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A ferroelectric liquid crystal confined in cylindrical nanopores: reversible smectic layer buckling, enhanced light rotation and extremely fast electro-optically active Goldstone excitations

Mark Busch、Andriy V. Kityk、Wiktor Piecek 等 10 位作者2017-01-01Nanoscale

The orientational and translational order of a thermotropic ferroelectric liquid crystal (2MBOCBC) imbibed in self-organized, parallel, cylindrical pores with radii of 10, 15, or 20 nm in anodic aluminium oxide monoliths (AAO) are explored by high-resolution linear and circular optical birefringence as well as neutron…

Liquid Crystal Research AdvancementsLipid Membrane Structure and BehaviorAdvanced Materials and Mechanics

Repulsion–attraction switching of nematic colloids formed by liquid crystal dispersions of polygonal prisms

Bohdan Senyuk、Qinlong Liu、Philip D. Nystrom 等 4 位作者2017-01-01Soft Matter

Self-assembly of colloidal particles due to elastic interactions in nematic liquid crystals promises tunable composite materials and can be guided by exploiting surface functionalization, geometric shape and topology, though these means of controlling self-assembly remain limited. Here, we realize low-symmetry achiral…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsSurfactants and Colloidal Systems

Compositional nanodomain formation in hybrid formate perovskites

Edwina A. Donlan、Hanna L. B. Boström、Harry S. Geddes 等 5 位作者2017-01-01Chemical Communications

(M = Mn, Zn, Mg). Using a combination of infrared spectroscopy, non-negative matrix factorization, and reverse Monte Carlo refinement, we show that the Mn- and Zn-containing compounds support compositional nanodomains resembling the polar nanoregions of conventional relaxor ferroelectrics. The M = Mg family exhibits a…

Ferroelectric and Piezoelectric MaterialsElectronic and Structural Properties of OxidesChemical and Physical Properties of Materials

Stacking-enriched magneto-transport properties of few-layer graphenes

Thi-Nga Do、Cheng-Peng Chang、Po-Hsin Shih 等 5 位作者2017-01-01Physical Chemistry Chemical Physics

The quantum Hall effects in sliding bilayer graphene and a AAB-stacked trilayer system are investigated using the Kubo formula and a generalized tight-binding model. The various stacking configurations can greatly diversify the magnetic quantization and thus create rich and unique transport properties. The quantum con…

Graphene research and applicationsQuantum and electron transport phenomenaDiamond and Carbon-based Materials Research

Magnetodielectric coupling in a non-perovskite metal–organic framework

Tathamay Basu、Anton Jesche、Björn Bredenkötter 等 8 位作者2017-01-01Materials Horizons

Multiferroicity and magnetodielectric coupling in metal–organic frameworks (MOFs) are rare and so far restricted mainly to formate-based systems with a perovskite structure.

Perovskite Materials and ApplicationsMultiferroics and related materialsAdvanced Condensed Matter Physics

First-Principles Study on Various Point Defects Formed by Hydrogen and Helium Atoms in Tungsten

Qiang Zhao、Zheng Zhang、Yang Li 等 4 位作者2017-01-01Science and Technology of Nuclear Installations

The different point defects formed by two hydrogen atoms or two helium atoms in tungsten were investigated through first-principles calculation. The energetically favorable site for a hydrogen atom is tetrahedral interstitial site while substitutional site is the most preferred site for a helium atom. The formation en…

Fusion materials and technologiesHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

Current–voltage characteristics of borophene and borophane sheets

Sahar Izadi Vishkayi、Meysam Bagheri Tagani2017-01-01Physical Chemistry Chemical Physics

Motivated by recent experimental and theoretical research on a monolayer of boron atoms, borophene, the current-voltage characteristics of three different borophene sheets, 2Pmmn, 8Pmmn, and 8Pmmm, are calculated using density functional theory combined with the nonequilibrium Green's function formalism. Borophene she…

Graphene research and applications2D Materials and ApplicationsBoron and Carbon Nanomaterials Research

Interlayer bond polarizability model for stacking-dependent low-frequency Raman scattering in layered materials

Liangbo Liang、Alexander A. Puretzky、Bobby G. Sumpter 等 4 位作者2017-01-01Nanoscale

, GaSe, h-BN, etc. Additionally, a general strategy is proposed to unify the stacking nomenclature for these 2D materials. Our model reveals the fundamental mechanism of LF Raman response to the stacking, and provides general rules for stacking identification.

