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Size Matters: New Zintl Phase Hydrides of REGa (RE = Y, La, Tm) and RESi (RE = Y, Er, Tm) with Large and Small Cations

Anton Werwein、Thomas C. Hansen、Holger Kohlmann2019-11-16Crystals

Many Zintl phases exhibiting a CrB type structure form hydrides. Systematic studies of AeTtHx (Ae = Ca, Sr, Ba; Tt = Si, Ge, Sn), LnTtHx (Ln = La, Nd; Tt = Si, Ge, Sn), and LnGaHx (Ln = Nd, Gd) showed the vast structural diversity of these systems. Hydrogenation reactions on REGa (RE = Y, La, Tm) and RESi (RE = Y, Er,…

Hydrogen Storage and MaterialsNuclear Materials and PropertiesMXene and MAX Phase Materials

Magnetism and Conductivity Along Structural Domain Walls of SrTiO3

Yiftach Frenkel、Yanwu Xie、Harold Y. Hwang 等 4 位作者2019-11-16Journal of Superconductivity and Novel Magnetism

Abstract The interface between the oxide insulators LaAlO 3 and SrTiO 3 (LAO/STO) hosts a two-dimensional electron gas. The combination of interfacial conductivity and superconductivity at ultra-low temperatures with the physical phenomena of the oxide parent materials has fueled extensive research in the field since…

Semiconductor materials and devicesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Fabrication of MgFe2O4-ZnO Nanocomposites forPhotocatalysis of Organic Pollutants under Solar Light Radiation

Krushitha Shetty、B.S. Prathibha、Dinesh Rangappa 等 6 位作者2019-11-16Asian Journal of Chemistry

MgFe2O4, ZnO and MgFe2O4-ZnO samples were successfully prepared through low temperature solution combustion route. The structural and morphological investigation were accomplished by PXRD, HRSEM, UV-visible and FTIR. The PXRD results point towards the reduced size of synthesized nanocomposites, which was further confi…

ZnO doping and propertiesMagnetic Properties and Synthesis of FerritesMagnesium Oxide Properties and Applications

Hydrophobic Polymer Encapsulation Effects on Subgap Density of States in Multilayered Molybdenum Disulfide Field‐Effect Transistors

Sungju Choi、Seung Gi Seo、Hye Ri Yu 等 6 位作者2019-11-16physica status solidi (RRL) - Rapid Research Letters

Herein, exfoliated, multilayered molybdenum disulfide (MoS 2 ) (m‐MoS 2 ) field‐effect transistors (FETs) are implemented with bilayered SiN x /SiO x gate dielectrics on indium tin oxide (ITO) substrates. For a quantitative understanding on gas adsorption effects on the electrical performance of m‐MoS 2 FETs, subgap d…

2D Materials and ApplicationsNanowire Synthesis and ApplicationsFerroelectric and Negative Capacitance Devices

Ca-Doped CrOX/γ-Al2O3 Catalysts with Improved Dehydrogenation Performance for the Conversion of Isobutane to Isobutene

Guangjian Wang、Ning Song、Kai Lu 等 9 位作者2019-11-16Catalysts

The dehydrogenation of low-carbon alkane to obtain olefins is an effective way to meet the steadily increasing demand of these building blocks in chemical industry. In this study, Ca-doped CrOx/γ-Al2O3 catalysts were fabricated via a one-pot method by employing Cr(OH)3 as the precursor, and their catalytic performance…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisCatalysis and Oxidation Reactions

Multiwavelength Raman Scattering Spectroscopy Study of Graphene Synthesized on Si(100) and SiO2 by Microwave Plasma‐Enhanced Chemical Vapor Deposition

Šarūnas Meškinis、Rimantas Gudaitis、Andrius Vasiliauskas 等 5 位作者2019-11-16physica status solidi (RRL) - Rapid Research Letters

Herein, multiwavelength Raman spectroscopy studies of graphene samples synthesized directly on SiO 2 and Si(100) substrates by microwave plasma‐enhanced chemical vapor deposition (MW PECVD), using five different excitation wavelengths in ultraviolet (UV), visible light, and near‐infrared (NIR) ranges, are presented pa…

Graphene research and applicationsDiamond and Carbon-based Materials ResearchGraphene and Nanomaterials Applications

Replacing K‐feldspar with a siliceous solid by‐product of zeolite industry for medium‐temperature calcium matte glazes

LU Xi-long、Kemu Cheng、Cao Chun-e 等 6 位作者2019-11-16International Journal of Applied Ceramic Technology

Abstract To recycle a multicomponent siliceous solid waste (MSW), a by‐product of the zeolite industry, as a K‐feldspar substitute for the preparation of medium temperature calcium matte glazes, the chemical composition, phase evolution, and thermal behavior of the waste versus temperature were characterized using mul…

Glass properties and applicationsRecycling and utilization of industrial and municipal waste in materials productionPigment Synthesis and Properties

Extreme Ultraviolet Generation of Localized Defects in Single-Layer Graphene: Raman Mapping, Atomic Force Microscopy, and High-Resolution Scanning Electron Microscopy Analysis

S. Botti、L. Mezi、A. Rufoloni 等 6 位作者2019-11-16ACS Applied Electronic Materials

We report micro-Raman spectroscopy, high-resolution scanning electron microscopy (HR-SEM) and atomic force microscopy (AFM) investigation of changes in chemical vapor deposition grown single-layer graphene structure induced by extreme ultraviolet (EUV) irradiation. We found that the exposures at doses up to 200 mJ/cm…

Graphene research and applicationsDiamond and Carbon-based Materials ResearchGraphene and Nanomaterials Applications

Photoinduced Carrier Generation and Distribution in Solution-Deposited Titanyl Phthalocyanine Monolayers

Shenkai Wang、Naihao Chiang、Han Guo 等 7 位作者2019-11-16Chemistry of Materials

We prepared titanyl phthalocyanine (TiOPc) monolayers on sapphire-prism supported Au{111} substrates through solution deposition and characterized their photoresponses using a custom-built laser-assisted scanning tunneling microscope under ambient conditions. Two types of lattice structures (hexagonal and rectangular)…

Molecular Junctions and NanostructuresSurface Chemistry and CatalysisElectronic and Structural Properties of Oxides

Gladkovskyite, MnTlAs3S6, a new thallium sulfosalt from the Vorontsovskoe gold deposit, Northern Urals, Russia

Anatoly V. Kasatkin、Emil Makovicky、Jakub Plášil 等 8 位作者2019-11-16Journal of Geosciences

Gladkovskyite (IMA2018-098), MnTlAs 3 S 6 , is a new sulfosalt from the Vorontsovskoe gold deposit, Sverdlovsk Oblast', Northern Urals, Russia. The new mineral occurs in limestone breccias cemented by abundant realgar, orpiment, baryte and pyrite, as well as minor clinochlore, fluorapatite, quartz and talc. Gladkovsky…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyInorganic Chemistry and Materials

Coordination Geometry Engineering in a Doped Disordered Matrix for Tunable Optical Response

Liting Lin、Yunpeng Wang、Bijiao Lan 等 14 位作者2019-11-16The Journal of Physical Chemistry C

The controllable incorporation of the dopant element with strictly designed coordination geometry into the target host merits untold scientific and technological potential, yet it has been met with limited success in a disordered matrix. Here, we present a general route for precisely tuning the coordination geometry o…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

Microstructure Evolution in ZrCx with Different Stoichiometries Irradiated by Four MeV Au Ions

Boxin Wei、Dong Wang、Yujin Wang 等 4 位作者2019-11-16Materials

ZrCx ceramics with different stoichiometries were irradiated under a four MeV Au ion beam in doses of 2 × 1016 ions/cm2 at room temperature, corresponding to ~130 dpa. Grazing incidence, X-ray diffraction and transmission electron microscopy were performed to study the radiation damage and microstructure evolution in…

Fusion materials and technologiesNuclear Materials and PropertiesNuclear materials and radiation effects

Poly(Acrylonitrile–Butadiene–Styrene) as a Special β-Nucleating Agent on the Toughness of Isotactic Polypropylene

Jingru Liu、Xinxu Zhu、Zheng Cao2019-11-16Polymers

The influence of poly(acrylonitrile–butadiene–styrene) (ABS) as a special β-nucleating agent on the impact and tensile properties of isotactic polypropylene (iPP) were investigated by dynamic rheological measurements, wide-angle X-ray diffraction (WAXD), differential scanning calorimetry (DSC), scanning electron micro…

Polymer crystallization and propertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Second-Generation Manganese(III) Porphyrins Bearing 3,5-Dichloropyridyl Units: Innovative Homogeneous and Heterogeneous Catalysts for the Epoxidation of Alkenes

Cláudia M. B. Neves、Susana L.H. Rebelo、M. Amparo F. Faustino 等 5 位作者2019-11-16Catalysts

The synthesis, characterisation and homogeneous catalytic oxidation results of two manganese(III) porphyrins of the so-called second-generation of metalloporphyrin catalysts, containing one or four 3,5-dichloropyridyl substituents at the meso positions are reported for the first time. The catalytic efficiency of these…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsOxidative Organic Chemistry Reactions

Circular Intensity Differential Scattering Reveals the Internal Structure of Polymer Fibrils

Ashish Sharma、Alison C. Campbell、Julien Leoni 等 6 位作者2019-11-16The Journal of Physical Chemistry Letters

The optical and electronic properties of π-conjugated polymers in organic electronic devices depend on their intra- and interchain interactions, dictated by the internal arrangement of the polymer chains in an amorphous or semicrystalline aggregated state. Here, we discuss the utility of circular intensity differentia…

Luminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic CompoundsPolydiacetylene-based materials and applications

Actively Tunable Metalens Array Based on Patterned Phase Change Materials

Wei Bai、Ping Yang、Shuai Wang 等 8 位作者2019-11-16Applied Sciences

Recently, the metalens has been investigated for its application in many fields due to its advantages of being much smaller than a conventional lens and is compatible with nano-devices. Although metalenses have extraordinary optical performance, it is still not enough in some occasions such as wavefront detection for…

Metamaterials and Metasurfaces ApplicationsPhase-change materials and chalcogenidesOptical and Acousto-Optic Technologies

Investigation of the crystallization behavior of laser‐irradiated EXTREME pattern by Raman spectroscopy

Megan Driggers、Clara Rivero‐Baleine2019-11-16International Journal of Applied Glass Science

Abstract This paper investigates the crystallization behavior of a Ge 2 Sb 2 Se 4 Te 1 (GSST) chalcogenide phase change material film using Raman spectroscopy. The properties of as‐deposited, thermally treated, and laser‐written GSST films are investigated. A single mask exposure laser excitation process was developed…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesNonlinear Optical Materials Studies

“Gene” modeling approach to new glass design

Liyan Zhang、Yongchun Xu、Hong Li2019-11-16International Journal of Applied Glass Science

Abstract Composition‐structure‐property (C‐S‐P) approach, named as “glass structural gene modeling (GSgM), for glass database development and new glass design are detailed in this article. C‐S‐P modeling principle and modeling procedure are selectively demonstrated using two sets of phosphate glass systems with variou…

Material Dynamics and PropertiesGlass properties and applicationsPhase-change materials and chalcogenides

Drain-engineered carbon-nanotube-film field-effect transistors with high performance and ultra-low current leakage

Lijun Liu、Chenyi Zhao、Li Ding 等 5 位作者2019-11-16Nano Research

A small bandgap and light carrier effective mass ( m 0 ) lead to obvious ambipolar transport behavior in carbon nanotube (CNT) field-effect transistors (FETs), including a high off-state current and severe degradation of the subthreshold swing (SS) with increasing drain bias voltage. We demonstrate a drain-engineered…

Carbon Nanotubes in CompositesGraphene research and applicationsAdvancements in Semiconductor Devices and Circuit Design

On the Colloidal Stability of Nitrogen-Rich Carbon Nanodots Aqueous Dispersions

Thiago Fiuza、Guilherme Gomide、Alex Fabiano Cortez Campos 等 5 位作者2019-11-16C – Journal of Carbon Research

The present survey reports on the colloidal stability of aqueous dispersions of nitrogen-rich carbon nanodots (N-CDs). The N-CDs were synthesized by thermally induced decomposition of organic precursors and present an inner core constituted of a β − C 3 N 4 crystalline structure surrounded by a surface shell containin…

Carbon and Quantum Dots ApplicationsNanocluster Synthesis and ApplicationsGraphene and Nanomaterials Applications