Materials Literature
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Abstract A unique feature of molecular iodine by far, is its ability to bind to polymeric materials. A plethora of natural and synthetic polymers develop complexes when treated with molecular iodine, or with a mixture of molecular iodine and potassium iodide. Many unexpected findings have been encountered upon complex…
The majority of pure silver nanoparticles in consumer products are likely released into sewer systems and usually end up in wastewater treatment plants (WWTPs). Research investigating the reduction in nanoscale silver particles (n-Ag-Ps) has focused on the biological treatment process, generally in controlled laborato…
A new route consisting of simultaneous centrifugal spinning and solution blowing to form polymer nanofibers is reported. The fiber diameter (60-1000 nm) is shown to be a function of polymer concentration, rotational speed, and working pressure of the processing system. The fiber length is dependent on the rotational s…
The properties of MX enes, a new group of quasi-2D d -metal carbide or nitride nanomaterials derived from the MAX phases by chemical exfoliation, can be very sensitive to the presence of surface functional groups. Herein, the MX enes Ti 2 C and Ti 3 C 2 functionalized by methoxy groups are considered by means of the d…
The effects of cerium oxide (CeO 2 ) and indium oxide (In 2 O 3 ) nanoparticles (NPs) exposure on Arabidopsis thaliana (L.) Heynh. were investigated. After inoculation in half strength MS medium amended with 0–2000 ppm CeO 2 and In 2 O 3 NPs for 25 days, both physiological and molecular responses were evaluated. Expos…
We theoretically investigate light-matter interactions for chiral molecules in the presence of nonchiral nanoantennas. Isotropic nanostructures supporting optical-frequency electric or magnetic dipoles are sufficient to locally enhance the excitation of a molecule's chiral polarizability and thus its circular dichrois…
Particle size is one of the key parameters determining the unexpected catalytic activity of gold, with reactivity improving as the particle gets smaller. While this is valid in the 1-5 nm range, chemists are now investigating the influence of particle size in the subnanometer regime. This is due to recent advances in…
The optical properties of graphene previously used to probe its electronic structure are its optical dispersion and absorption coefficients. Now, scientists report the third-harmonic generation of light in graphene and demonstrate the promise of this nonlinear optical response as a technically versatile microscopic im…
In this work, CuFe2O4 nanospheres with hierarchically porous structure have been synthesized via a facile solvothermal procedure. The superstructures consist of the textured aggregations of nanocrystals with high specific surface area, pore volume, and uniform pore size distribution.To figure out the formation mechani…
Heterogeneous catalysis by metals was among the first enabling technologies that extensively relied on nanoscience. The early intersections of catalysis and nanoscience focused on the synthesis of catalytic materials with high surface to volume ratio. These synthesis strategies mainly involved the impregnation of meta…
We introduce the idea of discontinuous electric and magnetic fields at a boundary to design and shape wavefronts in an arbitrary manner. To create this discontinuity in the field we use orthogonal electric and magnetic currents which act like Huygens source to radiate the desired wavefront. These currents can be synth…
A metasurface lens that focuses light and controls its polarization at a wavelength of 2 μm is presented. This lens demonstrates high transmission and complete phase control within a subwavelength thickness at near-infrared frequencies. By cascading four patterned sheets, the efficiency is dramatically improved over m…
Electronic states at domain walls in bilayer graphene are studied by analyzing their four- and two-band continuum models, by performing numerical calculations on the lattice, and by using quantum geometric arguments. The continuum theories explain the distinct electronic properties of boundary modes localized near dom…
The photoisomerization of azobenzenes provides a general means for the photocontrol of molecular structure and function. For applications in vivo, however, the wavelength of irradiation required for trans-to-cis isomerization of azobenzenes is critical since UV and most visible wavelengths are strongly scattered by ce…
Vascular endothelium offers a variety of therapeutic targets for the treatment of cancer, cardiovascular diseases, inflammation, and oxidative stress. Significant research has been focused on developing agents to target the endothelium in diseased tissues. This includes identification of antibodies against adhesion mo…
Current interest in melanin films derived from the autoxidation of dopamine stems from their use as a universal adhesion layer. Here we report chemical and physical characterization of polydopamine films deposited on gold surfaces from stirred basic solutions at times ranging from 2 to 60 min, with a focus on times ≤1…
Graphene and monolayer transition metal dichalcogenides (TMDs) are promising materials for next-generation ultrathin optoelectronic devices. Although visually transparent, graphene is an excellent sunlight absorber, achieving 2.3% visible light absorbance in just 3.3 Å thickness. TMD monolayers also hold potential as…
Pipelines for reeling are designed to tolerate the large plastic strain associated with the reeling installation process based on widely accepted strain based design principles for subsea pipelines as described in Det Norske Veritas (DNV) Offshore Pipeline Code OS-F101: 2012 [1]. Engineering Critical Assessment (ECA)…
We have studied the photopatterning of a gold surface functionalized with a self-assembled monolayer of an o -nitrobenzyl-based photouncaging ligand bound to the gold surface with a dual thiol anchor. We find that the dose of UV light required to induce the photoreaction on gold is very similar to the dose in an alcoh…
An ultrathin layer is investigated for its potential application of replacing conventional diffusion barriers and promoting interface adhesion for nanoelectric circuits with porous ultralow dielectrics. The porous ultralow dielectric (k ≈ 2.5) substrate is silanized by 3-aminopropyltrimethoxysilane (APTMS) to form the…