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Decoration of exfoliated black phosphorus with nickel nanoparticles and its application in catalysis

Maria Caporali、Manuel Serrano‐Ruiz、Francesca Telesio 等 7 位作者2017-01-01Chemical Communications

Nickel nanoparticles were dispersed on the surface of exfoliated black phosphorus and the resulting nanohybrid Ni/2DBP showed an improved stability with respect to pristine 2D BP when kept under ambient conditions in the dark. Ni/2DBP was applied as a catalyst in the semihydrogenation of phenylacetylene and exhibited…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Surface oxidation and thermoelectric properties of indium-doped tin telluride nanowires

Zhen Li、Enzhi Xu、Yaroslav Losovyj 等 10 位作者2017-01-01Nanoscale

which can be readily removed by argon ion sputtering. Exposure of the cleaned nanowires to atmosphere leads to rapid oxidation of the surface within only one minute. Characterization of electrical conductivity σ, thermopower S, and thermal conductivity κ was performed on the same In-doped nanowire which shows suppress…

Advanced Thermoelectric Materials and DevicesGas Sensing Nanomaterials and SensorsChalcogenide Semiconductor Thin Films

Topological vacancies in spherical crystals

Zhenwei Yao2017-01-01Soft Matter

Understanding geometric frustration of ordered phases in two-dimensional condensed matter on curved surfaces is closely related to a host of scientific problems in condensed matter physics and materials science. Here, we show how two-dimensional Lennard-Jones crystal clusters confined on a sphere resolve geometric fru…

Topological Materials and PhenomenaQuasicrystal Structures and PropertiesMathematical Approximation and Integration

Reproducibility and off-stoichiometry issues in nickelate thin films grown by pulsed laser deposition

Daniele Preziosi、Anke Sander、Agnès Barthélémy 等 4 位作者2017-01-01AIP Advances

Rare-earth nickelates are strongly correlated oxides displaying a metal-to-insulator transition at a temperature tunable by the rare-earth ionic radius. In PrNiO3 and NdNiO3, the transition is very sharp and shows an hysteretic behavior akin to a first-order transition. Both the temperature at which the transition occ…

Magnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of OxidesChemical and Physical Properties of Materials

Molecularly-thin anatase field-effect transistors fabricated through the solid state transformation of titania nanosheets

S. Sekizaki、Minoru Osada、Kosuke Nagashio2017-01-01Nanoscale

We demonstrate the field-effect transistor (FET) operation of a molecularly-thin anatase phase produced through solid state transformation from Ti0.87O2 nanosheets. A monolayer Ti0.87O2 nanosheet with a thickness of 0.7 nm is a two-dimensional oxide insulator in which Ti vacancies are incorporated, rather than oxygen…

ZnO doping and propertiesGa2O3 and related materialsElectronic and Structural Properties of Oxides

Edge control of graphene domains grown on hexagonal boron nitride

Lingxiu Chen、Haomin Wang、Haomin Wang 等 13 位作者2017-01-01Nanoscale

The edge structure of graphene has a significant influence on its electronic properties. However, control over the edge structure of graphene domains on insulating substrates is still challenging. Here we demonstrate edge control of graphene domains on hexagonal boron nitride (h-BN) by modifying the ratio of working-g…

Graphene research and applications2D Materials and ApplicationsThermal properties of materials

van der Waals heterostructures based on allotropes of phosphorene and MoSe 2

Sumandeep Kaur、Ashok Kumar、Sunita Srivastava 等 4 位作者2017-01-01Physical Chemistry Chemical Physics

The van der Waals heterostructures of allotropes of phosphorene (α- and β-P) with MoSe <sub>2</sub> (H-, T-, ZT- and SO-MoSe <sub>2</sub> ) are investigated in the framework of state-of-the-art density functional theory.

Graphene research and applications2D Materials and ApplicationsBoron and Carbon Nanomaterials Research

Anomalous lattice behavior of vanadium pentaoxide (V 2 O 5 ): X-ray diffraction, inelastic neutron scattering and ab initio lattice dynamics

Baltej Singh、Mayanak K. Gupta、S. K. Mishra 等 7 位作者2017-01-01Physical Chemistry Chemical Physics

van der Waals and Hubbard interactions are found to play an important role in the structure and dynamics of α-V <sub>2</sub> O <sub>5</sub> .

High-pressure geophysics and materialsTransition Metal Oxide NanomaterialsThermal Expansion and Ionic Conductivity

Strain effects on phonon transport in antimonene investigated using a first-principles study

Aixia Zhang、Jiangtao Liu、San‐Dong Guo 等 4 位作者2017-01-01Physical Chemistry Chemical Physics

Strain engineering is a very effective method to continuously tune the electronic, topological, optical and thermoelectric properties of materials. In this work, strain-dependent phonon transport of recently-fabricated antimonene (Sb monolayers) under biaxial strain is investigated using a combination of first-princip…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies