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Ordered structure of FeGe$_2$ formed during solid-phase epitaxy

B Jenichen、M Hanke、S Gaucher 等 10 位作者2019-07-11arXiv

Fe$_{3}$Si/Ge(Fe,Si)/Fe$_{3}$Si thin film stacks were grown by a combination of molecular beam epitaxy and solid phase epitaxy (Ge on Fe$_{3}$Si). The stacks were analyzed using electron microscopy, electron diffraction, and synchrotron X-ray diffraction. The Ge(Fe,Si) films crystallize in the well oriented, layered t…

Materials Science

Impurity concentration dependent electrical conduction in germanium crystal at low temperatures

Manoranjan Ghosh、Shreyas Pitale、S. G. Singh 等 5 位作者2019-07-11arXiv

Germanium single crystal having 45 mm diameter and 100 mm length of 7N+ purity has been grown by Czochralski method. Structural quality of the crystal has been characterized by Laue diffraction. Electrical conduction and Hall measurements are carried out on samples retrieved from different parts of the crystal along t…

Materials Sciencenucl-ex

Carbon Quantum Dots Codoped with Nitrogen and Lanthanides for Multimodal Imaging

Diego Bouzas‐Ramos、Jesus Cigales Canga、Juan C. Mayo 等 6 位作者2019-07-11Advanced Functional Materials

Abstract Nanoparticles are increasingly being used as advantageous alternatives to commonly used contrast agents in bioimaging, not only due to their improved imaging capabilities but also their great potential in theranostics. Herein, carbon quantum dots (CQDs) codoped with nitrogen and lanthanides (i.e., Gd and Yb)…

Luminescence and Fluorescent MaterialsCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

Inkjet‐Printed High‐Performance Flexible Micro‐Supercapacitors with Porous Nanofiber‐Like Electrode Structures

Tao Cheng、Youwei Wu、Yali Chen 等 6 位作者2019-07-11Small

Abstract Flexible planar micro‐supercapacitors (MSCs) with unique loose and porous nanofiber‐like electrode structures are fabricated by combining electrochemical deposition with inkjet printing. Benefiting from the resulting porous nanofiber‐like structures, the areal capacitance of the inkjet‐printed flexible planar…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Beyond Graphene: Chemistry of Group 14 Graphene Analogues: Silicene, Germanene, and Stanene

Tomáš Hartman、Zdeněk Sofer2019-07-11ACS Nano

Two-dimensional materials have been extensively studied over the last two decades as they represent a class of materials with properties applicable in catalysis, sensing, optical devices, nanoelectronics, supercapacitors, and semiconductors. The properties of 2D materials can be tuned by exfoliation into mono- or few-…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Mesoporous silica nanoparticles for tissue‐engineering applications

Liang Chen、Xiaojun Zhou、Chuanglong He2019-07-11Wiley Interdisciplinary Reviews Nanomedicine and Nanobiotechnology

Mesoporous silica nanoparticles (MSNs) have been widely investigated as a nanocarrier for the delivery of various cargoes in nanomedicine. The application of MSNs in tissue engineering is a relatively newly emerged field that has gained much research interest. In this review, the recent advances in the tissue-engineer…

Bone Tissue Engineering MaterialsMesoporous Materials and CatalysisAerogels and thermal insulation

Antioxidant, antimicrobial and cytotoxic activities of gold nanoparticles capped with quercetin

Felipe Guzansky Milanezi、Leandra Martins Meireles、Marcella Malavazi de Christo Scherer 等 10 位作者2019-07-11Saudi Pharmaceutical Journal

In the present work, we report the antioxidant, antimicrobial and cytotoxic activities of quercetin-capped gold nanoparticles (AuNPsQct). The synthesis of AuNPsQct was confirmed by UV–Vis spectroscopy, FTIR and transmission electron microscopy (TEM) analyses. The FTIR spectrum showed the integrity of the quercetin mol…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsFree Radicals and Antioxidants

Revealing the intrinsic nature of the mid-gap defects in amorphous Ge2Sb2Te5

Konstantinos Konstantinou、Felix C. Mocanu、Tae-Hoon Lee 等 4 位作者2019-07-11Nature Communications

Abstract Understanding the relation between the time-dependent resistance drift in the amorphous state of phase-change materials and the localised states in the band gap of the glass is crucial for the development of memory devices with increased storage density. Here a machine-learned interatomic potential is utilise…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesNonlinear Optical Materials Studies

Cellulose Nanofiber @ Conductive Metal–Organic Frameworks for High-Performance Flexible Supercapacitors

Shengyang Zhou、Xueying Kong、Bing Zheng 等 6 位作者2019-07-11OpenAlex

Conductive metal–organic frameworks (c-MOFs) show great potential in electrochemical energy storage thanks to their high electrical conductivity and highly accessible surface areas. However, there are significant challenges in processing c-MOFs for practical applications. Here, we report on the fabrication of c-MOF na…

Supercapacitor Materials and FabricationElectrospun Nanofibers in Biomedical ApplicationsMXene and MAX Phase Materials

Edge Capping of 2D‐MXene Sheets with Polyanionic Salts To Mitigate Oxidation in Aqueous Colloidal Suspensions

Varun Natu、James L. Hart、Maxim Sokol 等 6 位作者2019-07-11OpenAlex

Abstract MXenes have shown promise in myriad applications, such as energy storage, catalysis, EMI shielding, among many others. However, MXene oxidation in aqueous colloidal suspensions when stored in water at ambient conditions remains a challenge. It is now shown that by simply capping the edges of individual MXene…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Global Optimization of Dielectric Metasurfaces Using a Physics-Driven Neural Network

