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Synthesis and Characterization of a Novel Self-colored Fluorescent Polycarbonate Urethane based on the 1,8-Naphthalimide Group

Ehsan Zamani、Hossein Yahyaei、Alireza Khosravi 等 5 位作者2019-08-20Journal of Macromolecular Science Part B

The synthesis of a novel self-colored polyurethane (PU) is described using 4-amino-N-propanoic acid-1,8-naphthalimide dye. To synthesize the self- colored PU, the dye was added to the PU prepolymer at the chain extension step. PU and self-colored PU were characterized by using Fourier transform infrared spectroscopy (…

Molecular Sensors and Ion DetectionPolymer composites and self-healingLuminescence and Fluorescent Materials

Effects of Reactivity Ratios on Network Topology and Thermomechanical Properties in Vinyl Ester/Styrene Thermosets: Molecular Dynamics Simulations

Ming Huang、Cameron F. Abrams2019-08-20Macromolecular Theory and Simulations

Abstract Styrene‐based thermoset polymers using vinyl ester crosslinkers offer the potential ability to tune material properties via control of network topology, measured primarily by the distribution of poly(styrene) molecular weight between vinyl esters. Clearly, demonstrating a relationship between topology and pro…

Polymer crystallization and propertiesPolymer composites and self-healingEpoxy Resin Curing Processes

Structural, optical, and magnetic properties of a new system of Bi(Mn0.5Ti0.5)O3-modified Bi0.5Na0.5TiO3 materials

Luong Thi Kim Phuong、Đặng Đức Dũng、Nguyễn Quốc Dũng 等 11 位作者2019-08-20Materials Research Express

Structural, optical, and magnetic properties of a new system of Bi(Mn0.5Ti0.5)O3-modified Bi0.5Na0.5TiO3 materials, Phuong, L T K, Dung, D D, Dung, N Q, Hue, M M, Duong, N X, Luong, P D, Bac, L H, Duc, N A, Trung, N N, Duc, N V, Odkhuu, D

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

One‐Pot Synthesis of Spiropyrans

Lei Zhang、Yawen Deng、Zhenyu Tang 等 7 位作者2019-08-20Asian Journal of Organic Chemistry

Abstract A highly efficient one‐pot synthetic strategy for the preparation of spiropyrans was developed. The method is free of special equipment and operations, and meanwhile, it is energy‐ and time‐saving compared to the reported three‐step procedures. Tolerated with various solvents, bases, aldehydes, and alkyl brom…

Neurobiology and Insect Physiology ResearchPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Soluble Network Polymers Based on Trifunctional Open-cage Silsesquioxanes

Hiroaki Imoto、Ayano Ishida、Mari Hashimoto 等 6 位作者2019-08-20Chemistry Letters

Open-cage silsesquioxanes (IC-POSS, incompletely condensed polyhedral oligomeric silsesquioxane) were herein employed for construction of network polymers by utilizing the open moieties as reactive sites. The obtained polymers were soluble in organic solvents despite the high molecular weights. High thermal stability…

Advanced ceramic materials synthesisSynthesis and properties of polymersSilicone and Siloxane Chemistry

Unique Structural Relaxations and Molecular Conformations of Porphyra-334 at the Excited State

Makoto Hatakeyama、Kenichi Koizumi、Mauro Boero 等 8 位作者2019-08-20The Journal of Physical Chemistry B

Quantum chemistry based simulations were used to examine the excited state of porphyra-334, one of the fundamental mycosporine-like amino acids present in a wide variety of aqueous organisms. Our calculations reveal three characteristic aspects of porphyra-334 related to either its ground or excited state. Specificall…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesLight effects on plants

Bandwidth analysis of AC magnetic field sensing based on electronic spin double-resonance of nitrogen-vacancy centers in diamond

Tatsuma Yamaguchi、Yuichiro Matsuzaki、Shiro Saito 等 7 位作者2019-08-20Japanese Journal of Applied Physics

