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Influence of the Defect Concentration of Ceria on the Pt Dispersion and the CO Oxidation Activity of Pt/CeO2

Jaeha Lee、YoungSeok Ryou、Jong‐Hyun Kim 等 6 位作者2018-02-14The Journal of Physical Chemistry C

The CO oxidation ability can be modulated by controlling the metal–support interaction of Pt/CeO 2 catalysts. The Pt/(800C)CeO 2 sample prepared by the thermal treatment of ceria at 800 °C before loading Pt maintained the much higher Pt dispersion than Pt/γ-Al 2 O 3 after the thermal aging at 800 °C, indicating its ex…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Polymeric Nanocomposites (PNCs) for Wastewater Remediation: An Overview

Michael Ovbare Akharame、Olalekan S. Fatoki、Beatrice Olutoyin Opeolu 等 5 位作者2018-02-14Polymer-Plastics Technology and Engineering

A decline in the world’s freshwater resources poses a major domestic and industrial challenge. Amelioration efforts that proffer possible water management and reclamation technology is therefore, of utmost priority. One of the most promising solutions to water conservation is to recycle wastewater. The use of polymeri…

Membrane Separation TechnologiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Effect of Cation–π Interaction on Macroionic Self‐Assembly

Jiancheng Luo、Kun Chen、Panchao Yin 等 11 位作者2018-02-14Angewandte Chemie International Edition

Abstract A series of rod‐shaped polyoxometalates (POMs) [Bu 4 N] 7 [Mo 6 O 18 NC(CH 2 O) 3 MnMo 6 O 18 (OCH 2 ) 3 CNMo 6 O 18 ] and [Bu 4 N] 7 [ArNMo 6 O 17 NC(CH 2 O) 3 MnMo 6 O 18 (OCH 2 ) 3 CNMo 6 O 17 NAr] (Ar=2,6‐dimethylphenyl, naphthyl and 1‐methylnaphthyl) were chosen to study the effects of cation–π interacti…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsCovalent Organic Framework Applications

Investigation of different physical aspects such as structural, mechanical, optical properties and Debye temperature of Fe2ScM (M=P and As) semiconductors: A DFT-based first principles study

Md. Lokman Ali、Md. Zahidur Rahaman2018-02-14International Journal of Modern Physics B

By using first principles calculation dependent on the density functional theory (DFT), we have investigated the mechanical, structural properties and the Debye temperature of Fe 2 ScM (M=P and As) compounds under various pressures up to 60 GPa. The optical properties have been investigated under zero pressure. Our ca…

Boron and Carbon Nanomaterials ResearchMXene and MAX Phase MaterialsHeusler alloys: electronic and magnetic properties

Genomic perspectives of spider silk genes through target capture sequencing: Conservation of stabilization mechanisms and homology-based structural models of spidroin terminal regions

Matthew A. Collin、Thomas H. Clarke、Nadia A. Ayoub 等 4 位作者2018-02-14International Journal of Biological Macromolecules

A powerful system for studying protein aggregation, particularly rapid self-assembly, is spider silk. Spider silks are proteinaceous and silk proteins are synthesized and stored within silk glands as liquid dope. As needed, liquid dope is near-instantaneously transformed into solid fibers or viscous adhesives. The dom…

Insect and Arachnid Ecology and BehaviorSilk-based biomaterials and applicationsBiochemical and Structural Characterization

Biodegradable Synthetic Antimicrobial with Aggregation-Induced Emissive Luminogens for Temporal Antibacterial Activity and Facile Bacteria Detection

Shuai Chen、Qixian Chen、Qiaoying Li 等 7 位作者2018-02-14Chemistry of Materials

Aiming to address the antimicrobial resistance and environmental burdens because of the widespread indulgence in biocides, a synthetic formula of biocides with controllable antibacterial activities and biodegradable characters are encouraged for the emergence of a novel spectrum of green biocides. In this respect, a p…

Antimicrobial Peptides and ActivitiesLuminescence and Fluorescent MaterialsAntimicrobial agents and applications

Enzymatic stimuli‐responsive methotrexate‐conjugated magnetic nanoparticles for target delivery to breast cancer cells and release study in lysosomal condition

