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Synthesis and Electronic Structures of Heavy Lanthanide Metallocenium Cations

Conrad A. P. Goodwin、Daniel Reta、Fabrizio Ortu 等 5 位作者2017-11-28Journal of the American Chemical Society

High Resolution Image Download MS PowerPoint Slide The origin of 60 K magnetic hysteresis in the dysprosocenium complex [Dy(Cp ttt ) 2 ][B(C 6 F 5 ) 4 ] (Cp ttt = C 5 H 2 t Bu 3 -1,2,4, 1-Dy ) remains mysterious, thus we envisaged that analysis of a series of [Ln(Cp ttt ) 2 ] + (Ln = lanthanide) cations could shed lig…

Magnetism in coordination complexesOrganometallic Complex Synthesis and CatalysisLanthanide and Transition Metal Complexes

Transparent and Flexible Surface-Enhanced Raman Scattering (SERS) Sensors Based on Gold Nanostar Arrays Embedded in Silicon Rubber Film

Seung‐Young Park、Jiwon Lee、Hyunhyub Ko2017-11-28ACS Applied Materials & Interfaces

Integration of surface-enhanced Raman scattering (SERS) sensors onto transparent and flexible substrates enables lightweight and deformable SERS sensors which can be wrapped or swabbed on various nonplanar surfaces for the efficient collection and detection of analytes on various surfaces. However, the development of…

Gold and Silver Nanoparticles Synthesis and ApplicationsBiosensors and Analytical DetectionAdvanced biosensing and bioanalysis techniques

Aggregation-Induced Fluorescence-to-Phosphorescence Switching of Molecular Gold Clusters

Mizuho Sugiuchi、Junichi Maeba、Nobuyuki OKUBO 等 6 位作者2017-11-28Journal of the American Chemical Society

Aggregation-induced optical responses are ubiquitous among a wide range of organic and inorganic compounds. Here, we demonstrate an unprecedented effect of aggregation on the photoluminescence (PL) profiles of [core + exo ]-type [Au 8 ] 4+ clusters, which displayed a change in the dominant PL emission mode from fluore…

Nanocluster Synthesis and ApplicationsNeurological Complications and SyndromesAdvanced Nanomaterials in Catalysis

Revisiting Nitrogen Species in Covalent Triazine Frameworks

Dmitrii Osadchii、Alma I. Olivos Suarez、Anastasiya Bavykina 等 4 位作者2017-11-28Langmuir

Covalent triazine frameworks (CTFs) are porous organic materials promising for applications in catalysis and separation due to their high stability, adjustable porosity, and intrinsic nitrogen functionalities. CTFs are prepared by ionothermal trimerization of aromatic nitriles; however, multiple side reactions also oc…

Advanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework Applications

Defect chemistry and electrical properties of sodium bismuth titanate perovskite

Fan Yang、Ming Li、Linhao Li 等 6 位作者2017-11-28Journal of Materials Chemistry A

We review the diversity of the electrical behaviour of NBT induced by various defect mechanisms, including A-site Na or Bi non-stoichiometry, isovalent-substitution, and acceptor- and donor-doping.

Ferroelectric and Piezoelectric MaterialsPerovskite Materials and ApplicationsMicrowave Dielectric Ceramics Synthesis

Carbon Nanotube Dispersion in Solvents and Polymer Solutions: Mechanisms, Assembly, and Preferences

Chandrani Pramanik、Jacob R. Gissinger、Satish Kumar 等 4 位作者2017-11-28ACS Nano

Debundling and dispersion of carbon nanotubes (CNTs) in polymer solutions play a major role in the preparation of carbon nanofibers due to early effects on interfacial ordering and mechanical properties. A roadblock toward ultrastrong fibers is the difficulty to achieve homogeneous dispersions of CNTs in polyacrylonit…

Graphene research and applicationsCarbon Nanotubes in CompositesNanotechnology research and applications

