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A study on magnesium corrosion by real-time imaging and electrochemical methods: relationship between local processes and hydrogen evolution

Yuan‐Feng Yang、Fabio Scenini、M. Curioni2016-03-11Electrochimica Acta

This work investigates the hydrogen evolution process on magnesium by real time imaging of the corroding surface at the free corrosion potential and during potentiodynamic polarization in alkaline and neutral environments, in the presence and absence of chloride ions. High-magnification imaging of the corrosion proces…

Corrosion Behavior and InhibitionMagnesium Alloys: Properties and ApplicationsHydrogen embrittlement and corrosion behaviors in metals

Investigation of the de-alloying behaviour of θ-phase (Al2Cu) in AA2024-T351 aluminium alloy

X. Zhang、Teruo Hashimoto、J. Lindsay 等 4 位作者2016-03-11Corrosion Science

For multi-phase intermetallic particles consisting of both θ-and S-phase, de-alloying occurred preferentially at S-phase and the de-alloying of θ-phase initiated in the regions surrounding S-phase. The selective dissolution of Al from θ-phase resulted in porous copper-rich θ-phase remnant, comprised of randomly orient…

Corrosion Behavior and InhibitionAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Facile synthesis and photoluminescence characteristics of blue-emitting nitrogen-doped graphene quantum dots

Jian Gu、Xiaoping Zhang、Aimin Pang 等 4 位作者2016-03-11Nanotechnology

A one-step hydrothermal method for synthesizing nitrogen-doped graphene quantum dots (N-GQDs) from organic carbon sources is presented in this paper. The high-quality N-GQDs can be obtained via tuning the degree of dehydration/carbonization of citric acid and doping of nitrogen atoms into the graphene lattice. The mic…

Luminescence and Fluorescent MaterialsCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

MoS 2 –Titanium Contact Interface Reactions

Stephen McDonnell、Christopher M. Smyth、Christopher L. Hinkle 等 4 位作者2016-03-11ACS Applied Materials & Interfaces

The formation of the Ti-MoS2 interface, which is heavily utilized in nanoelectronic device research, is studied by X-ray photoelectron spectroscopy. It is found that, if deposition under high vacuum (∼1 × 10(-6) mbar) as opposed to ultrahigh vacuum (∼1 × 10(-9) mbar) conditions are used, TiO2 forms at the interface ra…

2D Materials and ApplicationsSemiconductor materials and interfacesMXene and MAX Phase Materials

Chitosan and Its Derivatives as Highly Efficient Polymer Ligands

A. V. Pestov、Svetlana Bratskaya2016-03-11Molecules

The polyfunctional nature of chitosan enables its application as a polymer ligand not only for the recovery, separation, and concentration of metal ions, but for the fabrication of a wide spectrum of functional materials. Although unmodified chitosan itself is the unique cationic polysaccharide with very good complexi…

Nanocomposite Films for Food PackagingConducting polymers and applicationsPolymer Surface Interaction Studies

Two-Dimensional Covalent Triazine Framework Membrane for Helium Separation and Hydrogen Purification

Yong Wang、Jinping Li、Qingyuan Yang 等 4 位作者2016-03-11ACS Applied Materials & Interfaces

Ultrathin membranes with intrinsic pores are highly desirable for gas separation applications, because of their controllable pore sizes and homogeneous pore distribution and their intrinsic capacity for high flux. Two-dimensional (2D) covalent organic frameworks (COFs) with layered structures have periodically distrib…

Metal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas TransportCovalent Organic Framework Applications

Graphene quantum dot modified glassy carbon electrode for the determination of doxorubicin hydrochloride in human plasma

Nastaran Hashemzadeh、Mohammad Hasanzadeh、Nasrin Shadjou 等 6 位作者2016-03-11Journal of Pharmaceutical Analysis

Low toxic graphene quantum dot (GQD) was synthesized by pyrolyzing citric acid in alkaline solution and characterized by ultraviolet--visible (UV-vis) spectroscopy, X-ray diffraction (XRD), atomic force microscopy (AFM), spectrofluorimetery and dynamic light scattering (DLS) techniques. GQD was used for electrode modi…

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsCarbon and Quantum Dots Applications

Recent progress in magnesium borohydride Mg(BH4)2: Fundamentals and applications for energy storage

Olena Zavorotynska、Abdel El Kharbachi、Stefano Deledda 等 4 位作者2016-03-11International Journal of Hydrogen Energy

Magnesium borohydride (Mg(BH4)2) shows interesting properties both from fundamental and applicative points of view. Mg(BH4)2 has the most complex crystal structures and the largest number of phase polymorphs among other borohydrides. Some of these polymorphs possess a significant porosity, and on the other hand ultra-…

Hydrogen Storage and MaterialsBoron and Carbon Nanomaterials ResearchSuperconductivity in MgB2 and Alloys

Metal-Catalyzed Chemical Reaction of Single Molecules Directly Probed by Vibrational Spectroscopy

Han-Kyu Choi、Won‐Hwa Park、Chan-Gyu Park 等 6 位作者2016-03-11Journal of the American Chemical Society

The study of heterogeneous catalytic reactions remains a major challenge because it involves a complex network of reaction steps with various intermediates. If the vibrational spectra of individual molecules could be monitored in real time, one could characterize the structures of the intermediates and the time scales…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Average-atom interatomic potential for random alloys

Céline Varvenne、A. Luque、Wolfram G. Nöhring 等 4 位作者2016-03-11Physical review. B./Physical review. B

An average-atom ($A$-atom) embedded-atom-method potential for random multicomponent alloys at any composition is derived analytically and validated by comparing $A$-atom and true random alloys bulk and defect properties, in model Fe-Ni-Cr systems. The $A$-atom can be mixed with the individual alloying-element potentia…

