incident energy is converted to lattice heat and finally dissipates into the environment. Here, we report an acoustic phonon recycling process in graphene-WS 2 hetero…

Graphene research and applications2D Materials and ApplicationsThermal properties of materials

Accelerating Crystallization of Open Organic Materials by Poly(ionic liquid)s

Suyun Zhang、H. Miao、Hemin Zhang 等 9 位作者2020-08-03Angewandte Chemie International Edition

The capability to significantly shorten the synthetic period of a broad spectrum of open organic materials presents an enticing prospect for materials processing and applications. Herein we discovered 1,2,4-triazolium poly(ionic liquid)s (PILs) could serve as a universal additive to accelerate by at least one order of…

Metal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent MaterialsCovalent Organic Framework Applications