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Chemical modification of polyaniline by N-grafting of polystyrenic chains synthesized via nitroxide-mediated polymerization

Maryam Hatamzadeh、Ali Mahyar、Mehdi Jaymand2012-06-01Journal of the Brazilian Chemical Society

This study aims to explore an effective route for the preparation of conductive N-substituted polyaniline (PANI) by the incorporation of brominated poly(styrene-co-p-methylstyrene) onto the emeraldine form of polyaniline. For this purpose, at first, poly(styrene-co-p-methylstyrene) was synthesized via nitroxide-mediat…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Inhibitory Action of Nicotiana tabacum Extracts on the Corrosion of Mild Steel in HCl: Adsorption and Thermodynamics Study

Emmanuel Folorunso Olasehinde、Sunday J. Olusegun、Adetunji Samuel Adesina 等 5 位作者2012-06-01OpenAlex

The toxic effects of synthetic corrosion inhibitors have led to the search for naturally occurring substances which are not only readily available but are also environmentally friendly. Therefore, this study investigates the inhibition efficacy of acid extract of Nicotiana tabacum leaves on mild steel in 1M HCl using…

Corrosion Behavior and InhibitionInorganic and Organometallic ChemistryConcrete Corrosion and Durability

Novel Approach for Silver Nanoparticle Synthesis Using <I>Aspergillus terreus</I> CZR-1: Mechanism Perspective

Ramesh Raliya、J. C. Tarafdar2012-06-01Journal of Bionanoscience

A novel biological approach for the rapid and cost effective synthesis of silver nanoparticles was attempted in the limelight of nanotechnology research. The present study demonstrates the synthesis of silver nanoparticle using fungus Aspergillus terreus CZR-1 (NCBI GenBank Accession No. JF 681300). The fungal isolate…

Nanoparticles: synthesis and applications

Preparation and application of hydrophobic hybrid monolithic columns containing polyhedral oligomeric silsesquioxanes for capillary electrochromatography

Junjie Ou、Zhenbin Zhang、Hui Lin 等 6 位作者2012-06-01Electrophoresis

Hydrophobic organic-inorganic hybrid monolithic columns were synthesized via thermally initiated free radical polymerization with the confines of 75 μm id capillary using a polyhedral oligomeric silsesquioxane (POSS) reagent containing eight or more methacrylate groups as the crosslinker. Three organic functional mono…

Surface Modification and SuperhydrophobicityAnalytical Chemistry and SensorsSilicone and Siloxane Chemistry

Electronic transport properties on transition-metal terminated zigzag graphene nanoribbons

Can Cao、Lingna Chen、Mengqiu Long 等 5 位作者2012-06-01Journal of Applied Physics

By using non-equilibrium Green’s functions in combination with the density-functional theory, we investigate the spin transport properties of molecular junctions based on 3d transition terminated zigzag graphene nanoribbons. The results show that the electronic transport properties are strongly depending on the type o…

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures

Effects of Methane Cold Plasma in Sisal Fibers

Bruna Barra、Bergo Paulo、Clodomiro Alves 等 5 位作者2012-06-01Key engineering materials

One of the main problems in using vegetable fibers as reinforcement in aggressive cement matrix is the penetration of alkaline products in the porous structure of the filaments, making them very fragile with the time. In this sense a series of physical and chemical methods of surface modification has been used in orde…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical Applications

Synthesis and characterization of high molecular weight polyaniline for organic electronic applications

Praveen C. Ramamurthy、Ashwini N. Mallya、Alex Joseph 等 5 位作者2012-06-01Polymer Engineering and Science

Abstract High molecular weight polyaniline (PANI) was synthesized by a combined procedure incorporating various synthesis methods. Temperature and open circuit potential of the reaction mixture were collected to monitor the reaction progress. The polymer is characterized by various techniques including gel permeation…

Organic Electronics and PhotovoltaicsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Non-linear dynamic thermomechanical behaviour of shape memory alloys

Mohamed Ould Moussa、Ziad Moumni、Olivier Doaré 等 5 位作者2012-06-01Journal of Intelligent Material Systems and Structures

The non-linear dynamic thermomechanical behaviour of superelastic shape memory alloys is investigated. To this end, the Zaki–Moumni model, initially developed for quasi-static loading cases, is extended to simulate the uniaxial forced oscillations of a shape memory alloy device. First, the influence of loading rate is…

Shape Memory Alloy TransformationsElasticity and Material ModelingElasticity and Wave Propagation

Synthesis of Nitrogen-Doped Graphene via Thermal Annealing Graphene with Urea

Xin-jing Li、Xinxin Yu、Jinyang Liu 等 8 位作者2012-06-01Chinese Journal of Chemical Physics

Chemical doping is an effective method to intrinsically modify the chemical and electronic property of graphene. We propose a novel approach to synthesize the nitrogen-doped graphene via thermal annealing graphene with urea, in which the nitrogen source can be controllably released from the urea by varying the anneale…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

On the influence of the architecture of poly(ethylene glycol)-based thermoresponsive polymers on cell adhesion

Katja Uhlig、Björn Boysen、Andreas Lankenau 等 8 位作者2012-06-01Biomicrofluidics

Thermoresponsive polymer surface coatings are a promising tool for cell culture applications. They allow for a mild way of cell detachment that preserves the activity of membrane proteins-a prerequisite for reliable cell analysis. To enlarge the application range of these coatings to cells with different adhesion prop…

