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Recent Progress in Chemical Characterization of Supported Gold Catalysts: CO Adsorption on Au/Ceria–Zirconia

Juan J. Delgado、José M. Cíes、Miguel López‐Haro 等 6 位作者2011-10-26Chemistry Letters

Abstract An approach correlating quantitative CO adsorption data with the nanostructural properties of Au/CeO2–ZrO2 catalysts is discussed. It has been used to show that the CO adsorption occurs on Au sites with coordination number ≤7, that Au dispersion has a dramatic influence on the amount of CO strongly chemisorbe…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Effect of pre-freezing rate on porosity ratio and mechanical property of pig aorta

Meng Yin2011-10-26Frontiers in bioscience

Vacuum freeze-dried blood is a good material for vascular grafts. However, studies on this technology are few, particularly on physical performance change of freeze-dried blood vessel at different pre-freezing rate. In our study, pig aortas were non-invasively scanned by micro-CT in each stage of freeze-drying at diff…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsCollagen: Extraction and Characterization

The influence of diffusion temperature on the structural, optical, and magnetic properties of nickel‐doped zinc oxysulfide thin films

İ. Polat、Serdar Aksu、M. Altunbaş 等 4 位作者2011-10-26physica status solidi (a)

Abstract We investigated the structural, optical, and magnetic properties of Ni–Zn(O,S) films. The Zn(O,S) films were deposited by a spray pyrolysis method on glass substrate. A thin Ni layer evaporated on these films served as the source for the diffusion doping. The XRD of the undoped films revealed the presence of…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsChalcogenide Semiconductor Thin Films

Spectroscopic Investigation of Oxygen Sensitivity in CdTe and CdTe/CdS Nanocrystals

Yueran Yan、Lei Wang、Cheryl B. Vaughn 等 5 位作者2011-10-26The Journal of Physical Chemistry C

Excited-state dynamics of CdTe nanocrystals and CdTe/CdS core/shell nanocrystals have been studied on the picosecond time scale using pump–probe transient absorption spectroscopy. The results show that exposure of CdTe nanocrystals to air can produce profound changes in the ultrafast excited-state dynamics. These chan…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Decrease of sintering temperature by CuO doping of the 0.8Pb(Mg1/3Nb2/3)O3‐0.2PbTiO3 ceramics prepared by reaction‐sintering method

Bijun Fang、Na Jiang、Chenlu Ding 等 5 位作者2011-10-26physica status solidi (a)

Abstract CuO‐doped 0.8Pb(Mg 1/3 Nb 2/3 )O 3 ‐0.2PbTiO 3 (0.8PMN‐0.2PT) ceramics were prepared by the reaction‐sintering method. X‐ray diffraction (XRD) measurement, scanning electron microscopy (SEM) observation and density measurement confirmed that the CuO‐doped 0.8PMN‐0.2PT ceramics prepared by the reaction‐sinteri…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

Creation of Individual Defects at Extremely High Proton Fluences in Carbon Nanotube $p{-}n$ Diodes

Everett Comfort、Matthew Fishman、Argyrios Malapanis 等 8 位作者2011-10-26IEEE Transactions on Nuclear Science

We show that carbon nanotubes are robust under high H2+ion fluences. We draw this conclusion by analyzing radiation-induced defects in reconfigurable single-walled carbon nanotube p-n diodes with partially suspended nanotubes. Our analysis show that any defects created through radiation is likely the result of interac…

Carbon Nanotubes in CompositesGraphene research and applicationsIon-surface interactions and analysis

Self-assembly scenarios of block copolymer stars

Christian Koch、Christos N. Likos、Athanassios Z. Panagiotopoulos 等 4 位作者2011-10-26Molecular Physics

We examine the self-organization scenarios of star-shaped AB-block copolymers, consisting of a solvophilic A-block and a solvophobic B-block, in which f such blocks are chemically anchored on a common centre on their A-parts, leaving the B-blocks exposed on their exterior. We employ a lattice model and we perform Gran…

Advanced Polymer Synthesis and CharacterizationTheoretical and Computational PhysicsBlock Copolymer Self-Assembly

Deposition of Diamond-Like Carbon Films on Inner Wall Surfaces of Millimeter-Size-Diameter Steel Tubes by Plasma Source Ion Implantation

K. Baba、R. Hatada、S. Flege 等 4 位作者2011-10-26IEEE Transactions on Plasma Science

Diamond-like carbon (DLC) film deposition on the interior surfaces of steel tubes was carried out by plasma source ion implantation. SUS304 austenitic-type stainless steel tubes with inner diameters of 9, 5, and 4 mm were used as substrate tubes. Acetylene was the working gas for the plasma that was generated by apply…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

An Anticoagulant Activity System Using Nanoengineered Autofluorescent Heparin Nanotubes

Wei Cui、Yue Cui、Pengli Zhu 等 7 位作者2011-10-26Chemistry - An Asian Journal

Heparin (HEP) and periodate-oxidized heparin (O-HEP) nanotubes were prepared by combining the template method with a layer-by-layer (LbL) technique. The tubular structure was obtained and characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and confocal laser scanning microscopy…

Protease and Inhibitor MechanismsElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

HisB fromMycobacterium tuberculosis: cloning, overexpression inMycobacterium smegmatis, purification, crystallization and preliminary X-ray crystallographic analysis

Mohd Syed Ahangar、Yogesh Khandokar、Nazia Nasir 等 5 位作者2011-10-26Acta Crystallographica Section F Structural Biology and Crystallization Communications

HisB, encoded by open reading frame Rv1601, possesses enzymatic activity as an imidazoleglycerol-phosphate dehydratase in the histidine-biosynthetic pathway of Mycobacterium tuberculosis. A recombinant form of HisB was crystallized in three crystal forms: crystals grown using 20% PEG 1500 as a precipitant belonged to…

Tuberculosis Research and EpidemiologyEnzyme Structure and FunctionBiochemical and Molecular Research

Highly Efficient Extraction of Serum Peptides by Ordered Mesoporous Carbon

Hongqiang Qin、Peng Gao、Fangjun Wang 等 9 位作者2011-10-26Angewandte Chemie

Winzige Mengen genügen: Ein hochgeordnetes mesoporöses Kohlenstoffmaterial (OMC) wurde mit einer Weichtemplatmethode synthetisiert und als Adsorbens für die hocheffiziente Extraktion endogener Peptide aus menschlichem Serum genutzt (siehe Schema). Dabei konnten 3402 verschiedene Peptide in nur 20 μL menschlichem Serum…

Advanced biosensing and bioanalysis techniquesMass Spectrometry Techniques and ApplicationsMesoporous Materials and Catalysis

A Photo‐Thermal‐Electrical Converter Based On Carbon Nanotubes for Bioelectronic Applications

Eijiro Miyako、Chie Hosokawa、Masami Kojima 等 11 位作者2011-10-26Angewandte Chemie

Elektrifizierend! Ein Bauelement aus Kohlenstoffnanoröhren, die von Poly(3-hexylthiophen) umhüllt und in Polydimethylsiloxan-Blättchen dispergiert sind, konvertiert Laserlicht effizient in thermische Energie und nachfolgend in Elektrizität. Der Konverter ist flexibel und äußerst kompakt (siehe Bild) und kann mit einem…

Organic Electronics and PhotovoltaicsCarbon Nanotubes in CompositesAdvanced Thermoelectric Materials and Devices

Interplay between Raman scattering and four-wave mixing in As_2S_3 chalcogenide glass waveguides

Xin Gai、Duk‐Yong Choi、Steve Madden 等 4 位作者2011-10-26Journal of the Optical Society of America B

We have studied parametric amplification in dispersion-engineered As2S3 waveguides achieving a highest gain of over +35 dB using a pulsed pump. The gain is shown to involve an interaction between stimulated Raman scattering (SRS) and four-wave mixing (FWM). The gain was studied both experimentally and using com…

Optical Network TechnologiesPhotonic and Optical DevicesPhase-change materials and chalcogenides

Enzymatic Synthesis of L-tert-Leucine with Branched Chain Aminotransferase

Young-Man Seo2011-10-26Journal of Microbiology and Biotechnology

In this study, we demonstrated the asymmetric synthesis of L-tert-leucine from trimethylpyruvate using branchedchain aminotransferase (BCAT) from Escherichia coli in the presence of L-glutamate as an amino donor. Since BCAT was severely inhibited by 2-ketoglutarate, in order to overcome this here, we developed a BCAT/…

Enzyme Catalysis and ImmobilizationMicrobial Metabolic Engineering and BioproductionEnzyme Structure and Function

RF transmission properties of graphene monolayers with width variation

Hee‐Jo Lee、Eunho Kim、Won‐Jun Lee 等 4 位作者2011-10-26physica status solidi (RRL) - Rapid Research Letters

Abstract We report the radio‐frequency transmission properties and distributed elements of chemical vapour deposition (CVD)‐grown graphene monolayers with width variation using a coplanar waveguide electrode in the microwave region. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

Graphene research and applications2D Materials and ApplicationsMolecular Junctions and Nanostructures

Processing and properties of syntactic foams reinforced with carbon nanotubes

Mauricio E. Guzman、Alejandro J. Rodriguez、Bob Minaie 等 4 位作者2011-10-26Journal of Applied Polymer Science

Abstract This article presents synthesis and mechanical characterization of carbon nanotube (CNT)‐reinforced syntactic foams. Following a dispersion approach (comprising ultrasonic, calendering, and vacuum centrifugal mixing), single‐ and multi‐walled functionalized CNTs (FCNTs) were incorporated into two foam composi…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Mixed-layer corrensite-chlorites and their formation mechanism in the glauconitic sandstone-clayey rocks (Riphean, Anabar Uplift)

V. A. Drits、Т. А. Ivanovskaya、B. A. Sakharov 等 7 位作者2011-10-26Lithology and Mineral Resources

The paper presents the first detailed mineralogical, structural, and crystal-chemical characteristics of the mixed-layer corrensite-chlorites from the glauconitic sandy-clayey rocks that make up the bottom (0.10 m) of a basal member (1.50 m) of the lower subformation of the Yusmastakh Formation (Riphean, Anabar Uplift…

Geological and Geochemical AnalysisCrystal Structures and PropertiesClay minerals and soil interactions

Generalized Hamilton’s Principle for Inelastic Bodies Within Non-Equilibrium Thermodynamics

Kuangdai Leng、Qiang Yang2011-10-26Entropy

Within the thermodynamic framework with internal variables, the classical Hamilton’s principle for elastic bodies is extended to inelastic bodies composed of materials whose free energy densities are point functions of internal variables, or the so‑termed Green-inelastic bodies, subject to finite deformation and non-c…

Elasticity and Material ModelingThermoelastic and Magnetoelastic PhenomenaNonlocal and gradient elasticity in micro/nano structures

Temperature‐dependent thermo‐mechanical and Raman spectroscopy study of the SRS‐active melilite‐type crystal Ca2ZnSi2O7 (hardystonite) at its incommensurate–commensurate phase transition

P. Becker、Eugen Libowitzky、L. Bohatý 等 7 位作者2011-10-26physica status solidi (a)

Abstract Stimulated Raman scattering (SRS) active crystals of Ca 2 ZnSi 2 O 7 (hardystonite) adopt a melilite‐type structure at temperatures above ca. 402 K, while at ambient conditions they show a two‐dimensionally incommensurate structure modulation. To study the influence of the incommensurability of the structure…

Glass properties and applicationsCrystal Structures and PropertiesMineralogy and Gemology Studies

Synthesis, nano-features, ex vivo anti-platelet aggregation and in vivo antithrombotic activities of poly-α,β- dl -aspartyl- l -arginine

Lin Gui、Ming Zhao、Yuji Wang 等 7 位作者2011-10-26MedChemComm

In the nanoscale assembly-based design of antithrombotic agents, poly-α,β-DL-aspartyl-L-arginine (MW: 20 741) was prepared from the thermal polycondensation of DL-aspartic acid and the amidation of polysuccimide with L-arginine. In the pH environments corresponding to the stomach (pH 1.2), intestinal tract (pH 7.6), b…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies