Materials Literature
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A novel TPE-functionalized pillar[5]arene (TPEP5) was successfully synthesized, and the motion of the TPE motif was restricted via pillararene-based host–guest recognition-mediated cross-linking, resulting in the efficient “turn-on” of fluorescence emission based on the AIE mechanism.
The crystal structure of selenolate-capped Au25(SePh)18(-) nanoclusters has been unambiguously determined for the first time, and provides a solid basis for a deeper understanding of the structure-property relationships. The selenolate-capped Au25 cluster shows noticeable differences from the previously reported Au25(…
Transition metal (Fe2+, Co2+, VO2+ or Cu2+) Schiff base complexes were immobilized onto graphene oxide previously functionalized with 3-aminopropyltriethoxysilane (3-APTES). X-ray diffraction (XRD), IR spectroscopy, thermal gravimetric analyses (TGA) and inductively coupled plasma atomic emission spectroscopy (ICP-AES…
Oxide electronics relies on the availability of epitaxial oxide thin films. The extreme flexibility of the chemical composition of ABO3 perovskites and the broad spectrum of properties they cover, inspire the creativity of scientists and place perovskites in the lead of functional materials for advanced technologies.…
Many small molecules can self-assemble by non-covalent interactions into fibrous networks and thereby induce gelation of organic liquids. However, no capability currently exists to predict whether a molecule in a given solvent will form a gel, a low-viscosity solution (sol), or an insoluble precipitate. Gelation has b…
In order to achieve high energy and power densities, a high-voltage asymmetric electrochemical supercapacitor has been developed, with activated carbon (AC) as the negative electrode and a silicon carbide-MnO2 nanoneedle (SiC-N-MnO2) composite as the positive electrode. A neutral aqueous Na2SO4 solution was used as th…
Ways to orchestrate the mechanical properties and colors of mussel-inspired metal cross-linked hydrogels based on DOPA functionalized cationic polymers are demonstrated. This is achieved by systematically varying the hardness of the coordinating metal and/or the cationic polymer.
In order to improve compatibility and composite properties of pineapple leaf fibers/polyamide 6 composite, alkaline and silane treatments were conducted for fiber modification. Effect of fiber surface treatment on the properties of the composites was investigated. Untreated and treated fibers were raw (R-PALF), alkali…
In order to construct efficient solar-driven devices, many potential materials have been explored in search of desirable photocatalyts for water splitting. Layered structure nitride halides have received significant attention from different fields because of their unusual electronic properties. In this work, we have s…
A donor-acceptor-donor molecule, , showed typical twist intramolecular charge transfer at the excited state and piezochromic property. XRD, DSC and computational researches revealed that the collapse of the crystalline structure upon applying pressure caused the piezochromic phenomenon, while the fluorescence was reco…
Aminated polyacrylonitrile(APAN) nanofiber mat was a surface modification of electrospun polyacrylonitrile (e-spun PAN) with diethylenetriamine (DETA). It was developed for the removal of Ag(I), Cu(II), Pb(II) and Fe(II) from aqueous solution. The results showed that adsorbent has the highest adsorption capacity for A…
Nature provides a multitude of nanostructures that have been finely tuned by natural selection and produce structural colourations that play a role in many biological functions such as mating, signalling or camouflage. A recurring design that is found both in the animal and plant kingdoms is the helicoidal structure,…
In this work, nanocrystalline MgO particles were prepared through combustion method using magnesium nitrate as oxidizer and hexamine as a fuel. The materials obtained by combustion method were subsequently annealed at<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" id="M1"><mml:msup><mml:mrow><mml:mn fontstyle…
Layered materials, such as layered sodium silicates and layered double hydroxides (LDHs), are well-known for their remarkable adsorption, intercalation and swelling properties. Their tunable interlayers offer an interesting avenue for the fabrication of pillared nanoporous materials, organic-inorganic hybrid materials…
The chitin was isolated from the Ganoderma lucidum submerged cultures mycelium as potential source of chitin under biotechnological processes. The extraction of chitin was carried out through 5 different assays which involved mainly three phases: pulverization of the mushroom, deproteinization of the mycelia with NaOH…
This paper presents the study of the tensile, compressive, flexural, impact energy and water absorption characteristics of the luffa fiber and Ground nut reinforced epoxy polymer hybrid composites. Luffa fiber and Ground nut reinforced epoxy resin matrix composites have been developed by hand lay-up technique with luf…
The oxidation of CO has attracted great interest in recent years because of its important role in enhancing the catalyst durability in fuel cells and in solving the growing environmental problems caused by CO emission. The usually used noble metal nanocatalysts are costly and require high reaction temperature for effi…
Hierarchical nanoscale multi-shell Au/CeO <sub>2</sub> hollow spheres with interconnected nanochambers and high catalytic activity were synthesized using a controllable approach.
We show numerically that the response of simple amorphous solids (elastic networks and particle packings) to a local force dipole is characterized by a lengthscale lc that diverges as unjamming is approached as lc ∼ (z - 2d)(-1/2), where z ≥ 2d is the mean coordination, and d is the spatial dimension, at odds with pre…
This article reviews the most recent literature data on the applications of gold nanoparticles and their various conjugates which make them suitable structures towards biomedical and clinical purposes, with an emphasis on their use as drug delivery vehicles for selective targeting of cancer cells. With the rapid surge…