Cellular Mechanics and InteractionsPolymer Surface Interaction StudiesNanofabrication and Lithography Techniques

Ab Initio Study of Reaction Pathways Related to Initial Steps of Thermal Decomposition of the Layered Double Hydroxide Compounds

Deyse G. Costa、Alexandre B. Rocha、Wladmir F. Souza 等 5 位作者2012-06-01The Journal of Physical Chemistry C

We present density functional theory (DFT) calculations with periodic boundary conditions combined with thermodynamic and kinetic analyses to study the changes in the [Mg 2/3 Al 1/3 (OH) 2 ](CO 3 ) 1/6 ·2/3H 2 O layered double hydroxide (LDH) over a temperature interval of 25–350 °C. The inspection of five different h…

Layered Double Hydroxides Synthesis and ApplicationsInorganic Chemistry and MaterialsMagnesium Oxide Properties and Applications

Optical Absorption Length, Scattering Length, and Refractive Index of ${\rm LaBr}_{3}\!\!:\!\!{\rm Ce}^{3+}$

Herman T. van Dam、Stefan Seifert、Winicjusz Drozdowski 等 5 位作者2012-06-01IEEE Transactions on Nuclear Science

Despite the large interest in the application of LaBr3:Ce3+, little is known yet about its optical properties, as measurements are hampered by the hygroscopicity of LaBr3:Ce3+and because it is not trivial to produce crystals with optically polished surfaces. Here, the absorption and scattering lengths as well as the r…

Luminescence Properties of Advanced MaterialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Mesoporous Al2O3 by Nanocasting: Relationship between Crystallinity and Mesoscopic Order

Stefanie Haffer、Christian Weinberger、Michael Tiemann2012-06-01European Journal of Inorganic Chemistry

Abstract Crystalline, mesoporous alumina (Al 2 O 3 ) materials with specific surface areas up to 400 m 2 g –1 have been synthesized by means of structure replication (nanocasting) using CMK‐8 carbon as a structure matrix. A crucial step during this synthesis procedure is the conversion of aluminum nitrate into aluminu…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisAerogels and thermal insulation

Study on aging characteristics of silicone rubber insulator sheds using FTIR

Hui Zhang、Youping Tu、Yi Lu 等 6 位作者2012-06-01OpenAlex

In order to explore a method for assessing the aging characteristics of composite insulators, the composite insulators in service were studied using the Fourier Transform Infra-Red (FTIR) test. The influences of several aging factors on the shed materials of composite insulators in service such as shed locations, oper…

High voltage insulation and dielectric phenomena

Thermal–Photovoltaic Hybrid Solar Generator Using Thin-Film Thermoelectric Modules

Mizue Mizoshiri、Masashi Mikami、Kimihiro Ozaki2012-06-01Japanese Journal of Applied Physics

We fabricated thin-film thermoelectric modules for thermal–photovoltaic hybrid solar generator. Bi 0.5 Sb 1.5 Te 3 (p-type) and Bi 2 Te 2.7 Se 0.3 (n-type) thermoelectric thin films were deposited by radio-frequency magnetron sputtering method and patterned to form plane-type thermoelectric modules using lift-off tech…

Advanced Thermoelectric Materials and DevicesSolar Thermal and Photovoltaic SystemsThermal Radiation and Cooling Technologies

Simultaneous measurement of partial discharge using TEV, IEC60270 and UHF techniques

Alistair Reid、M.D. Judd、Graeme Duncan2012-06-01OpenAlex

This paper explores a means of quantifying the relationship between transient earth voltage (TEV), ultra-high-frequency (UHF) and IEC60270 partial discharge (PD) measurements on a pulse-by-pulse basis for well-defined, laboratory-based discharge sources. Since each technique responds differently to the same PD event,…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaElectrostatic Discharge in Electronics

Array of Thermoelectric Coolers for On-Chip Thermal Management

Owen Sullivan、Man Prakash Gupta、Saibal Mukhopadhyay 等 4 位作者2012-06-01Journal of Electronic Packaging

Site-specific on-demand cooling of hot spots in microprocessors can reduce peak temperature and achieve a more uniform thermal profile on chip, thereby improve chip performance and increase the processor’s life time. An array of thermoelectric coolers (TECs) integrated inside an electronic package has the potential to…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Optical, Thermal and Structural Properties of CdS Quantum Dots Synthesized by A Simple Chemical Route

Nida Qutub、S. Sabir2012-06-01International journal of nanoscience and nanotechnology

The present work deals with the synthesis and characterization of CdS nanoparticles with good thermal stability and optical properties by a novel and simple synthetic route. The nanoparticles were synthesized via chemical precipitation method in a single reaction vessel under ambient conditions. The prepared CdS nanop…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Preparation and Characterization of Nano Crystalline Cellulose from Bamboo Fibers by Controlled Cellulase Hydrolysis

Yong Zhang、Xiao-Bin Lu、Chang Gao 等 5 位作者2012-06-01Journal of Fiber Bioengineering and Informatics

The extracellular cellulase enzyme produced by Trichoderma reesei was used to prepare Nanocrystalline Cellulose (NCC) by controlled hydrolysis of bamboo fibers. The morphology of the prepared bamboo cellulose nanocrystals was characterized by field emission scanning electron microscopy and the crystallinity was measur…

Biofuel production and bioconversionNatural Fiber Reinforced CompositesAdvanced Cellulose Research Studies