Microstructure and mechanical propertiesHigh Temperature Alloys and CreepIntermetallics and Advanced Alloy Properties

Charge Transport and Electrical Properties of Spin Crossover Materials: Towards Nanoelectronic and Spintronic Devices

Constantin Lefter、Vincent Davesne、Lionel Salmon 等 7 位作者2016-03-11Magnetochemistry

In this paper, we present a comprehensive review of research on electrical and charge transport properties of spin crossover complexes. This includes both the effect of spin-state switching on the dielectric permittivity and electrical conductivity of the material and vice versa the influence of an applied electrical…

Magnetism in coordination complexesMolecular Junctions and NanostructuresLanthanide and Transition Metal Complexes

Controllable Encapsulation of “Clean” Metal Clusters within MOFs through Kinetic Modulation: Towards Advanced Heterogeneous Nanocatalysts

Hongli Liu、Lina Chang、Cuihua Bai 等 6 位作者2016-03-11Angewandte Chemie International Edition

Surfactant-free tiny Pt clusters were successfully encapsulated within MOFs with controllable size and spatial distribution by a novel kinetically modulated one-step strategy. Our synthesis relies on the rational manipulation of the reduction rate of Pt ions and/or the growth rate of MOFs by using H2 as assistant redu…

Metal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials ScienceNanocluster Synthesis and Applications

Enzyme-Instructed Self-Assembly of Small d -Peptides as a Multiple-Step Process for Selectively Killing Cancer Cells

Jie Zhou、Xuewen Du、Natsuko Yamagata 等 4 位作者2016-03-11Journal of the American Chemical Society

Selective inhibition of cancer cells remains a challenge in chemotherapy. Here we report the molecular and cellular validation of enzyme-instructed self-assembly (EISA) as a multiple step process for selectively killing cancer cells that overexpress alkaline phosphatases (ALPs). We design and synthesize two kinds of D…

Advanced biosensing and bioanalysis techniquesSupramolecular Self-Assembly in MaterialsProtein Tyrosine Phosphatases

Phytoremediation Ability of Calotropis procera in Reducing Air Pollution in Jeddah City-Kingdom of Saudi Arabia

Batoul Mohamed Abdullatif、Molouk Mohamed El-Kazan、Maram Ali Al-Zahrani2016-03-10International Journal of Current Microbiology and Applied Sciences

This study was conducted in Northeastern part of Jeddah city. Calotropis procera plant was used as bioindicator and phytoremediator of contamination with heavy metals arising from the cement factory located in this area. Three study sites were chosen, the first site (control) where C. procera plants growing 4.88 km fa…

Clay minerals and soil interactionsPhytochemistry and Bioactive Compounds

Modeling ellipsometric measurement of novel 3D structures with RCWA and FEM simulations

Samuel O’Mullane、Nick Keller、Alain C. Diebold2016-03-10Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Using rigorous coupled wave analysis (RCWA) and finite element method (FEM) simulations together, many interesting ellipsometric measurements can be investigated. This work specifically focuses on simulating copper grating structures that are plasmonically active. Looking at near-field images and Mueller matrix spectr…

Plasmonic and Surface Plasmon ResearchOptical Coatings and GratingsOptical Polarization and Ellipsometry

In situ observation of electrical property of thin-layer black phosphorus based on dry transfer method

Xin Xin、Hai‐Ming Zhao、Hui-Wen Cao 等 6 位作者2016-03-10Applied Physics Express

Abstract The electrical property of thin-layer black phosphorus (BP) was explored using a simple dry transfer method, which greatly reduced the fabrication time to carry out electrical measurement starting from an initial state with little degradation. As a result, the as-prepared BP field-effect transistor (FET) exhi…

Perovskite Materials and Applications2D Materials and ApplicationsMXene and MAX Phase Materials

Silsesquioxane nanocarriers in diagnostics and biomedicine

Kinga Gradzinska、Karolina Labecka、Anna Kowalewska 等 4 位作者2016-03-10Polimery

The paper reviews current literature concerning silsesquioxane nanocomposites as potential nanocarriers in contemporary teranostics. It describes synthetic methods leading to functionalized silsesquioxanes (POSS), including dendrimers as well as organo-inorganic copolymers studied as covalent composites and systems fo…

Electrospun Nanofibers in Biomedical ApplicationsDendrimers and Hyperbranched PolymersSilicone and Siloxane Chemistry

Optimization of the magnetic properties of nanostructured Y-Co-Fe alloys for permanent magnets

P. Tozman、M. Venkatesan、J. M. D. Coey2016-03-10AIP Advances

The structural and magnetic properties of ball-milled Fe-doped Y Co5−xFex(0 ≤ x ≤ 0.5) were investigated. The magnetization increases with Fe-doping up to the solid solubility limit, x = 0.3 without destroying the crystal structure or degrading the coercivity. A special magnet array is designed using ring magnets for…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

The Corrosion Behaviors of the Cerium Conversion Coatings on the Zinc Coating in a 5 % NaCl Solution

Jianghong Zhang、Binfang Meng、Xinying Wang 等 4 位作者2016-03-10High Temperature Materials and Processes

Abstract The present paper investigated the impact of cerium on the corrosion resistance of zinc coating in a 5 % NaCl solution. Electrochemistry was used to measure the electrochemical parameters to compare the corrosion resistance of the zinc coating with that of the cerium conversion coating on the galvanized layer…

Corrosion Behavior and InhibitionMagnesium Alloys: Properties and ApplicationsElectrodeposition and Electroless Coatings