Abstract We have recently demonstrated an AC magnetic field sensing scheme using a simple continuous-wave optically detected magnetic resonance of nitrogen-vacancy centers in diamond. This scheme is based on electronic spin double-resonance excited by continuous microwave and radiofrequency (RF) fields. Here, we measu…

Quantum and electron transport phenomenaDiamond and Carbon-based Materials ResearchQuantum optics and atomic interactions

Di(pyridin‐4‐yl)aniline Derivatives with a Push‐Pull Electronic Structure: Synthesis and Electrochromic Properties

Chuanwen Zhou、Chunrong Zhu、Zhen‐jie Huang 等 6 位作者2019-08-20ChemistrySelect

Abstract Traditionally, electrochromic materials rely on counter redox materials like ferrocene to realize redox processes. In this work, two novel, closely related series of electrochromic materials bearing push‐pull electronic structure were designed and synthesised (N,N,N’,N’‐tetra(pyridin‐4‐yl)‐1,4‐phenylenediamin…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

Influence of Ni content on impact-abrasion wear resistance of medium-carbon low alloy cast steel

Yongxin Xie、Ying Liu、Hong Guo 等 5 位作者2019-08-20Materials Research Express

Medium-carbon low alloy wear-resistant cast steel with different Ni contents (0.08 mass%, 0.77 mass%, 1.74 mass%, 2.43 mass%) were heat treated at 1050 °C, followed by water quenching and tempering at 250 °C. The influence of Ni content on the microstructure, hardness, impact toughness and abrasive resistance of the c…

Microstructure and Mechanical Properties of SteelsAdvanced materials and compositesMetal Alloys Wear and Properties

Influence of SiO 2 nanoparticles on the dielectric properties and anchoring energy parameters of pure ferroelectric liquid crystal

Abhishek Kumar Misra、Aradhana Roy、Bhupendra Pratap Singh 等 8 位作者2019-08-20Journal of Dispersion Science and Technology

In this study, we have investigated the electrical and anchoring energy of ferroelectric liquid crystal (FLC) with the dispersion of SiO2 nanoparticles (NPs). Due to their higher average spontaneous polarization and helical arrangement of FLC molecules, the molecules strongly interacted to SiO2 NPs which increased the…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPlant Reproductive Biology

Reconstruction of IrO2/(Pb, La)(Zr, Ti)O3 (PLZT) interface by optimization of postdeposition annealing and sputtering conditions

Kenji Nomura、Wensheng Wang、Ko Nakamura 等 12 位作者2019-08-20Journal of Applied Physics

We reconstruct the interface between ferroelectric (FE) lanthanum-doped lead zirconate titanate (PLZT) and an iridium oxide (IrOx) top electrode (TE), taking advantage of the interdiffusion of Ir and Pb during postdeposition annealing. The tetragonal perovskite phase with a low c/a axis ratio at the IrOx/PLZT interfac…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Unconventional phase transition of phase-change-memory materials for optical data storage*

Nian‐Ke Chen、Xianbin Li2019-08-20Chinese Physics B

Recent years, optically controlled phase-change memory draws intensive attention owing to some advanced applications including integrated all-optical nonvolatile memory, in-memory computing, and neuromorphic computing. The light-induced phase transition is the key for this technology. Traditional understanding on the…

Photorefractive and Nonlinear OpticsPhase-change materials and chalcogenidesNonlinear Optical Materials Studies

Investigation of graphene effect on the anti-corrosion behaviour of polyurethane coatings in sea-water

Hai Tan、Deguo Wang、Yanbao Guo2019-08-20Anti-Corrosion Methods and Materials

Purpose Abundant oil and gas reservoirs in the deep-water are the valuable non-renewable energy sources. However, sea-water could enhance the corrosion of marine equipment such as submarine pipe trees. Various coatings, for example, polyurethane (PU) coatings are sprayed on the steel surfaces to enhance the anti-corro…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsHigh voltage insulation and dielectric phenomena

Construction of Layered B3N3-Doped Graphene Sheets from an Acetylenic Compound Containing B3N3 by a Semisynthetic Strategy

Chen Chen、Kangkang Guo、Yaping Zhu 等 6 位作者2019-08-20ACS Applied Materials & Interfaces