Self‐Assembled α‐Cyanostilbenes for Advanced Functional Materials

Marta Martínez‐Abadía、Raquel Giménez、M. Blanca Ros2017-11-28Advanced Materials

In the specific context of condensed media, the significant and increasing recent interest in the α-cyanostilbene (CS) motif [ArCHC(CN)Ar] is relevant. These compounds have shown remarkable optical features in addition to interesting electrical properties, and hence they are recognized as very suitable and versat…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

In‐Plane Assembled Orthorhombic Nb2O5 Nanorod Films with High‐Rate Li+ Intercalation for High‐Performance Flexible Li‐Ion Capacitors

Bohua Deng、Tianyu Lei、Weihua Zhu 等 5 位作者2017-11-28Advanced Functional Materials

Abstract Organic hybrid supercapacitors that consist of a battery electrode and a capacitive electrode show greatly improved energy density, but their power density is generally limited by the poor rate capability of battery‐type electrodes. In addition, flexible organic hybrid supercapacitors are rarely reported. To…

Supercapacitor Materials and FabricationAdvancements in Battery MaterialsAdvanced Battery Materials and Technologies

Biomaterials of Poly(vinyl alcohol) and Natural Polymers

Mirela Teodorescu、Maria Bercea、Simona Morariu2017-11-28Journal of macromolecular science. Part C, Reviews in macromolecular chemistry and physics/Journal of macromolecular science. Reviews in macromolecular chemistry and physics

Polysaccharides and proteins are abundantly found in nature and are highly recommended for developing eco-friendly materials due to their special properties (biodegradability, biocompatibility, non-toxicity, low cost, etc.). However, they sometimes fail to meet specific requirements due to poor mechanical and physical…

Electrospun Nanofibers in Biomedical ApplicationsAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Extraction and physicochemical characterization of chitin and chitosan isolated from house cricket

E. B. Ibitoye、I. H. Lokman、M N M Hezmee 等 6 位作者2017-11-28Biomedical Materials

Chitin ranks next to cellulose as the most important bio-polysaccharide which can primarily be extracted from crustacean shells. However, the emergence of new areas of the application of chitin and its derivatives are on the increase and there is growing demand for new chitin sources. In this study, therefore, an atte…

Insect Utilization and EffectsPineapple and bromelain studiesNanocomposite Films for Food Packaging

Three-Dimensional Ionic Covalent Organic Frameworks for Rapid, Reversible, and Selective Ion Exchange

Zonglong Li、Hui Li、Xinyu Guan 等 11 位作者2017-11-28Journal of the American Chemical Society

Covalent organic frameworks (COFs) have emerged as functional materials for various potential applications. However, the availability of three-dimensional (3D) COFs is still limited, and nearly all of them exhibit neutral porous skeletons. Here we report a general strategy to design porous positively charged 3D ionic…

Covalent Organic Framework ApplicationsChemical Synthesis and CharacterizationMetal-Organic Frameworks: Synthesis and Applications

Remarkable Roles of Cu To Synergistically Optimize Phonon and Carrier Transport in n-Type PbTe-Cu2Te

Yu Xiao、Haijun Wu、Wei Li 等 12 位作者2017-11-28OpenAlex

High thermoelectric performance of n-type PbTe is urgently needed to match its p-type counterpart. Here, we show a peak ZT ∼ 1.5 at 723 K and a record high average ZT > 1.0 at 300–873 K realized in n-type PbTe by synergistically suppressing lattice thermal conductivity and enhancing carrier mobility by introducing Cu…

Thermal properties of materialsThermal Expansion and Ionic ConductivityAdvanced Thermoelectric Materials and Devices

Electrochemical Method To Prepare Graphene Quantum Dots and Graphene Oxide Quantum Dots

Satyaprakash Ahirwar、Sudhanshu Mallick、D. Bahadur2017-11-28OpenAlex

High Resolution Image Download MS PowerPoint Slide In this study, we present the preparation of graphene quantum dots (GQDs) and graphene oxide quantum dots (GOQDs). GQDs/GOQDs are prepared by an easy electrochemical exfoliation method, in which two graphite rods are used as electrodes. The electrolyte used is a combi…

