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Structure and dynamics of phosphate glasses

Aleksandar Matic、L. Börjesson1998-02-01Philosophical Magazine B

We have investigated phosphate glasses of metaphosphate composition containing three different cations Ag+, Li+ and Pr3+. Using Raman spectroscopy we study the influence of the modifier on the host structure of the glass. We observe an overall softening of the bands in the AgPO3 compared with LiPO3 and Pr(PO3)3. This…

Luminescence Properties of Advanced MaterialsMaterial Dynamics and PropertiesGlass properties and applications

Effects of SnO2 on the Phosphor Screen Behaviors under Low Energy Electron Excitation

Sang Won Kang、Jae Soo Yoo、Jong Duk Lee1998-02-01Journal of The Electrochemical Society

The behaviors of phosphor screen under low‐energy electron excitation were investigated. A phosphor screen was deposited by an electrophoretic method, thereafter transparent tin oxide was implanted in this screen by electroplating. It was found that incorporation of a small quantity of tin oxide onto the phosphor scre…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesAdvanced Energy Technologies and Civil Engineering Innovations

Epilithic diatoms of the St. Lawrence River and their relationships to water quality

Euan D. Reavie、John P. Smol1998-02-01Canadian Journal of Botany

Epilithic diatoms were sampled at 48 sites along the St. Lawrence River, from Salaberry de Valleyfield to Québec City, in an attempt to determine how diatom assemblages were related to measured water quality variables. Canonical correspondence analysis was used to explore the relationships between environmental variab…

Aquatic Ecosystems and Phytoplankton DynamicsWater Quality and Pollution AssessmentDiatoms and Algae Research

The Mechanism of the Oxidative Dissolution of Colloidal Gold in Cyanide Media

Andrew McCarthy、Robert G. Coleman、M.J. Nicol1998-02-01Journal of The Electrochemical Society

The kinetics of the dissolution of colloidal gold in aerated cyanide solutions has been investigated with a view to developing a fundamental understanding of the mechanism involved. Experimental results obtained are consistent with an electrochemical mixed potential model, where the mixed potential is set up in the pa…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsElectrochemical Analysis and Applications

Computer simulation studies of liquid crystals: A new Corner potential for cylindrically symmetric particles

Habtamu Zewdie1998-02-01The Journal of Chemical Physics

We have developed a new Corner potential suitable for computer simulation studies of pure and mixture systems composed of rodlike, disklike, and spherical molecules. The pair potential is assumed to have the shifted Lennard–Jones 12-6 potential which has the general form of εf(σ0/(r−σ+σ0)). The strength parameter ε an…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesMolecular spectroscopy and chirality

Dose dependence and fading effect of the thermoluminescence signals in γ-irradiated paprika

V. Correcher、J.L. Muñiz、J.M. Gómez-Ros1998-02-01Journal of the Science of Food and Agriculture

The thermoluminescence (TL) method can be used to discriminate irradiated and non-irradiated paprika. This study reports the polymineral composition of the dust adhered to paprika; radiation-specific luminescence is emitted by the inorganic material (mainly quartz, feldspars and calcite). On the basis of the shape of…

Luminescence Properties of Advanced MaterialsInsect and Pesticide ResearchIsotope Analysis in Ecology

Processing and Mechanical Properties of Pressureless‐Sintered Niobium‐Alumina‐Matrix Composites

Daniel E. García、S. Schicker、J. Bruhn 等 5 位作者1998-02-01Journal of the American Ceramic Society

Niobium‐alumina (Nb‐Al2O3) composites have been fabricated via the pressureless sintering of compacts of intensively milled Nb‐Al2O3 mixtures. Strength and fracture toughness of the composites increase as the niobium content increases. For a composite that contains 50 vol% niobium, strengths of up to 680 MPa, with a c…

Advanced ceramic materials synthesisIntermetallics and Advanced Alloy PropertiesAdvanced materials and composites

Morphology and melting behavior of nascent ultra-high molecular weight polyethylene

Roger A. Phillips1998-02-01Journal of Polymer Science Part B Polymer Physics

The nascent morphology of UHMW PE exhibits high melting point, high crystallinity, and increased WAXS line breadth relative to samples formed by melt crystallization. Different empirical relationships between crystal size and melting point are observed for nascent and molded samples. This differentiation is removed fo…

Polymer crystallization and propertiesFiber-reinforced polymer compositesRecycling and Waste Management Techniques

Evolution of Pore Structure in Microporous Silica Membranes: Sol-Gel Procedures and Strategies

Balagopal N. Nair、K. Keizer、Tatsuya Okubo 等 4 位作者1998-02-01Advanced Materials

Silica membranes exhibiting excellent molecular sieving capability, which would find applications in fuel-cell electric vehicles with on-board hydrogen generation, for example, are the aim of the sol-gel strategies outlined here. It is shown that optimization of the sol-gel synthesis parameters is important in order t…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisMembrane Separation and Gas Transport

Polyethylene-Oil Palm Frond Composites-A Preliminary Study on Mechanical Properties

H. D. Rozman、H. Ismail、R. M. Jaffri 等 5 位作者1998-02-01International Journal of Polymeric Materials

The mechanical properties of composites consisting of high density polyethylene (HDPE) and oil palm frond (OPF) have been investigated. Three sizes of OFF at different filler loadings were compounded using a single screw compounder. Modulus of rupture (MOR) of the OPF-HDPE composites decreased with increasing filler l…

Natural Fiber Reinforced CompositesFiber-reinforced polymer composites

The generation of two-dimensional vortices by transverse oscillation of a soap film

V. O. Afenchenko、Alexander Ezersky、S. V. Kiyashko 等 5 位作者1998-02-01Physics of Fluids

An experimental investigation of the dynamics of horizontal soap films stretched over circular or square boundaries undergoing periodic transverse oscillations at frequencies in the range 20–200 Hz is reported. Concomitant with modes of transverse flexural oscillations, it was observed that two-dimensional vortices in…

Fluid Dynamics and Heat TransferPickering emulsions and particle stabilizationFluid Dynamics and Thin Films

Interface Nanostructure of Brazed Silicon Nitride

Chihiro Iwamoto、Shun‐ichiro Tanaka1998-02-01Journal of the American Ceramic Society

Nanomorphologies and crystallographic orientations of the brazed interface of silicon nitride (Si 3 N 4 ) were analyzed via high‐resolution transmission electron microscopy. When Si 3 N 4 was brazed using an Ag‐Cu‐Ti alloy, titanium nitride (TiN) nanoparticles were formed adjacent to the ceramic as reaction products,…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsBoron and Carbon Nanomaterials Research

Syntheses and nonlinear optical properties of nonaggregated metallophthalocyanines

Minquan Tian、Suichi Yanagi、Keisuke Sasaki 等 5 位作者1998-02-01Journal of the Optical Society of America B

Hexadecakis(2,2,2-trifluoroethoxy)-substituted vanadyl and zinc phthalocyanines, and hexadecakis(ethoxy)vanadylphthalocyanine, were synthesized and characterized. Their aggregation properties were studied by evaluation of the concentration dependence of absorption spectra. Hexadecakis(2,2,2-trifluoroethoxy)-substitute…

Porphyrin and Phthalocyanine ChemistryNonlinear Optical Materials ResearchNonlinear Optical Materials Studies

Activation of blue emission from oxidized porous silicon by annealing in water vapor

Hideki Koyama、Yuka Matsushita、Nobuyoshi Koshida1998-02-01Journal of Applied Physics

It is reported that annealing of oxidized porous silicon in water vapor at about 250 °C drastically enhances its blue emission. Infrared absorption studies indicate that this annealing increases all the absorption peaks related to O–H vibrations, except for that of free silanol which disappears completely. No traces o…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

BLANC: the program suite for protein crystallography

A. A. Vagin、Garib N. Murshudov、B.V. Strokopytov1998-02-01Journal of Applied Crystallography

The BLANC program suite is a set of programs which can be used for macromolecular structure determination by X-ray crystallography. The suite is designed to provide experienced crystallographers and students with a number of simple tools, at the same time allowing the building and testing of new algorithms. Besides a…

Protein Structure and DynamicsEnzyme Structure and Function

Preparation and Characterization of a Cocrystalline Suspension of [LysB28,ProB29]-Human Insulin Analogue

Michael R. DeFelippis、Diane L. Bakaysa、Maureen A. Bell 等 9 位作者1998-02-01Journal of Pharmaceutical Sciences

Soluble preparations of [LysB28,ProB29]-human insulin analogue (LysPro) exhibit more rapid absorption than human insulin upon subcutaneous injection. Biphasic mixtures of LysPro and intermediate-acting insulin suspensions could provide advantages over current preparations for the treatment of diabetes. To prepare biph…

Protein Structure and DynamicsEnzyme Structure and FunctionHemoglobin structure and function

A new recycling system for expanded polystyrene using a natural solvent. Part 2. Development of a prototype production system

Tsutomu Noguchi、Yasuhito Inagaki、Mayumi Miyashita 等 4 位作者1998-02-01Packaging Technology and Science

A prototype production system for recycling expanded polystyrene (EPS), which uses an orange oil, d-limonene, as the EPS shrinking agent, has been developed. This system consists of an apparatus to dissolve EPS and a recycling plant to separate the limonene solution. The recycling plant can mass reproduce polystyrene…

biodegradable polymer synthesis and properties

Electrokinetic Behavior and Stability of Silicon Carbide Nanoparticulate Dispersions

Pedro Tartaj、Michael J. Reece、José S. Moya1998-02-01Journal of the American Ceramic Society

The stability of aqueous suspensions containing SiC nanoparticles prepared by inductively coupled plasma has been studied. Physicochemical analyses indicated that the as‐prepared samples consisted of monocrystalline spherical particles of the 3C‐SiC polytype with a mean diameter of about 40 nm. HRTEM clearly showed th…

Advanced ceramic materials synthesisDiamond and Carbon-based Materials ResearchIon-surface interactions and analysis

Three solutions of the protein solubility problem

W. Terry Jenkins1998-02-01Protein Science

Three simple equations are presented, which describe the variation of protein solubility (S) with changes in salt concentration, in terms of either the salt molality (M), the salt activity (ax), or the water activity (aw). Each equation yields, essentially independent, estimates of the numbers of salt ions (delta vx)…

Analytical Chemistry and ChromatographyProtein purification and stabilityCrystallization and Solubility Studies

Monte Carlo simulation of the kinetics of protein adsorption

Vladimir P. Zhdanov、B. Kasemo1998-02-01Proteins Structure Function and Bioinformatics

Adsorption of proteins occurs via diffusion toward the interface, actual adsorption, and subsequent irreversible conformational changes resulting in denaturation of the native protein structure. The conventional kinetic models describing these steps are based on the assumption that the denaturation transitions obey th…

Protein Structure and DynamicsMaterial Dynamics and PropertiesPolymer Surface Interaction Studies