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The Application of the Rare Earths to Magnesium and Titanium Metallurgy in Australia

Arne Biesiekierski、Yuncang Li、Cuié Wen2019-07-02Advanced Materials

Rare earth elements (REEs) have found application in metallurgical processes for nearly a century due to their unique chemical and physical properties but have gained increased attention in recent decades. Notably, the use of these elements may assist in the development of advanced magnesium and titanium products for…

Magnesium Alloys: Properties and ApplicationsAluminum Alloys Composites PropertiesHydrogen Storage and Materials

Micro‐Blooming: Hierarchically Porous Nitrogen‐Doped Carbon Flowers Derived from Metal‐Organic Mesocrystals

Jongkook Hwang、Ralf Walczak、Martin Oschatz 等 5 位作者2019-07-02Small

Abstract Synthesis of 3D flower‐like zinc‐nitrilotriacetic acid (ZnNTA) mesocrystals and their conformal transformation to hierarchically porous N‐doped carbon superstructures is reported. During the solvothermal reaction, 2D nanosheet primary building blocks undergo oriented attachment and mesoscale assembly forming…

Supercapacitor Materials and FabricationLayered Double Hydroxides Synthesis and ApplicationsCovalent Organic Framework Applications

Universal perpendicular orientation of block copolymer microdomains using a filtered plasma

Jinwoo Oh、Hyo Seon Suh、Youngpyo Ko 等 9 位作者2019-07-02Nature Communications

Sub-10 nm patterns prepared by directed self-assembly (DSA) of block copolymer (BCP) thin films offer a breakthrough method to overcome the limitations of photolithography. Perpendicular orientation of the BCP nanostructures is essential for lithographic applications, but dissimilar surface/interfacial energies of two…

Block Copolymer Self-AssemblyFluid Dynamics and Thin FilmsFerroelectric and Negative Capacitance Devices

Synergistic Effect of Covalent Bonding and Physical Encapsulation of Sulfur in the Pores of a Microporous COF to Improve Cycling Performance in Li‐S Batteries

Sergio Royuela、Joaquín Almarza、María J. Mancheño 等 9 位作者2019-07-02Chemistry - A European Journal

Lithium-sulfur batteries stands out as a promising technology for energy storage owing to a combination of favorable characteristics including a high theoretical gravimetric capacity, energy density, inexpensive character, and environmental benignity. Covalent organic frameworks (COFs) are a rapidly developing family…

Advanced Battery Materials and TechnologiesAdvanced battery technologies researchCovalent Organic Framework Applications

An All‐Alkynyl Protected 74‐Nuclei Silver(I)–Copper(I)‐Oxo Nanocluster: Oxo‐Induced Hierarchical Bimetal Aggregation and Anisotropic Surface Ligand Orientation

Yang Yang、Tao Jia、Ying‐Zi Han 等 7 位作者2019-07-02Angewandte Chemie International Edition

Abstract The hardness of oxo ions (O 2− ) means that coinage‐metal (Cu, Ag, Au) clusters supported by oxo ions (O 2− ) are rare. Herein, a novel μ 4 ‐oxo supported all‐alkynyl‐protected silver(I)–copper(I) nanocluster [Ag 74− x Cu x O 12 (PhC≡C) 50 ] ( NC‐1 , avg. x =37.9) is characterized. NC‐1 is the highest nuclear…

Metal-Organic Frameworks: Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

W18O49/Monolayer MoS2 Heterojunction-Enhanced Raman Scattering

Mingze Li、Xingce Fan、Yimeng Gao 等 4 位作者2019-07-02The Journal of Physical Chemistry Letters

Surface-enhanced Raman spectroscopy (SERS), a sensitive analytical technique that has single molecular sensitivity, has attracted continuous attention for both application and academic research. Semiconductor-based substrates with SERS activity present more practical applications, ranging from surface science to biolo…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Liposomal formulation of Galbanic acid improved therapeutic efficacy of pegylated liposomal Doxorubicin in mouse colon carcinoma

Maryam Ebrahimi Nik、Bizhan Malaekeh‐Nikouei、Mohamadreza Amin 等 8 位作者2019-07-02Scientific Reports