Hamed Nosrati、Amir Mojtahedi、Hossein Danafar 等 4 位作者2018-02-14Journal of Biomedical Materials Research Part A

In this study, magnetic nanoparticles (MNPs) coated with glycine (F-Gly NPs) and conjugated with methotrexate (MTX) (F-Gly-MTX NPs) were synthesized through a coprecipitation method followed by amidation reaction between the carboxylic acid end groups on MTX and the amine groups on the MNPs surface and studied its cyt…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsGraphene and Nanomaterials Applications

Influence of synthetic conditions on the performance of melamine–phenol–formaldehyde resin microcapsules

Zun-Xiang Hu、Xiangming Hu、Weimin Cheng 等 4 位作者2018-02-14High Performance Polymers

Melamine (M), phenol (P) and formaldehyde (F) were used as raw materials to synthesize a melamine–phenol–formaldehyde resin (MPF) which was used as shell material to prepare a self-healing microcapsule with E-51 epoxy resin as the core, via in situ polymerization. Fourier transform infrared spectroscopy, environmental…

Polymer composites and self-healingLignin and Wood ChemistryFlame retardant materials and properties

Symmetry-Breaking Charge Transfer in Boron Dipyridylmethene (DIPYR) Dimers

Jessica H. Golden、Laura Estergreen、Tyler M. Porter 等 9 位作者2018-02-14ACS Applied Energy Materials

We recently reported the photophysical properties of boron dipyridylmethene (DIPYR) dyes, a class of intensely fluorescent pyridine-based chromophores, which are structural analogues of both acenes and BODIPYs. In this work, we endeavored to explore the properties of DIPYR dimers. The synthesis and characterization of…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Bio-inspired Edible Superhydrophobic Interface for Reducing Residual Liquid Food

Yao Li、Jingran Bi、Siqi Wang 等 9 位作者2018-02-14Journal of Agricultural and Food Chemistry

Significant wastage of residual liquid food, such as milk, yogurt, and honey, in food containers has attracted great attention. In this work, a bio-inspired edible superhydrophobic interface was fabricated using U.S. Food and Drug Administration-approved and edible honeycomb wax, arabic gum, and gelatin by a simple an…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

A Series of Banana-Shaped 3d-4f Heterometallic Cluster Substituted Polyoxometalates: Syntheses, Crystal Structures, and Magnetic Properties

Ya-Nan Gu、Yi Chen、Yan‐Lan Wu 等 5 位作者2018-02-14Inorganic Chemistry

Four seven-nuclearity 3d-4f heterometallic cluster {Fe 6 LnO 28 } substituted polyoxometalates (HPz) 11 K 4 Fe 6 Ln(μ 3 -O) 2 (B-α-GeW 9 O 34 ) 2 (GeW 6 O 26 )· x H 2 O ( 1-Ln, Pz = piperazine, Ln = Tb, Dy, Ho, Er for x = 27, 25, 25, 24, respectively) have been hydrothermally prepared and structurally characterized by…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications

Photoinduced Proton Transfer between Photoacid and pH‐Sensitive Dyes: Influence Factors and Application for Visible‐Light‐Responsive Rewritable Paper

Ting Zhang、Lan Sheng、Junning Liu 等 9 位作者2018-02-14Advanced Functional Materials

Abstract Ink‐free printing based on rewritable paper is an efficient and environmental friendly way to reuse paper, protect resources, and save energy for sustainable development of human society. Among various kinds of rewritable media, light responsive rewritable paper (LRP) is one of the most popular research areas…

Luminescence and Fluorescent MaterialsPhotochromic and Fluorescence ChemistryElectrowetting and Microfluidic Technologies

Pr-Doped CeO 2 Catalyst in the Prins Condensation–Hydrolysis Reaction: Are All of the Defect Sites Catalytically Active?

