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Infrared conductivity and electron–molecular-vibration coupling in the organic superconductor di[bis(ethylenedithio)tetrathiafulvalene] bis(isothiocyanato)cuprate(I),κ-(BEDT-TTF)2[Cu(NCS)2]: Protonated and deuterated salts

Tadashi Sugano、Hakuro Hayashi、Minoru Kinoshita 等 4 位作者1989-06-01Physical review. B, Condensed matter

Polarized reflectance spectra of the organic superconductors protonated and deuterated \ensuremath{\kappa}-(BEDT-TTF${)}_{2}$[Cu(NCS${)}_{2}$] (H and D salts) [BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene] were measured over the range from 500 to 28 000 ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$ at room temperatur…

Magnetism in coordination complexesMolecular Junctions and NanostructuresOrganic and Molecular Conductors Research

The mechanism for the O2 dissociation on Ni(100)

Itai Panas、Per E. M. Siegbahn、Ulf Wahlgren1989-06-01The Journal of Chemical Physics

The dissociation of O2 on Ni(100) has been studied using a cluster model approach. The three principally different reaction pathways, over an on-top position, over a bridge position, and over a fourfold hollow position, were considered. The dissociation mechanisms were found to be very similar for these pathways. In t…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceMolecular Junctions and Nanostructures

Isotropic-nematic transition of hard ellipses

José A. Cuesta、Carlos F. Tejero、Marc Baus1989-06-01Physical Review A

The orientational freezing of a system of hard ellipses, as a first approximation for a nematogen adsorbed on a smooth substrate, is studied with the aid of an approximate density-functional theory used previously for the study of hard ellipsoids. The isotropic-nematic transition, which was first order for the ellipso…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesOptical Polarization and Ellipsometry

Transitions and modulated phases in chiral tilted smectic liquid crystals

George A. Hinshaw、Rolfe G. Petschek1989-06-01Physical Review A

Modulated phases that occur in tilted chiral smectic liquid crystals are discussed within mean-field theory in thin films and in bulk. A chiral term in the free energy containing three order parameters and one gradient can make the free energy of certain defects negative or the bend elastic constant negative. Assuming…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsMolecular spectroscopy and chirality

Theory of optimization of the experimental conditions of preparative elution using the ideal model of liquid chromatography

Sadroddin Golshan‐Shirazi、Georges Guiochon1989-06-01Analytical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTheory of optimization of the experimental conditions of preparative elution using the ideal model of liquid chromatographySadroddin. Golshan-Shirazi and Georges. GuiochonCite this: Anal. Chem. 1989, 61, 11, 1276–1287Publication Date (Print):June 1, 1989Publication History P…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesField-Flow Fractionation Techniques

Conductance control of porphyrin solids by molecular design and doping

Kazuo Yamashita、Yutaka Harima、Tatsuro Matsubayashi1989-06-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTConductance control of porphyrin solids by molecular design and dopingKazuo Yamashita, Yutaka Harima, and Tatsuro MatsubayashiCite this: J. Phys. Chem. 1989, 93, 13, 5311–5315Publication Date (Print):June 1, 1989Publication History Published online1 May 2002Published inissue…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresSurface Chemistry and Catalysis

1989 Speller Award Lecture: New Stainless Steels for Seawater Service

A. J. Sedriks1989-06-01CORROSION

A review is presented of the research and development effort that has been aimed at providing new stainless steels for use in seawater and seawater-cooled systems. Three new categories of highly corrosion-resistant stainless steels are described, namely the superaustenitics (i.e., austenitic nitrogen-containing 6% mol…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing Techniques

[Et4N]6[Na14Mo24P17O97(OH)31]·xH2O: A Hollow Cluster Filled with 12 Na⊕ Ions and a H3PO4 Molecule

Robert C. Haushalter、Frank W. Lai1989-06-01Angewandte Chemie International Edition in English

The hydrothermal reaction of Na2MoO4, Mo, H3PO4, Et4NOH, and H2O yields the title complex, the structure of which is characterized by tetramers of [Mo6P4O24(OH)7]5⊖ units 1 (Mo = hatched, P = dotted, O = empty circle). The complex structure of the reduced molybdenum phosphate can be rationalized by the differing hydro…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

Sonochemistry of alcohol-water mixtures. Spin-trapping evidence for thermal decomposition and isotope-exchange reactions

C. Murali Krishna、Takashi Kondo、Péter Riesz1989-06-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSonochemistry of alcohol-water mixtures. Spin-trapping evidence for thermal decomposition and isotope-exchange reactionsC. Murali Krishna, Takashi Kondo, and Peter RieszCite this: J. Phys. Chem. 1989, 93, 13, 5166–5172Publication Date (Print):June 1, 1989Publication History…

Ultrasound and Cavitation PhenomenaNuclear Physics and ApplicationsChemical Reactions and Isotopes

An Integrated Approach to Dynamic Analysis of the Ring Spinning Process

Subhash K. Batra、Tushar K. Ghosh、Mishu I. Zeidman1989-06-01Textile Research Journal

We have re-analyzed the dynamics of the ring spinning process as a coupled set of subproblems and have obtained the solutions numerically. The analyses in Parts I and II of this series deal with the case of an uncontrolled balloon. In Part I we ignore the effects of air drag as well as gravitational and Coriolis accel…

