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Flow and aggregation of rod-like proteins in slit and cylindrical pores coated with polymer brushes: an insight from dissipative particle dynamics

Zbyšek Posel、Martin Svoboda、Coray M. Colina 等 4 位作者2017-01-01Soft Matter

We use a meso-scale dissipative particle dynamics method to simulate the flow and aggregation of rod-like protein solutions through pores grafted with a solvent-sensitive polymer brush. The coated pores can control protein permeability and aggregation by a stretch-to-collapse conformational transition of the brush pol…

Polymer Surface Interaction StudiesBlock Copolymer Self-AssemblyPickering emulsions and particle stabilization

Efficient activation of a visible light-activatable CA4 prodrug through intermolecular photo-unclick chemistry in mitochondria

Moses Bio、Pallavi Rajaputra、Irene Lim 等 7 位作者2017-01-01Chemical Communications

Photo-unclick chemistry mediates visible and near IR-controlled drug release via a singlet oxygen (SO)-cleavable linker. Due to the limited diffusion distance of SO in biological systems, a photosensitizer and the SO-cleavable linker have been conjugated in one molecule or mixed in nano-drug delivery systems. In this…

Luminescence and Fluorescent MaterialsPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Near-infrared light-emitting devices from individual heavily Ga-doped ZnO microwires

Gaohang He、Mingming Jiang、Lin Dong 等 7 位作者2017-01-01Journal of Materials Chemistry C

Electrically driven near-infrared light-emission from individual heavily Ga-doped ZnO microwires has been achieved, which can be analogous to incandescent sources.

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesNanowire Synthesis and Applications

Electronic transport properties of carbon and boron nitride chain heterojunctions

Yi Zhou、Yifan Li、Jie Li 等 5 位作者2017-01-01Journal of Materials Chemistry C

Long, stable, and free-standing linear atomic carbon chains and boron nitride (BN) chains have been carved out from their 2D sheets recently [Meyer <italic>et al.</italic> , <italic>Nature</italic> , 2008, <bold>454</bold> (7202), 319; Jin <italic>et al. Phys. Rev. Lett.</italic> , 2009, <bold>102</bold> (20), 205501;…

Graphene research and applications2D Materials and ApplicationsMolecular Junctions and Nanostructures

Synthesis of carbon nanodots from waste paper with hydrothermal method

Andi Fadllan、Putut Marwoto、Mahardika Prasetya Aji 等 5 位作者2017-01-01AIP conference proceedings

Synthesis of C-Dots from waste paper has been successfully created. A total of 5 grams of waste paper is mixed with 40 mL aquades, 30 mL H2SO4 and 50 mL NaOH 2 M. A precursor solution is prepared by adding urea in 20 ml of material. Synthesis of C-Dots done by heating the precursor hydrothermally using a furnace with…

Carbon and Quantum Dots ApplicationsNanocluster Synthesis and ApplicationsGraphene and Nanomaterials Applications

Topography preserved microwave plasma etching for top-down layer engineering in MoS 2 and other van der Waals materials

Abin Varghese、Chithra H. Sharma、Madhu Thalakulam2017-01-01Nanoscale

A generic and universal layer engineering strategy for van der Waals (vW) materials, scalable and compatible with the current semiconductor technology, is of paramount importance in realizing all-two-dimensional logic circuits and to move beyond the silicon scaling limit. In this letter, we demonstrate a scalable and…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Morphology transition in helical tubules of a supramolecular gel driven by metal ions

Krishnamoorthy Lalitha、Vellaisamy Sridharan、C. Uma Maheswari 等 5 位作者2017-01-01Chemical Communications

We report a chiral molecular packing with α-helical tubules, and chiral symmetry-breaking upon exposure to metal ions that generated the final ordered structure <italic>via</italic> an <italic>in situ</italic> morphological transition without undergoing any phase change.

Supramolecular Chemistry and ComplexesLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials

Biodistribution of upconversion/magnetic silica-coated NaGdF 4 :Yb 3+ /Er 3+ nanoparticles in mouse models

Uliana Kostiv、Lenka Rajsiglová、Dominika Luptáková 等 12 位作者2017-01-01RSC Advances

Upconversion magnetic nanoparticles emit visible light after NIR irradiation. Gd renders them with MRI contrast. Localization of the particles is excellently visible in blood vasculature of tumor bearing mice after intravenous administration.

Luminescence Properties of Advanced MaterialsNanoplatforms for cancer theranosticsLanthanide and Transition Metal Complexes

One-Pot Aqueous Synthesis of Fluorescent Ag-In-Zn-S Quantum Dot/Polymer Bioconjugates for Multiplex Optical Bioimaging of Glioblastoma Cells

Alexandra A.P. Mansur、Herman S. Mansur、Sandhra M. Carvalho 等 4 位作者2017-01-01Contrast Media & Molecular Imaging

Cancer research has experienced astonishing advances recently, but cancer remains a major threat because it is one of the leading causes of death worldwide. Glioblastoma (GBM) is the most malignant brain tumor, where the early diagnosis is vital for longer survival. Thus, this study reports the synthesis of novel wate…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Improved electrochromic device performance from silver grid on flexible transparent conducting electrode prepared by electrohydrodynamic jet printing

Jieun Lee、Youngwoo Lee、Jinhyeok Ahn 等 7 位作者2017-01-01Journal of Materials Chemistry C

Silver grid printed on ITO film through EHD jet printing as a transparent conducting electrode improves electrochromic performances of soft ECDs.

Conducting polymers and applicationsTransition Metal Oxide NanomaterialsElectrowetting and Microfluidic Technologies

Simultaneous enhancements in the mechanical, thermal stability, and flame retardant properties of poly(1,4-butylene terephthalate) nanocomposites with a novel phosphorus–nitrogen-containing polyhedral oligomeric silsesquioxane

San‐E Zhu、Lili Wang、Mingzhen Wang 等 9 位作者2017-01-01RSC Advances

A novel functionalized POSS greatly reinforced the mechanical, thermal stability, and flame retardant properties of PBT.

Synthesis and characterization of novel inorganic/organometallic compoundsFlame retardant materials and propertiesSilicone and Siloxane Chemistry

Chapter 2. Gadolinium-based Contrast Agents

Lothar Helm、Janet R. Morrow、Christopher J. Bond 等 12 位作者2017-01-01New developments in NMR

In this chapter, the development of efficient GdIII-based agents for MRI is detailed. This chapter is divided into ten sections covering the general theory of the relaxivity of GdIII-based contrast agents; the measurement of longitudinal (T1) and transverse (T2) relaxation times; the theory, acquisition, and interpret…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesMRI in cancer diagnosis

Preparation of P3HB4HB/(Gelatin + PVA) Composite Scaffolds by Coaxial Electrospinning and Its Biocompatibility Evaluation

Minxian Ma、Qin Liu、Chuan Ye 等 6 位作者2017-01-01BioMed Research International

This study was conducted to prepare coaxial electrospun scaffolds of P3HB4HB/(gelatin + PVA) with various concentration ratios with P3HB4HB as the core solution and gelatin + PVA mixture as the shell solution; the mass ratios of gelatin and PVA in each 10 mL shell mixture were 0.6 g : 0.2 g (Group A), 0.4 g : 0.4 g (G…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Hierarchical micro/submicrometer-scale structured scaffolds prepared via coaxial electrospinning for bone regeneration

Chen Tao、Yanxia Zhang、Bin Li 等 4 位作者2017-01-01Journal of Materials Chemistry B

In this study, a cell-free bone tissue engineering scaffold based on core-sheath fibers with micro/submicro-scale structures were fabricated for bone regeneration. The composite fibers were prepared by coaxial electrospinning with cellulose acetate (CA) core solution and a sheath solution consisting of a mixture of si…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

Study of the Optical Properties of Functionalized Gold Nanoparticles in Different Tissues and Their Correlation with the Temperature Increase

A. Carrillo-Cazares、Nallely Jiménez‐Mancilla、Myrna Luna‐Gutiérrez 等 5 位作者2017-01-01Journal of Nanomaterials

Mie theory explains the interaction of light with a gold nanoparticle (AuNP) through the absorption <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" id="M1"><mml:mo stretchy="false">(</mml:mo><mml:msub><mml:mrow><mml:mi>C</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant="normal">a</mml:mi><mml:mi mathvariant="…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsPhotoacoustic and Ultrasonic Imaging

Distinct room-temperature dielectric transition in a perchlorate-based organic–inorganic hybrid perovskite

Yu-Ling Sun、Chao Shi、Wen Zhang2017-01-01Dalton Transactions

hpz = diprotonated homopiperazine) exhibits a distinct room-temperature dielectric transition. The dielectric switching at 303 K is associated with an order-disorder transition of the polar guest cation confined in the cage, corresponding to a dynamic change between motional and frozen states.

Perovskite Materials and ApplicationsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Novel chloride-centered Ag 18 clusters featuring a cuboctahedral Ag 12 skeleton

Hui Shen、Kazuyuki Kubo、Shoko Kume 等 5 位作者2017-01-01Dalton Transactions

, which is well recognized as the Menshutkin reaction. This research provides insights into the dependence of the cluster structure on the nature of the ligand and into the cluster formation mechanism of the Menshutkin reaction.

Gold and Silver Nanoparticles Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications