Materials Literature
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Direct observation of superplastic deformation in shear in a scanning electron microscope in Pb-62% Sn eutectic alloy at different microstructural levels were performed. The sliding of grains as an entity was observed. Such cooperative grain-boundary sliding proceeds by means of the sequential shear of grains along sh…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermogravimetry/gas chromatography/mass spectrometry and thermogravimetry/gas chromatography/Fourier transform infrared spectroscopy: Novel hyphenated methods in thermal analysisWilliam H. McClennen, Richard M. Buchanan, Neil S. Arnold, Jacek P. Dworzanski, and Henk L. C. M…
We report multireference configuration-interaction calculations for the lowest potential energy surfaces of the B(2s22p 2P)...H2 van der Waals molecule. The degeneracy of the 2p orbital implies that there exist three adiabatic potential energy surfaces (two of A′ symmetry and one of A″ symmetry in Cs geometry) which b…
Probability distributions are evaluated for electromigration induced open failures in narrow, passivated interconnects with a near-bamboo grain structure. Void formation is initiated at the cathode ends of the polycrystalline line segments or ‘‘grain clusters.’’ If these clusters are longer than a critical size Lc, th…
Recent observation of efficient light emission from porous silicon has attracted much attention and renewed interests in the study of nonlinear optical properties of nanometer-sized quantum systems. In this paper, we study the third-order nonlinear optical susceptibility of semiconductor quantum wires. The quantum wir…
We show in this paper that measurements of charge-state distributions for 5--1600 eV Li, Na, and K scattered from a clean Cu(001) surface provide an excellent probe of the dynamics of atom-surface charge transfer. The neutralization probabilities, measured as a function of the perpendicular velocities of the scattered…
We report detailed measurements of the electrical resistivity, Seebeck coefficient, and differential scanning calorimetry across the metal-insulator (MI) transition ( T MI ≊205 K) of NdNiO 3 . As in the isostructural oxide PrNiO 3 , the transition is extremely hysteretic, consistent with the first-order character of t…
An expression for the electron-phonon coupling strength in fullerene nanotubules is derived within the tight-binding model. It is shown that the interaction of electrons with longitudinal acoustic phonons gives rise to intraband scattering but not to interband scattering; the reverse is true for interaction of electro…
A zero-field spontaneous relaxor-ferroelectric transition is reported in Pb(Sc0.5Ta0.5)O3 (PST). This behavior is different from that of other relaxors, where such transitions occur only under the field. A highly disordered PST that has the wide relaxation spectrum typical of relaxors is shown to transform spontaneous…
The spectral quantum efficiency in ReS2 heterodiodes was measured in the wavelength region between 600 and 850 nm. Anisotropy effects in the van der Waals plane were observed by means of linearly polarized light at normal incidence to the (001) plane of ReS2 single crystals. The anisotropy in quantum efficiency reache…
Electron-energy-loss spectroscopy has been used to identify microcrystalline diamond films produced by laser ablation of graphite. The production of the diamond phase results from varying the deposition geometry and parameters from those of an earlier configuration that produced diamondlike carbon films. A complete st…
Abstract The thermal degradation of poly( N ‐vinyl‐2‐pyrrolidone) (PVP) was studied by dynamic thermogravimetric analysis (TGA) in the range 200–600°C under nitrogen and oxygen atmospheres at various heating rates. The apparent activation energy of the degradative process was determined by the application of kinetic t…
We report on the optical response of size selected Ag2, Ag3, Au2, and Au3 embedded in argon matrices. Cluster samples were investigated in situ by excitation, fluorescence, and absorption spectroscopy. The spectra for the dimers are in agreement with previous measurements made on conventionally prepared matrices. Our…
Electron-electron and electron-phonon thermalization processes are investigated in gold films using a high-sensitivity multiple-wavelength femtosecond pump-probe technique. A nonequilibrium electron distribution is excited by free-carrier absorption of an infrared femtosecond pulse and its relaxation dynamics followed…
Film-thickness profiles obtained in pulsed-laser deposition are calculated by using the well-known solution of the gas-dynamic equations which describes the expansion of the plasma plume in vacuum. The time for plasma formation is supposed to be short compared with the time of expansion. The film profile depends on th…
The luminescence in the visible range of porous silicon is analyzed in the hypothesis of quantum confinement. We calculate the electronic and optical properties of silicon crystallites and wires with sizes between 0 and 4.5 nm. The band-gap energies of such confined systems are in agreement with the photon energies ob…
Details are given of an experimental study of field emission characteristics of diamond-coated Mo electrodes: in particular, a transparent anode imaging technique was used to monitor the spatial distribution of the individual emission centres. This study has revealed the important fact that substantial emission can be…
The results of a high resolution photoemission study of the Be(0001) surface carried out at temperatures between 100 and 450 K are reported. At 100 K, three distinctly shifted Be 1s levels, exhibiting shifts of -825, -570, and -265 meV, are revealed and interpreted to originate from the three outermost atomic layers.…
Photoinduced poling (PIP) is a new technique which allows the room-temperature preparation of guest/host polymer films exhibiting significant polar order for nonlinear optical applications. We report a comparison of this novel technique with the conventional electrode poling procedure performed at the glass transition…
Characterization of the arc-discharge deposits at the cathode from anodes containing yttrium oxide and titanium by transmission electron microscopy and x-ray diffraction shows different results with respect to an encapsulation of the metal carbides into carbon clusters. Yttrium carbide is encapsulated into carbon nano…