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Luminescent tetraphenylethene-cored, carbazole- and thiophene-based microporous polymer films for the chemosensing of nitroaromatic analytes

Alex Palma‐Cando、D. Woitassek、Gunther Brunklaus 等 4 位作者2016-12-17Materials Chemistry Frontiers

Chemically and electrochemically generated novel microporous polymer networks (MPNs) have been prepared from tetraphenylethene (TPE)-cored, multifunctional carbazole- or thiophene-based monomers for the fluorescence sensing of nitroaromatic analytes.

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsCovalent Organic Framework Applications

High-Mobility Transport Anisotropy in Few-Layer MoO3 and Its Origin

Wei‐Bing Zhang、Qian Qu、Lai Kang2016-12-17ACS Applied Materials & Interfaces

The novel two-dimensional semiconductors with high carrier mobility and excellent stability are essential to the next-generation high-speed and low-power nanoelectronic devices. Because of the natural abundance, intrinsic gap, and chemical stability, metal oxides were also recently suggested as potential candidates fo…

2D Materials and ApplicationsGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Optical and Electrical Properties of (002)-Oriented ZnO Films Prepared on Amorphous Substrates by Sol-Gel Spin-Coating

Gonzalo Alonso Velázquez-Nevárez、Jorge Roberto Vargas-García、J. Aguilar‐Hernández 等 7 位作者2016-12-17Materials Research

Zinc oxide (ZnO) films were prepared on amorphous quartz substrates by sol-gel spin-coating using Zn(CH3COO)2•2H2O precursor. Isopropanol, ethanol and 2-methoxyethanol were used as solvents. The film drying temperature was kept constant at 200 ºC and the annealing temperature was varied from 400 to 800 ºC. Highly tran…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Controllable growth of monolayer MoS 2 by chemical vapor deposition via close MoO 2 precursor for electrical and optical applications

Yong Xie、Zhan Wang、Yongjie Zhan 等 11 位作者2016-12-17Nanotechnology

Abstract MoO 2 is used as a new source material for the growth of large area and high optical quality monolayer MoS 2 . However, a systematic study of the growth parameters is still missing and large-area growth of discreet single crystals is still challenging. Hereby, we report the shape evolution of monolayer growth…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Wetting and Dewetting Transitions on Submerged Superhydrophobic Surfaces with Hierarchical Structures

Huaping Wu、Zhe Yang、Binbin Cao 等 8 位作者2016-12-17Langmuir

The wetting transition on submersed superhydrophobic surfaces with hierarchical structures and the influence of trapped air on superhydrophobic stability are predicted based on the thermodynamics and mechanical analyses. The dewetting transition on the hierarchically structured surfaces is investigated, and two necess…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferFluid Dynamics and Thin Films

Third-Order Optical Response of Metallic Armchair Graphene Nanoribbons to an Elliptically-Polarized Terahertz Excitation Field

Yichao Wang、David R. Andersen2016-12-17IEEE Journal of Selected Topics in Quantum Electronics

We present a theoretical description of the third-order response induced by an elliptically-polarized terahertz beam normally-incident on intrinsic and extrinsic metallic armchair graphene nanoribbons. Our results show that using a straightforward experimental setup, it should be possible to observe novel polarization…

Graphene research and applicationsMetamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon Research

Deciphering the Role of Solvents in the Liquid Phase Exfoliation of Hexagonal Boron Nitride: A Molecular Dynamics Simulation Study

Titas Kumar Mukhopadhyay、Ayan Datta2016-12-17The Journal of Physical Chemistry C

Boron nitride (BN) nanosheets are promising candidates for device applications because of structural stability and large in-plane conductivity that require highly scalable and efficient preparatory routes. Liquid phase exfoliation (LPE), the best known method for the synthesis of two-dimensional nanosheets, demands an…

Graphene research and applicationsThermal properties of materialsBoron and Carbon Nanomaterials Research

Cross-linker mediated formation of sulfur-functionalized V 2 O 5 /graphene aerogels and their enhanced pseudocapacitive performance

Gamze Yilmaz、Xianmao Lu、Ghim Wei Ho2016-12-17Nanoscale

The development of efficient synthesis methods for the preparation of vanadium oxide (V2O5)–graphene holds great promise considering the excellent performance of the composite in electrochemical applications. Herein, we report the cross-linking of a V2O5–graphene hybrid via a vanadium–thiourea redox system, which allo…

Supercapacitor Materials and FabricationTransition Metal Oxide NanomaterialsAerogels and thermal insulation

High Visible Photoelectrochemical Activity of Ag Nanoparticle-Sandwiched CdS/Ag/ZnO Nanorods

Xu Yang、Hui Li、Wu Zhang 等 8 位作者2016-12-17ACS Applied Materials & Interfaces

We report on the sensitizing of CdS-coated ZnO (CdS/ZnO) nanorods (NRs) by Ag nanoparticles (NPs) embedded between the CdS coating and the ZnO nanorod and the improved optical and photoelectrochemical properties of the Ag NP-sandwiched nanostructure CdS/Ag/ZnO NRs. The CdS/Ag/ZnO NRs were fabricated by growing Ag NPs…

Advanced Photocatalysis TechniquesZnO doping and propertiesQuantum Dots Synthesis And Properties

Structural Transformation from Dimerization to Tetramerization of Serine‐Decorated Rare‐Earth‐Incorporated Arsenotungstates Induced by the Usage of Rare‐Earth Salts