Textile materials and evaluations

Composites of polyvinyl chloride—wood fibers: IV. Effect of the nature of fibers

D. Maldas、B. V. Kokta、Claude Daneault1989-06-01Journal of Vinyl Technology

Abstract The suitability of different pulps (e.g. chemithermomechanical, kraft, tempure, temalfa, cotton, and sawdust) as well as various wood species (e.g. softwood, spruce; hardwood, aspen and birch) as the reinforcing filler for thermoplastic composites of PVC (two different grades) have been evaluated on the basis…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesFiber-reinforced polymer composites

Angle Phase Matching in Second Harmonic Generation from a Ferroelectric Liquid Crystal

A. Taguchi、Yukio Ouchi、Hideo Takezoe 等 4 位作者1989-06-01Japanese Journal of Applied Physics

Phase matched second harmonic generation was observed in a ferroelectric liquid crystal mixture. An electric field was applied parallel to glass plates of a homeotropically aligned cell in order to introduce a uniform alignment of the directors and the permanent dipoles. The phase matching was performed with an extrao…

Liquid Crystal Research AdvancementsPlant Reproductive BiologyMolecular spectroscopy and chirality

The use of direct convolution products in profile and pattern fitting algorithms. I. Development of algorithms

Scott A. Howard、Robert L. Snyder1989-06-01Journal of Applied Crystallography

Convolution products Were obtained by folding a specimen-related function into another function representing the intrinsic profile of the diffractometer used in this study. The instrumental contributions were modeled with three split-Pearson VII functions: one for each of the α1, α2 and α3 components in the Cu Kα spec…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsX-ray Diffraction in Crystallography

Substitution of a lysyl residue for arginine 386 of Escherichia coli aspartate aminotransferase

Yasushi Inoue、Seiki Kuramitsu、Ken‐ichiro Inoue 等 7 位作者1989-06-01Journal of Biological Chemistry

Substitution of a lysyl residue for Arg-386 of Escherichia coli aspartate aminotransferase resulted in an extensive decrease in Vmax values (0.8% with the aspartate-2-oxoglutarate pair and 0.2% with the glutamate-oxalacetate pair, compared with the corresponding values for the wild-type enzyme). Kinetic analysis of th…

Bacterial Genetics and BiotechnologyEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Strengthening of Ceria‐Doped Tetragonal Zirconia Polycrystals by Reduction‐Induced Phase Transformation

Karl‐Heinz Heussner、Nils Claussen1989-06-01Journal of the American Ceramic Society

Phase‐transformation‐induced compressive surface stresses were introduced into ceria‐doped tetragonal zirconia polycrystals by reduction of CeO 2 . Four‐point‐bending strength of sintered ZrO 2 containing 12 mol% CeO 2 increased from 240 to 545 MPa after it was annealed at 1400°C for 2 h in nitrogen. The strength of t…

Advanced ceramic materials synthesisMXene and MAX Phase MaterialsAdvanced materials and composites

Influence of calcium on the ferroelectricity of modified lead titanate ceramics

J. Mendiola、B. Jiménez、C. Alemany 等 5 位作者1989-06-01Ferroelectrics

Lead titanate ceramics modified with 24, 30, 35 and 40 mole% of calcium have been obtained. The thermal behaviour of permittivity as well as that of pyroelectric coefficient present a larger broadening the larger the Ca content, which could be adscribed to an increasing disorder on the Ca and Pb arrangement. On the ot…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesDielectric materials and actuators

Synthesis and characterization of a model saturated hydrocarbon diblock copolymer

Frank S. Bates、Jeffrey H. Rosedale、H. E. Bair 等 4 位作者1989-06-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and characterization of a model saturated hydrocarbon diblock copolymerFrank S. Bates, Jeffrey H. Rosedale, Harvey E. Bair, and Thomas P. RussellCite this: Macromolecules 1989, 22, 6, 2557–2564Publication Date (Print):June 1, 1989Publication History Published onlin…

Theoretical and Computational PhysicsMembrane Separation and Gas TransportBlock Copolymer Self-Assembly

Characterization of Boron-Doped Diamond Film

Ken Okano、Hidetoshi Naruki、Yukio Akiba 等 7 位作者1989-06-01Japanese Journal of Applied Physics

Diamond films doped with boron were fabricated by the thermal filament CVD method. Powdered B 2 O 3 was used as the doping source. The films were identified as diamond by means of several methods including Raman spectroscopy. The resistivity of the films was inversely proportional to the B / C ratio over four orders.…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchAdvanced Materials Characterization Techniques

Identification, molecular cloning and sequence analysis of a gene cluster encoding the Class II fructose 1,6‐bisphosphate aldolase, 3‐phosphoglycerate kinase and a putative second glyceraldehyde 3‐phosphate dehydrogenase of Escherichia coli

Peter R. Alefounder、Richard N. Perham1989-06-01Molecular Microbiology

To investigate a possible chromosomal clustering of glycolytic enzyme genes, the complete nucleotide sequence of the 8029 bp insert of Escherichia coli DNA in the ColE1 plasmid pLC33-5 of the Clarke and Carbon collection (Clark and Carbon, 1976) was determined. Genes (pgk, fda) encoding the phosphoglycerate kinase and…

Genomics and Phylogenetic StudiesGlycosylation and Glycoproteins ResearchEnzyme Structure and Function

Chemical and physical properties of electrochemically prepared polyaniline p-toluenesulfonates

Kyung Moon Choi、Keu Hong Kim、Jae Shi Choi1989-06-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChemical and physical properties of electrochemically prepared polyaniline p-toluenesulfonatesKyung Moon Choi, Keu Hong Kim, and Jae Shi ChoiCite this: J. Phys. Chem. 1989, 93, 11, 4659–4664Publication Date (Print):June 1, 1989Publication History Published online1 May 2002Pu…

Conducting polymers and applications