Abstract Galbanic acid (Gba), a sesquiterpene coumarin , with strong antiangiogenic activity could serve as an excellent anti-cancer agent. However, Gba is a poor water-solube which hampered its clinical application. In this study, a pegylated liposomal Gba (PLGba) with HSPC/Cholesterol/mPEG 2000 -DSPE (56.2, 38.3, 5.…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsNatural product bioactivities and synthesis

Bio-Catalysis and Biomedical Perspectives of Magnetic Nanoparticles as Versatile Carriers

Muhammad Bilal、Shahid Mehmood、Tahir Rasheed 等 4 位作者2019-07-02Magnetochemistry

In recent years, magnetic nanoparticles (MNPs) have gained increasing attention as versatile carriers because of their unique magnetic properties, biocatalytic functionalities, and capabilities to work at the cellular and molecular level of biological interactions. Moreover, owing to their exceptional functional prope…

Nanoparticle-Based Drug DeliveryNanocluster Synthesis and ApplicationsNanomaterials for catalytic reactions

Influence of manganese on the microstructure and mechanical properties of oxide-dispersion-strengthened steels

Andrews Nsiah Ashong、Min Young Na、Hyoung Chan Kim 等 7 位作者2019-07-02Materials & Design

A novel high-Mn oxide-dispersion-strengthened (ODS) steel, with high cryogenic temperature impact energy, was developed. The effect of Mn content on the microstructure and mechanical properties of ODS steels were examined. The addition of 25 wt.% Mn to ODS steel resulted in transformation from a full ferrite phase to…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsFusion materials and technologies

Synthesis, physico-chemical characterization, antimicrobial activity and toxicological features of Ag ZnO nanoparticles

Liliana Burlibaşa、Mariana Carmen Chifiriuc、Magdalena Valentina Lungu 等 11 位作者2019-07-02Arabian Journal of Chemistry

Silver-zinc oxide nanoparticles (AgZnO NPs) were chemically synthesized by the deposition of Ag NPs on the surface of ZnO NPs using silver nitrate, three types of anionic polyelectrolytes and citric acid as reagents. The Wavelength Dispersive X-ray Fluorescence (WDXRF) spectrometry of AgZnO NPs revealed 0.41–0.69 wt%…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Emerging Bottom‐Up Strategies for the Synthesis of Graphene Nanoribbons and Related Structures

Anthony Jolly、Dandan Miao、Maxime Daigle 等 4 位作者2019-07-02Angewandte Chemie

Abstract The solution‐phase synthesis is one of the most promising strategies for the preparation of well‐defined graphene nanoribbons (GNRs) in large scale. To prepare high quality, defect‐free GNRs, cycloaromatization reactions need to be very efficient, proceed without side reaction and mild enough to accommodate t…

Graphene research and applicationsMolecular Junctions and NanostructuresSynthesis and Properties of Aromatic Compounds

Radiation damage in tungsten from cascade overlap with voids and vacancy clusters

Aslak Fellman、Andrea E. Sand、Jesper Byggmästar 等 4 位作者2019-07-02Journal of Physics Condensed Matter

We have performed a systematic molecular dynamics investigation of the effects of overlap of collision cascades in tungsten with pre-existing vacancy-type defects. In particular, we focus on the implications for fusion neutron irradiated tungsten in relation to comparisons with damage production under ion irradiation…

Fusion materials and technologiesNuclear Materials and PropertiesIon-surface interactions and analysis

Intrinsic Low Thermal Conductivity and Phonon Renormalization Due to Strong Anharmonicity of Single-Crystal Tin Selenide

Joon Sang Kang、Huan Wu、Man Li 等 4 位作者2019-07-02Nano Letters

Two-dimensional (2D) van der Waals material tin selenide (SnSe) has recently attracted intensive interest due to its exceptional thermoelectric performance. However, the thermal properties and phonon transport mechanisms in its single-crystal form remain elusive. Here, we measured high-quality SnSe single crystals usi…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Afterglow, TL and OSL properties of Mn2+-doped ZnGa2O4 phosphor

A. Luchechko、Yaroslav Zhydachevskyy、S. Ubizskii 等 9 位作者2019-07-02Scientific Reports

Abstract Zinc gallate (ZnGa 2 O 4 ) spinel ceramics doped with Mn 2+ ions was prepared by a solid-state reaction at 1200 °C in air. Manganese concentration was equal to 0.05 mol.% of MnO with respect to ZnO. Ceramics produced in this way show an efficient green emission at about 505 nm under UV or X-ray excitations, w…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesNuclear materials and radiation effects

A field-plated Ga2O3 MOSFET with near 2-kV breakdown voltage and 520 mΩ · cm2 on-resistance

Ke Zeng、Abhishek Vaidya、Uttam Singisetti2019-07-02Applied Physics Express

A composite field-plated Ga 2 O 3 MOSFET with highly doped ohmic-capping layer is fabricated. An output current of 20 mA mm −1 and on-resistance of 520 mΩ · cm 2 shows big improvement upon the previous experiment on similar field plated devices. The breakdown voltage is measured to be 1975 V on an L gd = 25 μ m device…

ZnO doping and propertiesGa2O3 and related materialsElectronic and Structural Properties of Oxides

Facile Nanocasting of Dielectric Metasurfaces with Sub-100 nm Resolution

Kwan Kim、Gwanho Yoon、Seungho Baek 等 5 位作者2019-07-02ACS Applied Materials & Interfaces

This work presents a facile nanocasting technique to fabricate dielectric metasurfaces at low cost and high throughput. A flexible polymer mold is replicated from a master mold, and then the polymer mold is used to shape particle-embedded UV-curable polymer resin. The polymer mold is compatible with flexible and curve…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Anti-/Pro-Oxidant Behavior of Naturally Occurring Molecules in Polymers and Biopolymers: A Brief Review

Nadka Tzankova Dintcheva、Francesca D’Anna2019-07-02ACS Sustainable Chemistry & Engineering

Polymers and biopolymers are continuously subjected to the action of different stress factors, such as oxygen, heat, UV light, mechanical stress, humidity, etc., during their processing and service life, undergoing overall oxidative degradation, that causes performance and property deterioration. To improve the resist…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionPolymer Science and PVC

Lignin Nanoparticles as A Promising Way for Enhancing Lignin Flame Retardant Effect in Polylactide

Benjamin Chollet、José‐Marie Lopez‐Cuesta、Fouad Laoutid 等 4 位作者2019-07-02Materials

The present study investigates the effect of using lignin at nanoscale as new flame-retardant additive for polylactide (PLA). Lignin nanoparticles (LNP) were prepared from Kraft lignin microparticles (LMP) through a dissolution-precipitation process. Both micro and nano lignins were functionalized using diethyl chloro…

biodegradable polymer synthesis and propertiesLignin and Wood ChemistryFlame retardant materials and properties

Primary Nucleation-Dominated Chemical Vapor Deposition Growth for Uniform Graphene Monolayers on Dielectric Substrate

Huaping Wang、Xudong Xue、Qianqing Jiang 等 9 位作者2019-07-02Journal of the American Chemical Society

Direct chemical vapor deposition growth of high quality graphene on dielectric substrates holds great promise for practical applications in electronics and optoelectronics. However, graphene growth on dielectrics always suffers from the issues of inhomogeneity and/or poor quality. Here, we first reveal that a novel pr…

Graphene research and applications2D Materials and ApplicationsGraphene and Nanomaterials Applications

Fractal‐Theory‐Based Control of the Shape and Quality of CVD‐Grown 2D Materials

Junzhu Li、Mingguang Chen、Chenhui Zhang 等 10 位作者2019-07-02Advanced Materials

The precise control of the shape and quality of 2D materials during chemical vapor deposition (CVD) processes remains a challenging task, due to a lack of understanding of their underlying growth mechanisms. The existence of a fractal-growth-based mechanism in the CVD synthesis of several 2D materials is revealed, to…

Graphene research and applicationsThermal properties of materialsComposite Material Mechanics