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Fabrication of MgO–rGO hybrid catalysts with a sandwich structure for enhanced ethylbenzene dehydrogenation performance

Jiangyong Diao、Yajie Zhang、Jiayun Zhang 等 6 位作者2017-01-01Chemical Communications

MgO-rGO hybrid catalysts with a sandwich structure have been successfully prepared through a simple "solid-solid" method. Obviously enhanced reactivity is observed on the hybrid catalysts in ethylbenzene dehydrogenation reactions, which is attributed to the sandwich structure and the synergistic effect between MgO and…

Catalytic Processes in Materials ScienceHydrogen Storage and MaterialsCatalysis and Oxidation Reactions

Bond dissociation energy controlled σ-bond metathesis in alkaline-earth-metal hydride catalyzed dehydrocoupling of amines and boranes: a theoretical study

Dongdong Xu、Chunhui Shan、Yingzi Li 等 7 位作者2017-01-01Inorganic Chemistry Frontiers

Alkaline-earth-metal could catalyse the dehydrocoupling procedure of N–H and B–H bond due to the low Ae–H bond energy. The direct σ-bond metathesis procedure is proved to be unfavourable.

Hydrogen Storage and MaterialsCarbon dioxide utilization in catalysisInorganic Chemistry and Materials

Effect of transformer oil on room temperature vulcanized silicone rubber

Xishan Wen、Xiaoqing Yuan、Lei Lan 等 7 位作者2017-01-01IEEE Transactions on Dielectrics and Electrical Insulation

Concerns over the operation safety of power transformers have triggered an application of room temperature vulcanized (RTV) silicone rubber on transformer bushings. However, transformer oil may cause a severe deterioration in the performance of RTV silicone rubber coatings due to oil leakage. Little attention has been…

High voltage insulation and dielectric phenomenaDielectric materials and actuatorsSilicone and Siloxane Chemistry

Reduction Reactions on Iron Sulfides in Aqueous Acidic Solutions

Saba Navabzadeh Esmaeely、Srdjan Nešić2017-01-01Journal of The Electrochemical Society

Iron sulfide corrosion product layers commonly form on mild steel surfaces corroding in aqueous H 2 S environments. These porous layers present a barrier which may reduce the corrosion rate, however, their semi-conductive nature leads to an acceleration of corrosion via galvanic coupling, by increasing the cathodic su…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsMetal Extraction and Bioleaching

Heavy metal detoxification by recombinant ferritin from Apostichopus japonicus

Kaixue Si、Tinghong Ming、Yanyan Li 等 10 位作者2017-01-01RSC Advances

Ferritin from <italic>Apostichopus japonicas</italic> showed better ability in heavy metal detoxification than horse spleen ferritin.

Parasite Biology and Host InteractionsMarine Bivalve and Aquaculture StudiesCalcium Carbonate Crystallization and Inhibition

Rapid thermal thinning of black phosphorus

Shuangqing Fan、Haicheng Hei、Chunhua An 等 8 位作者2017-01-01Journal of Materials Chemistry C

Two-step rapid thermal thinning obtains monolayer black phosphorus with a high surface quality.

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Fabrication of an l -glutathione sensor based on PEG-conjugated functionalized CNT nanocomposites: a real sample analysis

Mohammed M. Rahman、Mahmoud A. Hussein、Mohamed Abdel Salam 等 4 位作者2017-01-01New Journal of Chemistry

Three series of polyethylene glycol–carbon nanotube nanocomposites in the form of PEG/CNT <sub>a–e</sub> , PEG/f-CNT.Oxi <sub>a–e</sub> , and PEG/CNT.C <sub>18a–e</sub> have been fabricated using a dissolution stirring ultra-sonication method.

Conducting polymers and applicationsLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors

Aggregation-induced emission in precursors to porous molecular crystals

Zhenglin Zhang、Mohamed I. Hashim、Ognjen Š. Miljanić2017-01-01Chemical Communications

Trigonal fluorinated pyrazoles assemble into porous molecular crystals and show solid-state fluorescence. However, their emission behavior in solution is dramatically different.

Molecular Sensors and Ion DetectionOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Long-range surface plasmon resonance and surface-enhanced Raman scattering on X-shaped gold plasmonic nanohole arrays

C. Hou、Daniel David Galvan、Guowen Meng 等 4 位作者2017-01-01Physical Chemistry Chemical Physics

A multilayered architecture including a thin Au film supporting an X-shaped nanohole array and a thick continuous Au film separated by a Cytop dielectric layer is reported in this work. Long-range surface plasmon resonance (LR-SPR) was generated at the top Au/water interface, which also resulted in a long-range surfac…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchOrbital Angular Momentum in Optics

A new understanding of the failure of waterborne acrylic coatings

Hongxia Wan、Dongdong Song、Xiaogang Li 等 6 位作者2017-01-01RSC Advances

Two waterborne coatings, a styrene–acrylic coating and a terpolymer coating based on acrylic acid, vinyl chloride and 1,1-dichloroethylene segments, had their barrier properties and wet adhesion compared after immersion in 3.5 wt% NaCl solution.

Corrosion Behavior and InhibitionPolymer composites and self-healingConcrete Corrosion and Durability

High electron mobility of β-HgS colloidal quantum dots with doubly occupied quantum states

Jaekyun Kim、Bitna Yoon、Jaehyun Kim 等 7 位作者2017-01-01RSC Advances

Steady-state electron occupation of the lowest quantum state in the conduction band of a colloidal quantum dot gives rise to unique electrical properties. An electron mobility of 1.29 cm <sup>2</sup> V <sup>−1</sup> s <sup>−1</sup> was measured in a mercury sulfide quantum dot FET.

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Oxygen Ion Transport in Molten Oxide Membranes for Air Separation and Energy Conversion

А. А. Климашин、В. В. Белоусов2017-01-01Journal of The Electrochemical Society

Molten oxide membranes (MOMs) are a new class of ion transport inorganic membranes which demonstrate superior oxygen selectivity and permeability and could be used in electrochemical devices such as molten oxide fuel cells (MOFCs) and oxygen separators for energy conversion and air separation, respectively [ Acc. Chem…

Advanced Battery Materials and TechnologiesAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Investigation of the dispersion behavior of fluorinated MWCNTs in various solvents

Yang Liu、Yichun Zhang、Zaoming Wang 等 7 位作者2017-01-01Physical Chemistry Chemical Physics

, respectively. As a result, mixed solvents of acetone and water were carefully tuned to be compatible with hF-MWCNTs. The dispersion behaviors of lF-MWCNTs and hF-MWCNTs in epoxy were also predicted according to HSPs. It was found that hF-MWCNTs maintain a stable dispersion in epoxy due to their heterogeneous structu…

Synthesis and properties of polymersPolymer Nanocomposite Synthesis and IrradiationSilicone and Siloxane Chemistry

Effects of Coconut Husk and Corn Cob as Fillers in Flexible Polyurethane Foam

P.U. Chris-Okafor2017-01-01American Journal of Polymer Science and Technology

The effects of local materials as fillers incorporated into the flexible polyether foam recipes were investigated. The fillers; coconut husk and corn cob of mesh sizes of 150 µm respectively were mixed in the ratio of 50:50. Varying percentages of the mixed fillers, 5%, 10%, 15%, 20% and 25% were mixed with polyether…

Polymer composites and self-healing

A cobalt–nitrosyl complex with a hindered hydrotris(pyrazolyl)borate coligand: detailed electronic structure, and reactivity towards dioxygen

Kiyoshi Fujisawa、Shoko Soma、Haruka Kurihara 等 6 位作者2017-01-01Dalton Transactions

The cobalt–nitrosyl complex <bold>[Co(NO)(L3)]</bold> is supported by a highly hindered tridentate nitrogen ligand, hydrotris(3-tertiary butyl-5-isopropyl-1-pyrazolyl)borate (denoted as L3 <sup>−</sup> ), and shows a linear Co–N–O unit.

Nitric Oxide and Endothelin EffectsMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Multiscale structured glass for advanced light management

Jiejie Chen、Shifeng Zhou、Nan Jiang 等 5 位作者2017-01-01Journal of Materials Chemistry C

Advanced light management in bulk multiscale structured optical glass fabricated through relaxation control.

Glass properties and applicationsRandom lasers and scattering mediaSurface Roughness and Optical Measurements

Mn 4+ doped fluorotitanate phosphors: synthesis, optical properties and application in LED devices

Qiang Zhou、Huiying Tan、Qiuhan Zhang 等 8 位作者2017-01-01RSC Advances

Green and safe HAc acid was used as the reaction medium in the preparation process of Mn <sup>4+</sup> doped A <sub>2</sub> TiF <sub>6</sub> (X = Na, K and Cs) red phosphors, which is beneficial for the potential large scale production in the future.

Luminescence Properties of Advanced MaterialsInorganic Chemistry and MaterialsInorganic Fluorides and Related Compounds

Efficient multicolor tunability of ultrasmall ternary-doped LaF 3 nanoparticles: energy conversion and magnetic behavior

Navadeep Shrivastava、Latif Ullah Khan、J.M. Vargas 等 11 位作者2017-01-01Physical Chemistry Chemical Physics

ratio along with variously doped nanomaterials described in this work, results in tunable emission color in the blue-white-red regions, highlighting the potential application of the samples in solid-state lighting devices, scintillation devices, and multiplex detection.

Luminescence Properties of Advanced MaterialsLanthanide and Transition Metal ComplexesInorganic Fluorides and Related Compounds