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Effect of titanium dioxide nanoparticles on mechanical properties of vinyl ester-based nanocomposites

Hamed Salehian、Seyyed Ahmad Jenabali Jahromi2014-08-14Journal of Composite Materials

The incorporation of nanoparticles into a polymer can lead to a considerable improvement of mechanical properties. Especially, the toughness and stiffness of the nanocomposite can be enhanced at the same time. Therefore, a homogeneous distribution of fillers within the matrix is required. In this research study, the f…

Polymer Nanocomposites and PropertiesDielectric materials and actuatorsPolymer Nanocomposite Synthesis and Irradiation

Exploring the characteristics of sago starch films for pharmaceutical application

Crescentiana Dewi Poeloengasih、Frida Dwi Anggraeni2014-08-14Starch - Stärke

This study investigates the development of sago ( Metroxylon sagu ) starch‐based edible films for potential hard capsule application. In its conduct, films were made with different amount of starch (9, 10, and 11% w/v) and glycerol (25, 30, 35, and 40% w/w starch) by casting method. The films were characterized by phy…

Food composition and propertiesNanocomposite Films for Food PackagingPolysaccharides Composition and Applications

Mechanochromic Luminescence of Fluorenyl‐Substituted Ethylenes

Yun Lv、Yang Liu、Dan Guo 等 6 位作者2014-08-14Chemistry - An Asian Journal

It has been reported several times that some organic luminogens with aggregation-induced emission (AIE) characteristics exhibit the abnormal phenomenon of crystallization-induced blueshift fluorescence, which makes them suitable for utilization as luminescence color-switching materials. Because of the attractive appli…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Enhanced antitumor activity and mechanism of biodegradable polymeric micelles-encapsulated chetomin in both transgenic zebrafish and mouse models

Qinjie Wu、Guo‐You Li、Senyi Deng 等 11 位作者2014-08-14Nanoscale

Chetomin is a promising molecule with anti-tumor activities in the epipolythiodioxopiperazine family of fungal secondary metabolites; however, strong hydrophobicity has limited its further applications. In this work, chetomin was encapsulated into polymeric micelles to obtain an aqueous formulation, and the chetomin l…

Nanoparticle-Based Drug DeliveryAngiogenesis and VEGF in CancerNanoplatforms for cancer theranostics

The damping and flame‐retardant properties of poly(vinyl chloride)/chlorinated butyl rubber multilayered composites

Fengshun Zhang、Guansong He、Kangming Xu 等 5 位作者2014-08-14Journal of Applied Polymer Science

ABSTRACT The alternating multilayered damping composites, which were consisted of chlorinated butyl rubber (CIIR) layers and poly(vinyl chloride) (PVC) layers, were first prepared through multilayered coextrusion technology. The multilayered structure was controlled by adjusting the layer number or the thickness ratio…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesSynthesis and properties of polymers

Polymer Chain Dynamics: Evidence of Nonexponential Mode Relaxation Using Thermally Stimulated Depolarization Current Techniques

S. Arrese-Igor、Ángel Alegría、Juan Colmenero2014-08-14Physical Review Letters

The slowest (p=1) mode relaxation of several polyisoprenes has been experimentally isolated by thermally stimulated depolarization current techniques. Close to the glass transition the p=1 mode deviates from the exponential behavior assumed by Rouse and tube-reptation theories. This effect is found to be a consequence…

Material Dynamics and PropertiesForce Microscopy Techniques and ApplicationsRheology and Fluid Dynamics Studies

Universal scaling of potential energy functions describing intermolecular interactions. II. The halide-water and alkali metal-water interactions

Jasper C. Werhahn、Dai Akase、Sotiris S. Xantheas2014-08-14The Journal of Chemical Physics

The scaled versions of the newly introduced [S. S. Xantheas and J. C. Werhahn, J. Chem. Phys. 141, 064117 (2014)] generalized forms of some popular potential energy functions (PEFs) describing intermolecular interactions--Mie, Lennard-Jones, Morse, and Buckingham exponential-6--have been used to fit the ab initio rela…

Spectroscopy and Quantum Chemical StudiesThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

New azobenzene-based chiral-photochromic substances with thermally stable Z-isomers and their use for the induction of a cholesteric mesophase with a phototunable helix pitch

Alexey Bobrovsky、Alexander Ryabchun、Martin Cigl 等 7 位作者2014-08-14Journal of Materials Chemistry C

Novel photosensitive azobenzene-containing substances with sorbitol- and lactate-based chiral fragments were synthesized to serve as chiral-photochromic dopants in cholesteric mixtures. Owing to the presence of chlorine or methyl lateral substituents in the azobenzene fragment of the dopants, the photoinduced Z-form o…

Liquid Crystal Research AdvancementsPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

Characterization of Reactive Air Brazed Ceramic/Metal Joints with Unadapted Thermal Expansion Behavior

Kirsten Bobzin、Mehmet Öte、Stefanie Wiesner 等 5 位作者2014-08-14Advanced Engineering Materials

Reactive air brazing (RAB) is a promising and economic method for joining ceramic to metal as well as ceramic to ceramic. Hybrid joints gain importance in the field of challenging applications such as gas separation or solid oxide fuel cells. While the ceramic partner is often directly chosen due to its functionality,…

Advanced ceramic materials synthesisAdvancements in Solid Oxide Fuel CellsAdvanced materials and composites

Determination and Correlation of Solubilities of Lauric Acid in Eight Alcohols

Zhihong Yang、Zuoxiang Zeng、Li Sun 等 5 位作者2014-08-14Journal of Chemical & Engineering Data

The solubilities of lauric acid in methanol, ethanol, propanol, n -butanol, n -pentanol, n -hexanol, isobutanol, and isoamylol were measured by synthetic method in the temperature ranging from (276.17 to 306.12) K. Results of these measurements were correlated by the modified Apelblat equation, the λ h equation and ac…

Thermodynamic properties of mixturesCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Toxicity of nanomaterials; an undermined issue

Mehdi Mogharabi‐Manzari、Mohammad Abdollahı、Mohammad Ali Faramarzi2014-08-14DARU Journal of Pharmaceutical Sciences

Nanomaterials are employed in extensive variety of commercial products such as electronic components, cosmetics, food, sports equipment, biomedical applications, and medicine. With the increasing utilization of engineered nanomaterials, the potential exposure of human to nanoparticles is rapidly increasing. Nowadays w…

Nanoparticles: synthesis and applicationsGraphene and Nanomaterials ApplicationsNanotechnology research and applications

Shape Resonances in superconducting gaps in a 2DEG at oxide- oxide interface

A. Bianconi、Davide Innocenti、A. Valletta 等 4 位作者2014-08-14Journal of Physics Conference Series

In multiband superconductivity, the case where the single electron hopping between different Fermi surface spots of different symmetry is forbidden by selection rules is recently attracting a large interest. The focus is addressed to superconductivity made of multiple condensates with different symmetry where the chem…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

The surface-plasmon-resonance and band bending effects on the photoluminescence enhancement of Ag-decorated ZnO nanorods

Li Su、Ni Qin、Weiguang Xie 等 5 位作者2014-08-14Journal of Applied Physics

Doping with noble metal nanoparticles (NPs) is an effective method to tune the photoluminescence (PL) properties of semiconductor materials. The mechanism is widely attributed to the localized surface-plasmon-resonance (SPR) effect of the metal NPs, while the contribution of potential barrier at the interface between…

ZnO doping and propertiesGold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applications

Electrostatic Forces: Formulas for the First Derivatives of a Polarizable, Anisotropic Electrostatic Potential Energy Function Based on Machine Learning

Matthew J. L. Mills、Paul L. A. Popelier2014-08-14Journal of Chemical Theory and Computation

Explicit formulas are derived analytically for the first derivatives of a (i) polarizable, (ii) high-rank multipolar electrostatic potential energy function for (iii) flexible molecules. The potential energy function uses a machine learning method called Kriging to predict the local-frame multipole moments of atoms de…

Protein Structure and DynamicsComputational Drug Discovery MethodsMachine Learning in Materials Science

Transparent half metallic g-C4N3 nanotubes: potential multifunctional applications for spintronics and optical devices

Tao Hu、Arqum Hashmi、Jisang Hong2014-08-14Scientific Reports

Multifunctional material brings many interesting issues because of various potential device applications. Using first principles calculations, we predict that the graphitic carbon nitride (g-C4N3) nanotubes can display multifunctional properties for both spintronics and optical device applications. Very interestingly,…

ZnO doping and properties2D Materials and ApplicationsElectronic and Structural Properties of Oxides

Photoelectron emission from lithiated diamond

Kane M. O’Donnell、T. Martin、Mark T. Edmonds 等 9 位作者2014-08-14physica status solidi (a)

This paper reviews electron emission from negative electron affinity (NEA) diamond and gives account of the recent developments in alternatives to hydrogen‐termination for producing NEA diamond surfaces, particularly using lithium on oxygen‐terminated diamond. We discuss the background and motivation for using alkali…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchElectronic and Structural Properties of Oxides

Influence of carbon nanotube dimensions on the percolation characteristics of carbon nanotube/polymer composites

Khurram Shehzad、Mirza Nadeem Ahmad、Tajamal Hussain 等 9 位作者2014-08-14Journal of Applied Physics

The effect of carbon nanotube aspect ratio (AR) on the percolation characteristics of their polymer composites was investigated by melt blending the multi-wall carbon nanotubes (MWCNTs) with different AR with a thermoplastic elastomer. Previously, most studies reported the effect of aspect ratio of MWCNTs only in the…

Carbon Nanotubes in CompositesConducting polymers and applicationsDielectric materials and actuators

Pyridoxal hydrazonato molybdenum( vi ) complexes: assembly, structure and epoxidation (pre)catalyst testing under solvent-free conditions

Jana Pisk、Biserka Prugovečki、Dubravka Matković‐Čalogović 等 7 位作者2014-08-14RSC Advances

Pyridoxal hydrazonato molybdenum(VI) complexes were prepared by the reaction of the corresponding hydrazone (H2L1 = pyridoxal isonicotinic acid hydrazone, H2L2 = pyridoxal benzhydrazone, H2L3 = pyridoxal 4-hydroxy benzhydrazone) and [MoO2(acac)2] under appropriate conditions. The complexes can be classified into three…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Freestanding composite electrodes of MnO x embedded carbon nanofibers for high-performance supercapacitors

Yuxuan Du、Xin Zhao、Zilong Huang 等 5 位作者2014-08-14RSC Advances

Manganese oxide/carbon nanofiber (MnOx/CNF) composites were successfully fabricated as freestanding electrodes through incorporating different manganese sources of nanostructured MnO2 or Mn(CH3COO)2·4H2O into polyacrylonitrile (PAN) solution by electrospinning and a subsequent carbonization method. The MnO2 with a rod…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Functionalization of Microcrystalline Cellulose with N,N-dimethyldodecylamine for the Removal of Congo Red Dye from an Aqueous Solution

Dongying Hu、Peng Wang、Jian Li 等 4 位作者2014-08-14BioResources

Microcrystalline cellulose (MCC) was functionalized with quaternary amine groups for use as an adsorbent to remove Congo Red dye (CR) from aqueous solution. The ultrasonic pretreatment of MCC was investigated during its functionalization. Characterization was conducted using infrared spectroscopy (FT-IR), X-ray photoe…

Advanced Cellulose Research StudiesDyeing and Modifying Textile FibersNanomaterials for catalytic reactions