Zhixin Zhang、Yehong Wang、Jianmin Lü 等 7 位作者2018-02-14ACS Catalysis

Defect chemistries of metal-doped CeO 2 catalysts have attracted extensive scientific interests in heterogeneous catalysis. Here, we report the structure–activity relationship of CeO 2 catalysts doped by Pr. The Pr-doped CeO 2 solid solution catalysts were prepared by a coprecipitation method and evaluated in Prins co…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Yellow-Emissive Carbon Dot-Based Optical Sensing Platforms: Cell Imaging and Analytical Applications for Biocatalytic Reactions

Hongxia Li、Xu Yan、Shanpeng Qiao 等 5 位作者2018-02-14ACS Applied Materials & Interfaces

Carbon dots (CDs) have attracted increasing interest in bioimaging and sensing recently. Herein, we present a simple synthetic strategy to prepare yellow-emissive CDs (λ em = 535 nm) by one-pot hydrothermal treatment of p -phenylenediamine and aspartic acid. The as-prepared CDs possess outstanding optical features, ex…

Carbon and Quantum Dots ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Influence of an Al2O3 interlayer in a directly grown graphene-silicon Schottky junction solar cell

Malik Abdul Rehman、Imtisal Akhtar、Woosuk Choi 等 10 位作者2018-02-14Carbon

Graphene/Si Schottky junction solar cells are widely studied in relation to the harvesting of solar energy, but high efficiency is limited due to surface recombination at the interface. Moreover, surface defects, wrinkles, and impurities may arise during the wet transfer process of graphene. We propose an easy approac…

Graphene research and applicationsNanowire Synthesis and ApplicationsSemiconductor materials and interfaces

Electrospun Poly(lactic acid)-Based Fibrous Nanocomposite Reinforced by Cellulose Nanocrystals: Impact of Fiber Uniaxial Alignment on Microstructure and Mechanical Properties

Siqi Huan、Guoxiang Liu、Wanli Cheng 等 5 位作者2018-02-14Biomacromolecules

Uniform poly(lactic acid)/cellulose nanocrystal (PLA/CNC) fibrous mats composed of either random or aligned fibers reinforced with up to 20 wt % CNCs were successfully produced by two different electrospinning processes. Various concentrations of CNCs could be stably dispersed in PLA solution prior to fiber manufactur…

Advanced Cellulose Research Studiesbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Ab initio Eliashberg Theory: Making Genuine Predictions of Superconducting Features

Antonio Sanna、José A. Flores‐Livas、Arkadiy Davydov 等 7 位作者2018-02-14Journal of the Physical Society of Japan

We present an application of Eliashberg theory of superconductivity to study a set of novel superconducting systems with a wide range of structural and chemical properties. The set includes three intercalated group-IV honeycomb layered structures, SH3 at 200 GPa (the superconductor with the highest measured critical t…

Iron-based superconductors researchSuperconductivity in MgB2 and AlloysInorganic Chemistry and Materials

Characterization of titanium dioxide and zinc oxide nanoparticles in sunscreen powder by comparing different measurement methods

Pei-Jia Lu、Shaoyi Fang、Wei Cheng 等 6 位作者2018-02-14Journal of Food and Drug Analysis

Numerous consumer products, such as cosmetics, contain nanoparticles (NPs) of titanium dioxide (TiO 2 ) or zinc oxide (ZnO); however, this raises questions concerning the safety of such additives. Most of these products do not indicate whether the product includes NPs. In this study, we characterized metal oxide NPs a…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsMicroplastics and Plastic Pollution

Toxicity of PEG-Coated CoFe2O4 Nanoparticles with Treatment Effect of Curcumin

Shahnaz Akhtar、Wenzhen An、Xiaoying Niu 等 8 位作者2018-02-14Nanoscale Research Letters

In this work, CoFe 2 O 4 nanoparticles coated with polyethylene glycol (PEG) were successfully synthesized via a hydrothermal technique. Morphological studies of the samples confirmed the formation of polycrystalline pure-phase PEG-CoFe 2 O 4 nanoparticles with sizes of about 24 nm. Toxicity induced by CoFe 2 O 4 nano…

Nanoparticle-Based Drug DeliveryNanomaterials for catalytic reactionsGraphene and Nanomaterials Applications

Bioactive polydimethylsiloxane surface for optimal human mesenchymal stem cell sheet culture

Zichen Qian、David Ross、Wenkai Jia 等 5 位作者2018-02-14Bioactive Materials

Human mesenchymal stem cell (hMSC) sheets hold great potential in engineering three-dimensional (3D) completely biological tissues for diverse applications. Conventional cell sheet culturing methods employing thermoresponsive surfaces are cost ineffective, and rely heavily on available facilities. In this study, a cos…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine