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A review of recent advances in water-gas shift catalysis for hydrogen production

Parisa Ebrahimi、Anand Kumar、Majeda Khraisheh2020-08-03Emergent Materials

Abstract The water-gas shift reaction (WGSR) is an intermediate reaction in hydrocarbon reforming processes, considered one of the most important reactions for hydrogen production. Here, water and carbon monoxide molecules react to generate hydrogen and carbon dioxide. From the thermodynamics aspect, pressure does not…

Catalysts for Methane ReformingCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

K 2 Sb(P 2 O 7 )F: Cairo Pentagonal Layer with Bifunctional Genes Reveal Optical Performance

Yalan Deng、Ling Huang、Xuehua Dong 等 8 位作者2020-08-03Angewandte Chemie International Edition

Abstract Discovering new functional genes, designing perfect crystal structures, and developing high‐performance materials are the goals being pursued by scientists. Herein, the first antimony pyrophosphate, K 2 Sb(P 2 O 7 )F, possessing an optimal layered structure, is reported, where the perfect structural arrangeme…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyHigh-pressure geophysics and materials

CCDC 1939114: Experimental Crystal Structure Determination

Victor P. Zelenov、Nikita М. Baraboshkin、Dmitry V. Khakimov 等 9 位作者2020-08-02The Cambridge Structural Database

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space grou…

Crystallography and molecular interactionsX-ray Diffraction in CrystallographyCrystallization and Solubility Studies

CCDC 808421: Experimental Crystal Structure Determination

In-Taek Lim、Ki‐Young Choi2020-08-02The Cambridge Structural Database

An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space grou…

Crystallization and Solubility StudiesX-ray Diffraction in Crystallography

Make MicroED an efficient tool for ultrahigh-resolution structural determination?

Xueming Li2020-08-02Acta Crystallographica Section A Foundations and Advances

Microcrystal electron diffraction (MicroED) is becoming a powerful tool in determining the crystal structures of biological macromolecules and small organic compounds. An advantage of electron diffraction is that its resolution is just weakly influenced by the performance of the objective lens. Therefore, even on a lo…

Mass Spectrometry Techniques and ApplicationsDiamond and Carbon-based Materials ResearchAnalytical chemistry methods development

An ultra-low magnetic field thermal demagnetizer for high-precision paleomagnetism

Huafeng Qin、Xiang Zhao、Shuangchi Liu 等 9 位作者2020-08-02Research Square

Abstract Thermal demagnetization furnaces are widely used paleomagnetic facilities for progressive removal of naturally acquired magnetic remanence or the imparting of well controlled laboratory magnetization. An ideal thermal demagnetizer should maintain “zero” magnetic field in the sample chamber during thermal trea…

High-pressure geophysics and materialsGeomagnetism and Paleomagnetism StudiesMagnetic Properties of Alloys

Wendlandia syringoides: Energy Development Corporation (EDC)

IUCN2020-08-02IUCN Red List of Threatened Species

Established in 1964, the IUCN Red List of Threatened Species has evolved to become the world’s most comprehensive information source on the global conservation status of animal, fungi and plant species.

Forest Biomass Utilization and ManagementMetallurgy and Material Science

Faculty Opinions recommendation of A reanalysis of nanoparticle tumor delivery using classical pharmacokinetic metrics.

Xiaoming He2020-08-02Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature

Nanoparticle (NP) delivery to solid tumors has recently been questioned. To better understand the magnitude of NP tumor delivery, we reanalyzed published murine NP tumor pharmacokinetic (PK) data used in the Wilhelm et al. study. Studies included in their analysis reporting matched tumor and blood concentration versus…

Nanoparticle-Based Drug DeliveryBiosimilars and Bioanalytical MethodsCancer Treatment and Pharmacology

Wendlandia nervosa: Energy Development Corporation (EDC)

IUCN2020-08-02IUCN Red List of Threatened Species

Established in 1964, the IUCN Red List of Threatened Species has evolved to become the world’s most comprehensive information source on the global conservation status of animal, fungi and plant species.

Bioenergy crop production and managementMetallurgy and Material ScienceForest Biomass Utilization and Management

Mass Attenuation Coefficient Measurements of Photoelectric Absorption of Gamma-Rays in Copper Using Coincidence Technique

Mahmoud A. Elawi2020-08-02Tikrit Journal of Pure Science

The photoelectric absorption mass attenuation coefficients (m.a.c.) of ɤ- rays in Cu are measured using a two 3"x3" NaI(Tl) detector coincidence spectrometer at 511, 1173 and 1332keV energy gates using Na-22 and Co-60 point sources. The m.a.c. (in cm²/g) measured by coincidence method were lower than those obtained fr…

Welding Techniques and Residual StressesNuclear Physics and ApplicationsElectron and X-Ray Spectroscopy Techniques

A Direct Comparison of Three Buckling-Based Methods to Measure the Elastic Modulus of Nanobiocomposite Thin Films

Taylor C. Stimpson、Daniel A. Osorio、Emily D. Cranston 等 4 位作者2020-08-02ChemRxiv

To engineer tunable thin film materials, accurate measurement of their mechanical properties is crucial. However, characterizing the elastic modulus with current methods is particularly challenging for sub-micrometer thick films and hygroscopic materials because they are highly sensitive to environmental conditions an…

Advanced Sensor and Energy Harvesting MaterialsAdvanced Cellulose Research StudiesAdvanced Materials and Mechanics

Observation of nine-fold coordinated amorphous TiO2 at high pressure

Yu Shu、Yoshio Kono、Guoyin Shen2020-08-02Acta Crystallographica Section A Foundations and Advances

Understanding pressure-induced structural changes in amorphous dioxides (a-AO2) is of great importance in many fields of science. Here we report new experimental results of high pressure polyamorphism in amorphous TiO2 (a-TiO2) with the Ti-O coordination number (CN) close to 9. Our experimental data show that CN incre…

High-pressure geophysics and materialsThermal and Kinetic AnalysisLuminescence Properties of Advanced Materials

Real-time pressure–temperature reaction studies of biological systems using small-angle neutron scattering technique

Sai Venkatesh Pingali、Loukas Petridis、Utsab R. Shrestha 等 6 位作者2020-08-02Acta Crystallographica Section A Foundations and Advances

Scientific experiments that require the need to use extreme sample environments are ideally suited for neutron experiments due to the high penetration and non-destructive nature of biomass. The Bio-SANS instrument at Oak Ridge National Laboratory has developed a pressure cell that allows to heat the cell up to 300 C a…

Enzyme Structure and FunctionProtein Structure and DynamicsNuclear Physics and Applications

Atomistic ensembles of proteins and soft matter complexes from MD simulations and solution scattering data

Jochen S. Hub2020-08-02Acta Crystallographica Section A Foundations and Advances

Understanding the function of disordered proteins or soft-matter complexes requires understanding of their conformational ensembles. However, experimental data alone is often insufficient for defining all degrees of freedom of such systems, whereas simulations may be biased by poor sampling or force field limitations.…

Enzyme Structure and Function

Optimization of crystallization conditions for PfActII in complex with fragmin F1 domain

Andrea Lopez Moreno、Inari Kursula2020-08-02Acta Crystallographica Section A Foundations and Advances

Actins are among the most abundant proteins in cells. They form filaments, which are involved in essential processes in the cell, including cell division, transport, motility, and structural functions. Polymerization involves a transition of monomeric (G-form) actin to the filamentous F-form. Conformational changes up…

Erythrocyte Function and PathophysiologyEnzyme Structure and Function

Can 3D electron diffraction provide accurate atomic structures of metal–organic frameworks?

Ge Meng、Zhehao Huang、Xiaodong Zou2020-08-02Acta Crystallographica Section A Foundations and Advances

Many framework materials such as metal-organic frameworks (MOF) or porous coordination polymers (PCPs) are synthesized as polycrystalline powders, which are too small for structure determination by single crystal X-ray diffraction (SCXRD). Here, we show that a three-dimensional (3D) electron diffraction method, namely…

Metal-Organic Frameworks: Synthesis and ApplicationsX-ray Diffraction in CrystallographyCrystallography and molecular interactions

Study on structure, electrical and dielectric properties of pure and Sr-doped LaCoO3 for chemical sensor application

Norah Alhaqbani、Sultanah Almotairi2020-08-02Acta Crystallographica Section A Foundations and Advances

A perovskite LaCoO3 was prepared by combustion and citrate-gel methodsin order to test its possible application as a chemical sensor. The crystal evolution, structure, composition, texture, morphology, and particle size were analyzed by X-ray diffraction, BET and scanning electron microscopies. The effects of doped Sr…

Magnetic and transport properties of perovskites and related materialsGas Sensing Nanomaterials and Sensors

Comprehensive strategy for quick determination of protein structures

Miki Senda、Toshiya Senda2020-08-02Acta Crystallographica Section A Foundations and Advances

A special advantage of protein crystallography is quick determination of target proteins for biological science and high-throughput structure determination of a large number of protein-compound complexes for pharmaceutical science. To achieve the quick structure determination, utilization of well-experienced protein c…

Advanced Proteomics Techniques and ApplicationsEnzyme Structure and FunctionProtein Structure and Dynamics