Graphene and Nanomaterials ApplicationsCarbon and Quantum Dots ApplicationsGraphene research and applications

Recent Advances in the Application of Vitamin E TPGS for Drug Delivery

Conglian Yang、Tingting Wu、Yan Qi 等 4 位作者2017-11-28OpenAlex

D-ɑ-tocopheryl polyethylene glycol succinate (Vitamin E TPGS or TPGS) has been approved by FDA as a safe adjuvant and widely used in drug delivery systems. The biological and physicochemical properties of TPGS provide multiple advantages for its applications in drug delivery like high biocompatibility, enhancement of…

Nanoparticle-Based Drug DeliveryRetinoids in leukemia and cellular processesBioactive Compounds and Antitumor Agents

Nanomedicines: current status and future perspectives in aspect of drug delivery and pharmacokinetics

Young Hee Choi、Hyo‐Kyung Han2017-11-28OpenAlex

Nanomedicines have evolved into various forms including dendrimers, nanocrystals, emulsions, liposomes, solid lipid nanoparticles, micelles, and polymeric nanoparticles since their first launch in the market. Widely highlighted benefits of nanomedicines over conventional medicines include superior efficacy, safety, ph…

Advanced Drug Delivery SystemsNanoparticle-Based Drug DeliveryDrug Solubulity and Delivery Systems

Van der Waals epitaxial growth and optoelectronics of large-scale WSe2/SnS2 vertical bilayer p–n junctions

Tiefeng Yang、Biyuan Zheng、Zhen Wang 等 15 位作者2017-11-28OpenAlex

Abstract High-quality two-dimensional atomic layered p–n heterostructures are essential for high-performance integrated optoelectronics. The studies to date have been largely limited to exfoliated and restacked flakes, and the controlled growth of such heterostructures remains a significant challenge. Here we report t…

Perovskite Materials and ApplicationsMXene and MAX Phase Materials2D Materials and Applications

Methods of Recycling, Properties and Applications of Recycled Thermoplastic Polymers

Mădălina Elena Grigore2017-11-28OpenAlex

This study aims to provide an updated survey of the main thermoplastic polymers in order to obtain recyclable materials for various industrial and indoor applications. The synthesis approach significantly impacts the properties of such materials and these properties in turn have a significant impact on their applicati…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesAdditive Manufacturing and 3D Printing Technologies

Active Packaging Applications for Food

Selçuk Yildirim、Bettina Röcker、Marit Kvalvåg Pettersen 等 10 位作者2017-11-28OpenAlex

The traditional role of food packaging is continuing to evolve in response to changing market needs. Current drivers such as consumer's demand for safer, "healthier," and higher-quality foods, ideally with a long shelf-life; the demand for convenient and transparent packaging, and the preference for more sustainable p…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesAdvanced Sensor and Energy Harvesting Materials

Influence of macroscopic defects on the corrosion behavior of U–0.79 wt%Ti alloy in sodium chloride solution

Dingzhou Cai、Ming Wang、Yiming Ren 等 6 位作者2017-11-27Physical Chemistry Chemical Physics

Uranium alloys containing a low concentration of titanium have received wide attention due to their greatly enhanced corrosion resistance and outstanding mechanical performances. Herein, we investigated the effect of macroscopic defects on the corrosion behavior of U-0.79 wt%Ti (denoted as U-Ti) alloy in 0.01 M NaCl s…

High Temperature Alloys and CreepFusion materials and technologiesNuclear Materials and Properties

Wide angle reflective telescopes with NURBS freeform surfaces

Michael Chrisp2017-11-27OpenAlex

Freeform NURBS surfaces improve the resolution of two wide angle reflective telescopes. The first is an extremely wide angle design covering 40° by 40° supporting a 1.4 Gpixel visible array, and the second is an earth observing telescope with a 4° by 0.8° field of view.

Optical Coatings and GratingsAdvanced optical system designAdvanced Surface Polishing Techniques