Hai‐Lou Li、Ya‐Jie Liu、Jinglin Liu 等 6 位作者2016-12-17Chemistry - A European Journal

Abstract Three types of serine‐decorated rare‐ earth‐containing arsenotungstate [H 2 N(CH 3 ) 2 ] 6 NaH[RE 2 W 4 O 10 (H 2 O) 8 (Ser) 2 (B‐α‐AsW 9 O 33 ) 2 ]⋅30 H 2 O (RE 3+ =Eu 3+ , Gd 3+ , Tb 3+ , Dy 3+ , Ho 3+ , Er 3+ , Tm 3+ , Yb 3+ , and Y 3+ ; 1 ), [H 2 N(CH 3 ) 2 ] 6 Na 6− x RE x H 4−2 x [RE 4 W 8 O 19 (H 2 O)…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

Magnetic resonance study of bulk and thin film EuTiO3

V. V. Laguta、S. Kamba、M. Maryško 等 8 位作者2016-12-17arXiv

Magnetic resonance spectra of EuTiO3 in both bulk and thin film form were taken at temperatures from 3-350 K and microwave frequencies from 9.2-9.8 and 34 GHz. In the paramagnetic phase, magnetic resonance spectra are determined by magnetic dipole and exchange interactions between Eu2+ spins. In the film, a large cont…

Materials Science

Swift Heavy Ion Irradiation Induced Modifications in Structural, Microstructural, Electrical and Magnetic Properties of Mn Doped $SnO_{2}$ Thin Films

Sushant Gupta、Fouran Singh、B. Das2016-12-17arXiv

In this paper, we have presented the impact of swift heavy ion beam irradiation on the structural, microstructural, electrical and magnetic properties of $Sn_{0.9}Mn_{0.1}O_{2}$ thin films. The structural and electrical results have been interpreted by using properties of native or point defects, whereas the magnetic…

Materials Science

In-plane Topological p-n Junction in the Three-Dimensional Topological Insulator Bi$_{2-x}$Sb$_x$Te$_{3-y}$Se$_y$

Ngoc Han Tu、Yoichi Tanabe、Yosuke Satake 等 5 位作者2016-12-17arXiv

A topological p-n junction (TPNJ) is an important concept to control spin and charge transport on a surface of three dimensional topological insulators (3D-TIs). Here we report successful fabrication of such TPNJ on a surface of 3D-TI Bi$_{2-x}$Sb$_x$Te$_{3-y}$Se$_y$ thin films and experimental observation of the elec…

Mesoscale and Nanoscale PhysicsMaterials Science

Tunable Properties of Mg-Doped V2O5 Thin Films for Energy Applications: Li-Ion Batteries and Electrochromics

Marianthi Panagopoulou、Dimitra Vernardou、Emmanuel Koudoumas 等 6 位作者2016-12-17The Journal of Physical Chemistry C

Vanadium pentoxide (V 2 O 5 ) is doped for the first time with Mg, and the influence of Mg content on the films properties and functionality is investigated in detail, emphasis given on the electrochemical and electrochromic response. The Mg-doped V 2 O 5 films exhibit characteristics suitable for lithium ion batterie…

Advancements in Battery MaterialsGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Colloidal quantum-dots surface and device structure engineering for high-performance light-emitting diodes

Yuequn Shang、Zhijun Ning2016-12-17National Science Review

Abstract The application of colloidal quantum dots for light-emitting devices has attracted considerable attention in recent years, due to their unique optical properties such as size-dependent emission wavelength, sharp emission peak and high luminescent quantum yield. Tremendous efforts have been made to explore qua…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Diarylboryl-phenothiazine based multifunctional molecular siblings

Kalluvettukuzhy K. Neena、Pagidi Sudhakar、Dipak Kumbhar 等 4 位作者2016-12-17Chemical Communications

Herein we report the multifunctional characteristics such as aggregation induced emission (AIE), triboluminescence (TL), mechanofluorochromism and temperature sensing of molecular siblings 1 (10-(dimesitylboryl)phenothiazine) and 2 (10-(bis(2,6-dimethylphenyl)boryl)phenothiazine).

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic Compounds

Tuning Crystal Polymorphisms and Structural Investigation of Precipitated Calcium Carbonates for CO 2 Mineralization

Ribooga Chang、Dasol Choi、Min Hee Kim 等 4 位作者2016-12-17ACS Sustainable Chemistry & Engineering

Mineral carbonation, which involves spontaneous reactions of CO 2 with alkaline earth metals such as calcium or magnesium, is considered one of the most attractive options to sequester CO 2 because CO 2 can be permanently stored in an inert solid forming stable inorganic carbonate. Moreover, the precipitated CaCO 3 ha…

Calcium Carbonate Crystallization and InhibitionCO2 Sequestration and Geologic InteractionsClay minerals and soil interactions

Future perspectives for formaldehyde: pathways for reductive synthesis and energy storage

Leo E. Heim、Hannelore Konnerth、Martin H. G. Prechtl2016-12-17Green Chemistry

This perspective article spreads light on the recent directions towards the low-temperature reductive synthesis of formaldehyde and its derivatives and low-temperature formaldehyde reforming for hydrogen generation.

Catalytic Processes in Materials ScienceCarbon dioxide utilization in catalysisCatalysis and Oxidation Reactions