The structural modification of graphene at the atomic level is crucial for electrochemical applications. Doping heteroatoms to modify the structure of graphene has widely been adopted. However, the construction and controllable doping of heteroatom-doped graphene remains a challenge. Herein, a novel semisynthetic meth…

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Temperature-Induced Structural Transformations in Undoped and Eu3+-Doped Ruddlesden–Popper Phases Sr2SnO4 and Sr3Sn2O7: Relation to the Impedance and Luminescence Behaviors

Andrius Stanulis、Artūras Katelnikovas、Andrei N. Salak 等 10 位作者2019-08-20Inorganic Chemistry

We report that luminescence of Eu 3+ ion incorporated into Ruddlesden–Popper phases allows monitoring phase transition in powders (instead of single crystals), in a time-efficient manner (compared to neutron diffraction), and importantly, with greater sensitivity than previous methods. Crystal structure and dielectric…

Ferroelectric and Piezoelectric MaterialsAdvanced Condensed Matter PhysicsNuclear materials and radiation effects

A dual‐readout nanosensor based on biomass‐based C‐dots and chitosan@AuNPs with hyaluronic acid for determination of hyaluronidase

Wei Liu、Fang Ding、Yanying Wang 等 8 位作者2019-08-20Luminescence

Abstract A dual‐signal strategy is proposed based on fluorescent biomass‐based carbon dots (BC‐dots) and chitosan stabilized AuNPs (CS@AuNPs) to determine hyaluronidase (HAase). BC‐dots can induce aggregation of CS@AuNPs nanoparticles with a colour change from red to blue. Positively charged CS@AuNPs interacted with t…

Advanced biosensing and bioanalysis techniquesCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Effect of solder and barrier layer elements on the thermoelectric properties of Bi0.5Sb1.5Te3

Hongxing Mi、Ming-Xing Wu、Shen Cao 等 6 位作者2019-08-20Materials Research Express

The interfacial diffusion between the electrode and thermoelectric legs is a key factor to determine thermoelectric (TE) module performance. Metal elements M (Sn, Ni, Ag, Cu) are frequently used in lead-free solder SAC serials and barrier layers. M’s effects on thermoelectric properties are investigated in this work,…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsAdvanced Thermodynamics and Statistical Mechanics

Development of magnesium implants by application of conjoint‐based quality function deployment

Sarah Siefen、Michael Höck2019-08-20Journal of Biomedical Materials Research Part A

Biodegradable magnesium-based implants are the subject of a great deal of research for different orthopedic and vascular applications. The targeted design and properties depend on the specific medical function and location in the body. Development of the biomaterial requires a comprehensive understanding of the biolog…

Bone Tissue Engineering MaterialsMagnesium Alloys: Properties and ApplicationsTitanium Alloys Microstructure and Properties

Exploring Soft Donor Character of the N-2-Pyrazinylmethyl Group by Coordinating Trivalent Actinides and Lanthanides Using Aminopolycarboxylates

Travis S. Grimes、Colt R. Heathman、Santa Jansone‐Popova 等 6 位作者2019-08-20Inorganic Chemistry

The trivalent f-element coordination chemistry of a novel aminopolycarboxylate complexant was investigated. The novel reagent is an octadentate complexant that resembles diethylenetriamine- N, N, N ′, N ″, N ″-pentaacetic acid (DTPA), but a single N -acetate pendant arm was substituted with a N -2-pyrazinylmethyl func…

Magnetism in coordination complexesRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Face‐Centered‐Cubic Ag Nanoclusters: Origins and Consequences of the High Structural Regularity Elucidated by Density Functional Theory Calculations

Ying Lv、Xiangyu Ma、Jinsong Chai 等 5 位作者2019-08-20Chemistry - A European Journal

Abstract Face‐centered‐cubic (FCC) silver nanoclusters (NCs) adopting either cubic or half‐cubic growth modes have been recently reported, but the origin of these atomic assembly patterns and how they are achieved, which would inform our understanding of larger FCC silver nanomaterials, are both unknown. In this study…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications