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Computational and Experimental Study of Thermodynamics of the Reaction of Titania and Water at High Temperatures

Q. N. Nguyen、Charles W. Bauschlicher、Dwight L. Myers 等 5 位作者2017-11-13The Journal of Physical Chemistry A

Gaseous titanium hydroxide and oxyhydroxide species were studied with quantum chemical methods. The results are used in conjunction with an experimental transpiration study of titanium dioxide (TiO 2 ) in water vapor-containing environments at elevated temperatures to provide a thermodynamic description of the Ti(OH)…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsThermal and Kinetic Analysis

A Simplificative Approach‐based Modeling of SOFC Power Systems Fed by Natural Gas

M. Beigzadeh、Fathollah Pourfayaz、Mohammad Hossein Ahmadi 等 5 位作者2017-11-13Fuel Cells

Abstract The fuel cell system is modeled to investigate output factors including voltage, power, and system efficiency for various input elements including different fuel composition, the air and fuel temperature and their utilization ratios. The purpose of this study is to examine the proficiency of a tubular solid o…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Organized Peptidic Nanostructures as Functional Materials

Xuehai Yan、Helmuth Möhwald2017-11-13Biomacromolecules

ADVERTISEMENT RETURN TO ISSUEEditorialNEXTOrganized Peptidic Nanostructures as Functional MaterialsXuehai Yan*†‡§ and Helmuth Möhwald*∥View Author Information† State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China‡ Center for Mesoscience,…

2D Materials and ApplicationsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Spontaneous Microstructure Formation at Water/Paraffin Oil Interfaces

Murielle Schmitt、Ritu Toor、Renaud Denoyel 等 4 位作者2017-11-13Langmuir

An experimental investigation of spontaneous emulsification is proposed with a water drop pendant in a paraffin oil (PO) solution loaded with a surfactant (SPAN80). Optical microscopy in a transmission mode is employed for high-spatial-resolution image recording. The kinetics of spontaneous emulsification is studied.…

Enhanced Oil Recovery TechniquesSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Adsorption Forms of NO on Rhn+ (n = 6–16) Revealed by Infrared Multiple Photon Dissociation Spectroscopy

Toshiaki Nagata、Kohei Koyama、Satoshi Kudoh 等 6 位作者2017-11-13The Journal of Physical Chemistry C

The adsorption of NO on cationic Rh clusters, Rh n + ( n = 6–16), was studied by IRMPD spectroscopy using FELIX in combination with DFT calculations. The IRMPD spectra show that NO adsorbs molecularly on an on-top site of Rh n + for all n studied, while for n = 7, 12, 13, and 14 evidence is found for a second, bridgin…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Synthesis, thermoluminescence and defect centres in Eu3+doped Y2O3nanophosphor for gamma dosimetry applications

N.J. Shivaramu、B.N. Lakshminarasappa、K.R. Nagabhushana 等 5 位作者2017-11-13Materials Research Express

Europium doped Y 2 O 3 nanophosphors have been prepared by the solution combustion method. The prepared nanophosphors were characterized by powder x-ray diffraction (XRD). XRD revealed that the cubic phase with crystallite size in the range 25–37 nm formed. Surface morphology of the samples was studied by field emissi…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesSolid-state spectroscopy and crystallography

Role of lattice oxygen and oxygen vacancy sites in platinum group metal catalysts supported on Sr 3 Fe 2 O 7−δ for NO-selective reduction

Kosuke Beppu、Saburo Hosokawa、Hiroyuki Asakura 等 5 位作者2017-11-13Catalysis Science & Technology

The lattice oxygen in PGM/Sr <sub>3</sub> Fe <sub>2</sub> O <sub>7−δ</sub> contributes to the oxidation of CO and C <sub>3</sub> H <sub>6</sub> and the oxygen vacancy sites can play a role in NO reduction.

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Emission Tuning with Size‐Controllable Polymer Dots from a Single Conjugated Polymer

Jong‐Ho Kim、Taek Seung Lee2017-11-13Small

Two conjugated polymers (CPs) with various compositions of phenylene and benzoselenadiazoben (BSD) are synthesized to have a special emitting property; different fluorescence colors in solution and in the solid states, allowing the resulting conjugated polymer dots (Pdots) to emit different fluorescence colors upon th…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsLuminescence and Fluorescent Materials

Complex Phase Behavior and Network Characteristics of Midblock-Solvated Triblock Copolymers as Physically Cross-Linked Soft Materials

S. Wołoszczuk、Mohammad O. Tuhin、Soumya R. Gade 等 6 位作者2017-11-13ACS Applied Materials & Interfaces

In the presence of a midblock-selective solvent, triblock copolymers not only self-organize but also form a molecular network. Thermoplastic elastomer gels constitute examples of such materials and serve as sealants and adhesives, as well as ballistic, microfluidic, and electroactive media. We perform Monte Carlo and…

Advanced Polymer Synthesis and CharacterizationBlock Copolymer Self-AssemblyPickering emulsions and particle stabilization

Existence of Ti2+ States on the Surface of Heavily Reduced SrTiO3 Nanocubes

Shwetha Shetty、Shyam Kanta Sinha、Rafia Ahmad 等 6 位作者2017-11-13Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTExistence of Ti2+ States on the Surface of Heavily Reduced SrTiO3 NanocubesShwetha Shetty†, Shyam Kanta Sinha‡, Rafia Ahmad†, Abhishek K. Singh†, G. Van Tendeloo‡, and N. Ravishankar*†View Author Information† Materials Research Center, Indian Institute of Science, C. V…

Semiconductor materials and devicesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Optically Detected Magnetic Resonance for Selective Imaging of Diamond Nanoparticles

Margaret E. Robinson、James D. Ng、Huilong Zhang 等 9 位作者2017-11-13Analytical Chemistry

While there is great interest in understanding the fate and transport of nanomaterials in the environment and in biological systems, the detection of nanomaterials in complex matrices by fluorescence methods is complicated by photodegradation, blinking, and the presence of natural organic material and other fluorescen…

Diamond and Carbon-based Materials ResearchForce Microscopy Techniques and ApplicationsQuantum optics and atomic interactions

Water based fluidic radio frequency metamaterials

Xiaobing Cai、Shaolin Zhao、Mingjun Hu 等 6 位作者2017-11-13Journal of Applied Physics

Electromagnetic metamaterials offer great flexibility for wave manipulation and enable exceptional functionality design, ranging from negative refraction, anomalous reflection, super-resolution imaging, transformation optics to cloaking, etc. However, demonstration of metamaterials with unprecedented functionalities i…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Effect of CO2 Laser Treatment on the Fabric Hand of Cotton and Cotton/Polyester Blended Fabric

On-na Hung、Chi Wai Kan2017-11-13Polymers

This paper compares the impact of laser treatment on cotton and cotton/polyester blended fabric hand properties, using the PhabrOmeter system. Five fabric hand properties, namely, stiffness, smoothness, softness, wrinkle recovery rate, and drapability, were obtained, and it was proven that laser treatment could be suc…

Additive Manufacturing and 3D Printing TechnologiesDyeing and Modifying Textile FibersTextile materials and evaluations

Study on the relationship between physicochemical properties and catalytic activity of Mn2O3 nanorods

Pijun Gong、Junlin Xie、De Fang 等 6 位作者2017-11-13Materials Research Express

Selective catalytic reduction technology was considered to be the most effective technology for NO x treatment, and Mn 2 O 3 had good catalytic activity. In this paper, we successfully synthesized α -Mn 2 O 3 and γ -Mn 2 O 3 nanorods by hydrothermal method. Moreover, in order to study the effects of surface physicoche…

Supercapacitor Materials and FabricationCatalytic Processes in Materials ScienceNanomaterials for catalytic reactions

Contrast enhanced quarter-Talbot images

Saifollah Rasouli、Davud Hebri2017-11-13Journal of the Optical Society of America A

In this paper a rigorous mathematical approach to the near-field diffraction of 1D periodic structures at quarter-Talbot distances is presented. At the beginning of the paper, we present a mathematical investigation on the behavior of periodic functions under squaring by the aid of Fourier analysis. We determine suffi…

Optical measurement and interference techniquesAdvanced optical system designOptical Coatings and Gratings

Cobalt Gradient Evolution in Sputtered TiNiCuCo Films for Elastocaloric Cooling

Lars Bumke、Christoph Chluba、Hinnerk Oßmer 等 6 位作者2017-11-13physica status solidi (b)

Elastocaloric cooling demands for temperature changes larger than 30 K to become an alternative to classical vapour compression cooling systems. The principle of active regeneration allows to exceed the materials intrinsic adiabatic temperature change. The resulting temperature gradient of the cooling demonstrator lea…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsHigh Entropy Alloys Studies

Carbon Papers and Aerogels Based on Graphene Layers and Chitosan: Direct Preparation from High Surface Area Graphite

Vincenzina Barbera、Silvia Guerra、Luigi Brambilla 等 8 位作者2017-11-13Biomacromolecules

In this work, carbon papers and aerogels based on graphene layers and chitosan were prepared. They were obtained by mixing chitosan (CS) and a high surface area nanosized graphite (HSAG) in water in the presence of acetic acid. HSAG/CS water dispersions were stable for months. High resolution transmission electron mic…

Graphene research and applicationsSupercapacitor Materials and FabricationAerogels and thermal insulation

Formation Mechanism of Secondary Electron Contrast of Graphene Layers on a Metal Substrate

Kota Shihommatsu、Junro Takahashi、Yuta Momiuchi 等 6 位作者2017-11-13ACS Omega

Scanning electron microscopy (SEM) is widely used to observe graphene on metal substrates. However, the origin of the SEM image contrast of graphene is not well understood. In this work, we performed in situ SEM imaging of layer-number-controlled graphene on a Ni substrate using a high-pass energy filter for secondary…

Graphene research and applicationsElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Protoenzymes: the case of hyperbranched polyesters

Irena Mamajanov、George D. Cody2017-11-13Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences

Enzymes are biopolymeric complexes that catalyse biochemical reactions and shape metabolic pathways. Enzymes usually work with small molecule cofactors that actively participate in reaction mechanisms and complex, usually globular, polymeric structures capable of specific substrate binding, encapsulation and orientati…

RNA Interference and Gene DeliveryChemical Synthesis and AnalysisDendrimers and Hyperbranched Polymers

Porosity-enhanced solar powered hydrogen generation in GaN photoelectrodes

Yaonan Hou、Zohaib Ahmed Syed、L. Jiu 等 5 位作者2017-11-13Applied Physics Letters

Two types of GaN based photoelectrodes using either horizontally aligned or vertically aligned nanopores have been fabricated by means of using an electrochemical etching approach. The photoelectrodes based on such nanostructures have demonstrated an up to 5-fold enhancement in applied bias photon-to-current efficienc…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials