Materials Literature
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Band alignment of amorphous Ge2Sb2Te5 and various substrates was obtained using high-resolution x-ray photoelectron spectroscopy. The valence band offset of Ge2Sb2Te5 on various complementary-metal-oxide-semiconductor (CMOS) materials, i.e., Si, SiO2, HfO2, Si3N4 and NiSi, were investigated with the aid of the core le…
Based on causality, the limitation of the electromagnetic cloak with dispersive material is investigated in this letter. The results show that perfect invisibility cannot be achieved because of the dilemma that either the group velocity Vg diverges or a strong absorption is imposed on the cloaking material. It is an i…
Abstract This paper investigates the application of a recently proposed higher‐order Cauchy–Born rule in the continuum simulation and multiscale analysis of carbon nanotubes (CNTs). A mesh‐free computational framework is developed to implement the numerical computation of the hyper‐elastic constitutive model that is d…
The realization and the radio-frequency characterization of a tunable strontium titanate (STO) electrostrictive solidly mounted acoustic resonator (SMR) bulk acoustic wave are reported. For a 430nm thick strontium titanate layer, the resonance frequency at 2.2GHz can be switched on with a bias voltage of 6V and tuned…
The electrochromic switching times of solid state conducting polymer devices fabricated by the ionic self-assembled multilayer method has been investigated. The devices were composed of bilayers of poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) and poly(allylamine hydrochloride) on indium tin oxide substrate…
This paper reports the effect of replacement of selenium by antimony on the optical gap and some other physical parameters of new quaternary chalcogenide As14Ge14Se72− x Sb x (where x = 3, 6, 9, 12 and 15 at%) thin films. Thin films with thickness 200–220 nm of As14Ge14Se72− x Sb x were prepared by thermal evaporation…
The sequence infrastructure that has arisen through large-scale genomic projects dedicated to protein analysis, has provided a wealth of information and brought together scientists and institutions from all over the world. As a consequence, the development of novel technologies and methodologies in proteomics research…
With a high Curie temperature and low entropy change, the magnetic-field-induced martensitic transformation has been obtained in ferromagnetic shape memory alloys MnNiGa by doping a small amount of Co. Due to the ferromagnetic activation effect of Co, a large amount of antiferromagnetically aligned Mn moments are turn…
Multiple exciton generation and subsequent electrical extraction from a thin film photoconductive device constructed from PbSe nanocrystal quantum dots are demonstrated. The hydrazine treatment of the PbSe film drastically improves the conductivity of the film while maintaining excellent optical and structural film qu…
The dynamic mechanical properties of high density mixtures of polytetraflouroethylene, aluminum (Al), and tungsten (W) powders are tailored by changing the morphology of the particles and porosity. Powder composites with fine metallic particles exhibited higher ultimate compressive strength, despite higher porosity, t…
We report CO-induced lifting of the hexagonal surface reconstruction on Au (001). Using in-situ surface x-ray scattering, we determined a pressure-temperature phase diagram for the reconstruction and measured the dynamical evolution of the surface structure in real time. Our observations provide evidence that, under c…
The recent interest in the imaging possibilities of photonic crystals (superlensing, superprism, optical mirages etc...) call for a detailed analysis of beam propagation inside a finite periodic structure. In this paper, an answer to the question "where does the beam emerge?" is given. Contrarily to common knowledge,…
An efficient first principles method was developed to calculate spin transfer torques in layered system with noncollinear magnetization. The complete scattering wave function is determined by matching the wave function in the scattering region with the Bloch states in the leads. The spin transfer torques are obtained…
The use of cryogenic treatment (CT) to improve mechanical properties of materials has been developed from the end of the Sixties. At the present time, the initial mistrust about CT has been cleared up and many papers about different materials reporting laboratory tests results, microstructural investigations and hypot…
Abstract This article presents an XPS study of Ce 3d emission spectra dominated by atomic multiplet effects in core level spectroscopy of rare earth compounds (Ce oxides). Core level spectroscopy has been used to study the electronic states of Ce 3d 5/2 and Ce 3d 3/2 levels in Ce 4+ and Ce 3+ states. The well‐resolved…
The magnetic properties of the organic/inorganic hybrid copper-methylenediphosphonate, Cu2(O3PCH2PO3) were examined by performing the spin dimer analysis based on the extended Hckel tight binding method. In Cu2(O3PCH2PO3) the CuO3 chains made up of edge-sharing CuO5 square pyramidal units are inter-linked by O-P-O bri…
The polymeric ten-coordinate rare earth metal (RE) complex with nta, {[EuIII(C-nta)(T-nta)] · 3H2O} n , has been synthesized in aqueous solution and characterized by FT-IR, elemental analyses, TG-DTA and single-crystal X-ray diffraction technique. The {[EuIII(C-nta)(T-nta)] · 3H2O} n crystallizes in the cubic system w…
Three dimeric rare-earth complexes [Eu(p-FBA)3(phen)(H2O)]2 (1), [Tb(p-FBA)3phen]2 (2), and [Tb(o-FBA)3phen]2 (3) (where p-FBA = p-fluorobenzoate, o-FBA = o-fluorobenzoate, phen = 1,10-phenanthroline) were synthesized and structurally characterized. All are neutral dimeric molecules. Complex 1 crystallizes in triclini…
Poly(allylamine) hydrochloride is a weak cationic polyelectrolyte that exhibits different aggregation properties at different solution pH values and aging times. Specifically, after several days aging in a pH 3 buffer, less than 1 mg/mL poly(allylamine) hydrochloride became turbid, and the hydrodynamic radius increase…
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