Jiaqi Jiang、Jonathan A. Fan2019-07-11OpenAlex

We present a global optimizer, based on a conditional generative neural network, which can output ensembles of highly efficient topology-optimized metasurfaces operating across a range of parameters. A key feature of the network is that it initially generates a distribution of devices that broadly samples the design s…

Metamaterials and Metasurfaces ApplicationsPhotonic Crystals and ApplicationsAdvanced Antenna and Metasurface Technologies

Bimodal Probe for Magnetic Resonance Imaging and Photoacoustic Imaging Based on a PCTA‐Derived Gadolinium(III) Complex and ZW800–1

Marie Devreux、Céline Henoumont、Fabienne Dioury 等 9 位作者2019-07-10European Journal of Inorganic Chemistry

Abstract Invited for the cover of this issue is the group of Sophie Laurent from the University of Mons, Belgium. The cover image shows a blood vessel containing the bimodal probe reported in this paper.

Metal-Organic Frameworks: Synthesis and ApplicationsNanoplatforms for cancer theranosticsLanthanide and Transition Metal Complexes

Modelling of a Reversible SOC in Ansys Fluent

Stephan Herrmann、Zhan Zhoon Ong、Maximilian Hauck 等 8 位作者2019-07-10ECS Transactions

Reversible Solid Oxide Cells (SOC) are quite susceptible to variations in operating parameters, and especially the switching of operating modes is not yet well understood. Effects like thermal stress from changes in the current density pattern, as well as carbon deposition and nickel oxidation can destroy SOC. Thus, i…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsCatalysis and Oxidation Reactions

Alternative Ni-Alloy Cermet Anode Materials for SOFCs

Yusuke Ishibashi、Shotaro Futamura、Yuya Tachikawa 等 7 位作者2019-07-10ECS Transactions

Solid oxide fuel cell (SOFC) is a promising electrochemical energy conversion device that can directly produce electricity from chemical fuels. On the other hand, in the Ni-zirconia cermet currently used for the SOFC anode, the electron conducting pathways through the Ni metal phase can be easily destroyed by redox pr…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Proposal of a Modified Four-Point Bending Method for Determining Interfacial Fracture Energy at Electrode/Electrolyte Interfaces in SOFCs

Keigo KUMADA、Kazuhisa Sato、Yuki Asoh 等 4 位作者2019-07-10ECS Transactions

This study proposes the use of all-ceramic modified four-point bending specimens consisting of a thin porous electrode layer sandwiched between two dense electrolyte beams to determine the fracture energy of the electrolyte/electrode interface. The sandwich arrangement was effective to prevent the premature vertical c…

Corrosion Behavior and InhibitionFuel Cells and Related MaterialsHydrogen embrittlement and corrosion behaviors in metals

Operando Studies of Carbon Removal and Partial Oxidation in Solid Oxide Fuel Cells

William A. Maza、Stanislav Tsoi、Daniel A. Steinhurst 等 6 位作者2019-07-10ECS Transactions

Operando methods, including thermal imaging, infrared emission and Raman spectroscopy, are combined with simultaneous electrochemical measurements to characterize carbon removal and partial oxidation of methane on Ni/YSZ anodes of operating solid oxide fuel cells (SOFCs). Results for carbon removal indicate that the C…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel Cells

Operando NAP-HT-XPS and Impedance Spectroscopy Study of Pulsed Laser Deposited Ni-Ce0.9Gd0.1O2-δ Solid Oxide Fuel Cell Electrode

Gunnar Nurk、Kuno Kooser、Ove Korjus 等 16 位作者2019-07-10ECS Transactions

Detailed chemical information from electrode surfaces at operating conditions is essential for rational development of solid oxide cell (SOC) electrodes but so far, because of harsh operating conditions very little is known about mechanistic aspects of surface reactions as well as surface thermodynamics at SOC electro…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Hydrogen Oxidation Activity of SOFC Anodes with Metal Oxide Addition

Naoya Fujiwara、Taro Kayamori、Tomohiro Mishina 等 6 位作者2019-07-10ECS Transactions

Metal oxide addition is one of the major techniques to improve the performance of SOFC cermet anodes. However, the effects of the metal oxide addition on hydrogen oxidation activity of the anodes have not been clarified so far. In this study, Ni-CaO/YSZ anodes were prepared to examine the interaction between YSZ and C…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Pressurized Ammonia and Syngas Planar Anode-Supported Solid Oxide Fuel Cells and Their Performance Stability Test

S.S. Shy、Yung‐Tse Hung、Zhiling Chou 等 5 位作者2019-07-10ECS Transactions

This paper reports a stability test comparison between ammonia- and syngas-fueled anode-supported cells (ASC). The planar (50 x 50 mm 2 ) ASC is consisted of 400-mm-Ni-YSZ anode, 3-mm-YSZ electrolyte, and 12-mm-LSC-GDC cathode together with metallic frames and current collectors which are sandwiched by a pair of rib-c…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

An Improvement of Efficiency and Toughness of Solid Oxide Fuel Cells by Industry-Academia Collaboration

Teruhisa Horita2019-07-10ECS Transactions

An improvement of efficiency is one of the important technological issues to realize the distribution of SOFC technology. The NEDO has initiated the project on high efficiency and toughness of SOFC cell-stacks from 2018 to 2019. The target of this project is (1) making a concept for high-efficient SOFC cell-stacks ove…

Advancements in Solid Oxide Fuel Cells