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Novel D–π-A and A–π-D–π-A three-component photoinitiating systems based on carbazole/triphenylamino based chalcones and application in 3D and 4D printing

Hong Chen、Guillaume Noirbent、Yijun Zhang 等 10 位作者2020-01-01Polymer Chemistry

A series of carbazole or triphenylamine based mono-chalcones, displaying either D–π-A or A–π-D–π-A architecture have been designed as photoinitiators for 3D and 4D printing.

Dyeing and Modifying Textile FibersPhotochromic and Fluorescence ChemistryPhotopolymerization techniques and applications

Binary zinc–cobalt metal–organic framework derived mesoporous ZnCo 2 O 4 @NC polyhedron as a high-performance lithium-ion battery anode

Rui Sun、Zhaoxia Qin、Zhiyong Li 等 5 位作者2020-01-01Dalton Transactions

Ternary transition metal oxides have attracted increasing attention due to their many merits, and will enhance electrochemical performance via the synergistic effects of the different single metal oxides. Herein, ZnCo2O4 nanoparticles encapsulated in nitrogen-doped carbon (ZnCo2O4@NC) polyhedrons have been successfull…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Autonomous Probabilistic Coprocessing With Petaflips per Second

Brian Sutton、Rafatul Faria、Lakshmi Anirudh Ghantasala 等 6 位作者2020-01-01IEEE Access

In this article we present a concrete design for a probabilistic (p-) computer based on a network of p-bits, robust classical entities fluctuating between −1 and +1, with probabilities that are controlled through an input constructed from the outputs of other p-bits. The architecture of this probabilistic computer is…

Advanced Memory and Neural ComputingMachine Learning in Materials ScienceFerroelectric and Negative Capacitance Devices

Deep eutectic solvent-based manganese molybdate nanosheets for sensitive and simultaneous detection of human lethal compounds: comparing the electrochemical performances of M-molybdate (M = Mg, Fe, and Mn) electrocatalysts

Jeena N. Baby、Balasubramanian Sriram、Sea‐Fue Wang 等 6 位作者2020-01-01Nanoscale

Potentially hazardous chemical contaminants endanger the environment and human well-being, challenging scientists and policy makers to develop holistic alternative approaches for remediation.

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrochemical Analysis and Applications

Recent advances of polyoxometalates in multi-functional imaging and photothermal therapy

Xueping Kong、Guofeng Wan、Bao Li 等 4 位作者2020-01-01Journal of Materials Chemistry B

Polyoxometalates (POMs) as a kind of molecular metal-oxide cluster with precise chemical composition and architecture have been demonstrated to show potential in multidisciplinary materials. Accompanied by their bioactivities, POM clusters have also been shown to be capable of sensing diseases and allowing synergistic…

Nanoplatforms for cancer theranosticsPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Phenazine derivatives for optical sensing: a review

Xiaoni Qi、Li‐Rong Dang、Wenjun Qü 等 7 位作者2020-01-01Journal of Materials Chemistry C

Phenazine exhibiting an electron-deficient skeleton, lone pair of electrons on nitrogen atoms, and other properties (such as tunable structures, excellent optical performance and proper binding abilities) can effectively sense target ions or molecules via non-covalent interactions, involving hydrogen bonds, anion–π in…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsPhenothiazines and Benzothiazines Synthesis and Activities

Assessing electrochemical properties and diffusion dynamics of metal ions (Na, K, Ca, Mg, Al and Zn) on a C 2 N monolayer as an anode material for non-lithium ion batteries

Yingchun Ding、Qijiu Deng、Caiyin You 等 6 位作者2020-01-01Physical Chemistry Chemical Physics

We perform first-principles molecular dynamics (FPMD) simulations together with a CI-NEB method to explore the structure, electrochemical properties and diffusion dynamics of a C2N monolayer saturated with various univalent, bivalent and trivalent metal ions. A characteristic irregular adsorption structure consisting…

Advancements in Battery MaterialsGraphene research and applicationsSemiconductor materials and devices

Liquid–polymer triboelectricity: chemical mechanisms in the contact electrification process

Mariana D. Sosa、María Luz Martínez Ricci、Leandro L. Missoni 等 7 位作者2020-01-01Soft Matter

) to water decreases the electrical charge induced in the drop. The charge also decreases with increasing RH. These results suggest proton or hydroxyl transfer from the liquid to the hydrophobic polymer surface. A proposed thermodynamic model for the ion transfer process allows explaining the observed effects of RH, p…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

Multinary copper-based chalcogenide nanocrystal systems from the perspective of device applications

Soubantika Palchoudhury、Karthik Ramasamy、Arunava Gupta2020-01-01Nanoscale Advances

Multinary chalcogenide semiconductor nanocrystals are a unique class of materials as they offer flexibility in composition, structure, and morphology for controlled band gap and optical properties. They offer a vast selection of materials for energy conversion, storage, and harvesting applications. Among the multinary…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Unmodified bulk alumina as an efficient catalyst for propane dehydrogenation

Pengzhao Wang、Zhikang Xu、Tinghai Wang 等 6 位作者2020-01-01Catalysis Science & Technology

A series of unmodified bulk Al 2 O 3 materials show an intrinsic activity for selectively catalyzing propane dehydrogenation.

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisCatalysis and Oxidation Reactions

Flexible polyurethanes, renewable fuels, and flavorings from a microalgae oil waste stream

Thien An Phung Hai、Nitin Neelakantan、Marissa Tessman 等 8 位作者2020-01-01Green Chemistry

To achieve sustainably-sourced polymers from algae, azelaic acid was prepared from an algae oil waste stream and converted into a flexible polyurethane foam. The heptanoic acid co-product was converted into both a flavoring and a renewable solvent.

Algal biology and biofuel productionPolymer composites and self-healingOxidative Organic Chemistry Reactions

Iodide-doped precious metal nanoparticles: measuring oxidative stress in vivo via photoacoustic imaging

Yash Mantri、Barak Davidi、Jeanne E. Lemaster 等 5 位作者2020-01-01Nanoscale

Accumulation of reactive oxygen and nitrogen species (RONS) can induce cell damage and even cell death. RONS are short-lived species, which makes direct, precise, and real-time measurement difficult. Biologically-relevant RONS levels are in the nM-μM scale; hence, there is a need for highly sensitive RONS probes. We p…

Nanoplatforms for cancer theranosticsPhotoacoustic and Ultrasonic ImagingAdvanced Nanomaterials in Catalysis

Understanding the mechanism of byproduct formation with in operando synchrotron techniques and its effects on the electrochemical performance of VO 2 (B) nanoflakes in aqueous rechargeable zinc batteries

Qiang Pang、Hainan Zhao、Ruqian Lian 等 10 位作者2020-01-01Journal of Materials Chemistry A

The byproduct protects the vanadium-based positive electrode of ARZBs and facilitates Zn 2+ insertion into the electrode.

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationAdvanced battery technologies research

High-performance capacitive strain sensors with highly stretchable vertical graphene electrodes

Caihao Deng、Linfeng Lan、Penghui He 等 13 位作者2020-01-01Journal of Materials Chemistry C

A stretchable capacitive strain sensors based on vertical graphene electrodes with unique stress direction recognizing ability is demonstrated, showing potential to detect physical and physiological signals.

Advanced Sensor and Energy Harvesting MaterialsGas Sensing Nanomaterials and SensorsConducting polymers and applications

Correlating alkyl chain length with defect passivation efficacy in perovskite solar cells

Wenhuai Feng、Chengxi Zhang、Jun‐Xing Zhong 等 5 位作者2020-01-01Chemical Communications

We, for the first time, correlated the alkyl chain length of amine molecules with the defect passivation efficacy, either on the surfaces or at grain boundaries of perovskite films. Blade-coated perovskite solar cells with long-chain amine passivation achieved an efficiency of 21.5%, accompanied by a small voltage los…

Perovskite Materials and ApplicationsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Nickel iron phosphide ultrathin nanosheets anchored on nitrogen-doped carbon nanoflake arrays as a bifunctional catalyst for efficient overall water splitting

Jialin Bian、Ze-Yi Song、Xianglin Li 等 5 位作者2020-01-01Nanoscale

An efficient and durable bifunctional catalyst of NiFeP ultrathin nanosheets anchored on nitrogen-doped carbon nanoflake arrays is designed for overall water splitting.

Electrocatalysts for Energy ConversionAdvanced Photocatalysis TechniquesCopper-based nanomaterials and applications