Materials Literature
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Abstract New regioregular head‐to‐tail type poly(6‐alkylpyridine‐2,5‐diyl)s (P6RPys; R = nonyl, dodecyl, and pentadecyl) were prepared by organometallic polycondensation. The head‐to‐tail (HT) content in the polymers was higher than 95%, as revealed by 1 H NMR spectroscopy. Powder X‐ray diffraction data of HT‐P6RPys i…
A cholesterol derivative forms self-assembled helical ribbons in organic solvent, and treatment of this helical ribbon lipid as a template with Pd(Ac)2 provides helically-patterned arrays of palladium nanoparticles followed by reduction.
Abstract Studies on the mechanical properties of acetylated and phthalated starch blends with low density polyethylene (LDPE) were performed with and without LDPE‐ co ‐glycidyl methacrylate copolymer as compatibilizer. Impact and tensile properties of the blend specimens were measured following standard ASTM methods.…
The accuracies of the calculated vibrational frequencies and Raman intensities given by two new, highly compact Pol-type basis sets, Z2PolX and Z3PolX, have been determined and compared to the 6-31G(d), PolX, and aug-cc-pVTZ basis sets. Calculation of accurate Raman intensities has previously required large basis sets…
Magnetization, resistivity, and neutron diffraction measurements have been carried out on a series of samples ${\mathrm{La}}_{0.5\ensuremath{-}x}{\mathrm{Y}}_{x}{\mathrm{Ca}}_{0.5}\mathrm{Mn}{\mathrm{O}}_{3}$ ($x=0$, 0.1, 0.18), to study the influence of ionic radii in charge-ordered manganites. ${\mathrm{La}}_{0.5}{\…
The surface and bulk electronic structure of tetragonal (at 300 K) and orthorhombic (at 77 K) $\mathrm{K}{\mathrm{D}}_{2x}{\mathrm{H}}_{2(1\ensuremath{-}x)}\mathrm{P}{\mathrm{O}}_{4}$ single crystals (so-called KDP and DKDP), with a deuteration degree $x$ of 0.0, 0.3, and 0.6, is studied by soft x-ray absorption near-…
Potassium adsorption on graphite has been a model system for the understanding of the interaction of alkali metals with surfaces. The geometries of the $(2\ifmmode\times\else\texttimes\fi{}2)$ structure of potassium on both single-crystal graphite (SCG) and highly oriented pyrolytic graphite (HOPG) were investigated f…
A bistable chiral tilted-homeotropic nematic cell which uses dual-frequency liquid crystal is demonstrated. This cell can be switched between the tilted homeotropic state and the twisted state. The switching mechanisms are achieved by the backflow effect together with the anisotropic properties of the dual-frequency l…
Abstract Silane‐crosslinked polypropylene (PP) has been prepared first by the grafting of silane onto the backbone of PP in a melt process and then by crosslinking in warm water. The effects of type and concentration of silane and peroxide on the silane grafting on PP were investigated. The thermal behavior of the sil…
Abstract In this paper, polypropylene (PP)/organophilic montmorillonite (OMMT) nanocomposites were successfully prepared without any compatibilizers by solid‐state shear compounding (S 3 C) using pan‐mill equipment. X‐ray diffraction (XRD) patterns show that the OMMT characteristic (001) peak at 2θ equal to 4.59 degre…
Reliable control on the pretilt alignment of nematic liquid crystal (LC) in the 30°–50° range is a well-known challenge. An unconventional approach, involving microtextured surfaces with domains favoring dissimilar LC alignments, has recently demonstrated applicability in bi- and tristable displays. These textured dom…
Pasty materials encountered in industry and in earth science are intermediate between solids and liquids either in terms of their internal structure (disordered but jammed) or from a mechanical point of view. Our results indicate that the apparent behavior of a particulate system (soils, suspensions, clays, etc.) can…
We have investigated the process of a metamagnetic transition (MT) between the ferromagnetic and paramagnetic states in the $\mathrm{La}{\mathrm{Fe}}_{11.7}{\mathrm{Si}}_{1.3}$ compound, which has both giant magnetocaloric and large magnetovolume effects. The nucleation in MT, which indicates the coexistence of two ph…
We report on a two-photon absorption-induced photoenhancement effect on a densely packed CdSe∕ZnSe∕ZnS core-shell semiconductor nanocrystal solid film. The enhancement is found to be irreversible without a noticeable blueshift in emission spectra, hence we attribute the enhancement to the photoannealing of interface d…
Abstract Spin‐orbit coupling has been introduced into our newly developed ligand field density functional theory (LFDFT), using the zero‐order regular approximation as implemented into the Amsterdam density functional (ADF) code. Application of the formalism to a series of Ni X (XF − , Cl − , Br − , I − ) compounds s…
Bi 3.5 Nd 0.5 Ti 3 O 12 (BNT) ferroelectric thin films were fabricated on Pt∕Ti∕SiO2∕Si(100) substrates by chemical solution deposition. Structure evolution and ferroelectric and dielectric properties of the as-prepared thin films under a moderate temperature (600–750°C) annealing were studied in detail. The experimen…
Abstract Styrene (Sty), methyl methacrylate (MMA), methacrylamide (MAm) and acrylomorpholine (AcM) were grafted onto powder cellulose by atom‐transfer radical polymerization. Cellulose chloroacetate (Cell‐ClAc), as a macro‐initiator, was first prepared by the reaction of chloroacetyl chloride with primary alcoholic OH…
We present a detailed study of the lattice dynamics and electron-phonon coupling for a (3,3) carbon nanotube which belongs to the class of small diameter based nanotubes which have recently been claimed to be superconducting. We treat the electronic and phononic degrees of freedom completely by modern ab initio method…
Abstract Summary: We use a surface force balance (SFB) to study the normal interactions between polymer brushes, which are self‐assembled from solution. They consist of polystyrene (PS) chains in toluene (neutral chains in a good solvent) anchored on the interacting mica surfaces via sulfozwitterionic end groups. The…
Abstract Polylactides were prepared by ring‐opening polymerization (ROP) in bulk using as catalyst either stannous 2‐ethylhexanoate at a monomer to catalyst ratio of 2000, or ferrous acetate (Fe(OAc) 2 ) at monomer to catalyst ratios of 500, 1000, 2000 and 3000. The crystallization behaviour was studied for the prepar…