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Trisubstituted heteropolytungstates as soluble metal oxide analogs. III. Synthesis, characterization, phosphorus-31, silicon-29, vanadium-51, and 1- and 2-D tungsten-183 NMR, deprotonation, and proton mobility studies of organic solvent solute forms of HxSiW9V3O40x-7 and HxP2W15V3O62x-9

Richard G. Finke、Brian M. Rapko、Robert Saxton 等 4 位作者1986-05-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTrisubstituted heteropolytungstates as soluble metal oxide analogs. III. Synthesis, characterization, phosphorus-31, silicon-29, vanadium-51, and 1- and 2-D tungsten-183 NMR, deprotonation, and proton mobility studies of organic solvent solute forms of HxSiW9V3O40x-7 and HxP…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

Mechanisms of arterial graft healing. Rapid transmural capillary ingrowth provides a source of intimal endothelium and smooth muscle in porous PTFE prostheses.

A W Clowes、Thomas R. Kirkman、M A Reidy1986-05-01PubMed

Endothelial coverage of an exposed synthetic vascular graft surface limits thrombosis and may improve long-term graft performance. In most types of synthetic graft, luminal endothelium is derived from the cut edges of adjacent artery. In this study the authors investigated the possibility that endothelial coverage cou…

Electrospun Nanofibers in Biomedical ApplicationsConnective tissue disorders researchTissue Engineering and Regenerative Medicine

Theoretical Study of the Anomalies of Coated Dielectric Gratings

E. Popov、L. Mashev、D. Maystre1986-05-01Optica Acta International Journal of Optics

The zero-order diffraction efficiency anomalies of a corrugated dielectric waveguide are studied theoretically in detail. A new and surprising phenomenon is observed: the efficiency changes from 0 to 100 per cent in the vicinity of the excitation of guided waves. The fundamental parameters of the system are found in t…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Genesis of Mississippi Valley-Type Lead-Zinc Desposits

Dimitri A. Sverjensky1986-05-01Annual Review of Earth and Planetary Sciences

Carbonatites are igneous rocks formed in the crust by fractional crystallization of carbonate-rich parental melts that are mostly mantle derived. They dominantly consist of carbonate minerals such as calcite, dolomite, and ankerite, as well as minor ...Read More

Geological and Geochemical AnalysisPaleontology and Stratigraphy of FossilsClay minerals and soil interactions

Crystallization of poly(etheretherketone) (PEEK) in carbon fiber composites

Youngchul Lee、Roger S. Porter1986-05-01Polymer Engineering and Science

Abstract The tendency of carbon fiber to nucleate the zation of poly(etherettterlcetone) (PEEK) has been evaluated by DSC and other techniques. As the carbon fiber content was increased, the supercooling necessary for PEEK crystallization decreased. The repeated melting (at 396°C) of the same PEEK sample results in a…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesFiber-reinforced polymer composites

Localized Corrosion of Aluminum Alloys—A Review

R. T. Foley1986-05-01OpenAlex

Localized corrosion, which usually appears as pitting, crevice corrosion (CC), or certain aspects of stress corrosion cracking (SCC), is a multi-step process. This review is organized by a consideration of the four steps involved in localized corrosion: (1) adsorption of the reactive anion on the oxide covered aluminu…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityAnodic Oxide Films and Nanostructures

Extraction of phosphorus, potassium, calcium, and magnesium from soils by an ion‐exchange resin procedure

Bernardo van Raij、J. A. Quaggio、N.M. da Silva1986-05-01OpenAlex

A procedure for the simultaneous extraction of phosphorus, potassium, calcium and magnesium from soils, by an ion‐exchange resin procedure applicable to large‐scale advisory soil testing, is described. The important steps are the disaggregation of soil by shaking in water during 15 minutes with a glass marble, the tra…

Clay minerals and soil interactionsIron oxide chemistry and applicationsPhosphorus and nutrient management

Protein volumes and hydration effects. The calculations of partial specific volumes, neutron scattering matchpoints and 280-nm absorption coefficients for proteins and glycoproteins from amino acid sequences

Stephen J. Perkins1986-05-01OpenAlex

Amino acid sequences, carbohydrate compositions and residue volumes are used to compare critically calculations of partial specific volumes v, neutron scattering matchpoints and 280-nm absorption coefficients with experimental v values for proteins and glycoproteins. The v values that are obtained from amino acid dens…

Protein Structure and DynamicsEnzyme Structure and FunctionCrystallization and Solubility Studies

Optical band gap of indium nitride

T.L. Tansley、C. P. Foley1986-05-01OpenAlex

Room-temperature optical absorption data in the 1.5–2.5-eV range are reported for indium nitride thin films prepared by reactive radio-frequency sputtering. The fundamental absorption edge in high-purity material is located at 1.89±0.01 eV and corresponds to a direct transition at k=0, in agreement with band-structure…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGas Sensing Nanomaterials and Sensors

Improved Fourier coefficients for maps using phases from partial structures with errors

Randy J. Read1986-05-01OpenAlex

Unrefined or partially refined models of macromolecules are generally incomplete and typically have large coordinate errors. It is shown that phase probability equations appropriate for a perfect partial structure lead to inaccurate estimates of phase probabilities in such cases. Therefore, it is necessary to use equa…

Advancements in Photolithography TechniquesMachine Learning in Materials ScienceElectron and X-Ray Spectroscopy Techniques

The effect of alternating electric fields on ion migration in solid dielectrics

R.A. Fouracre、M.J. Given、B.H. Crichton1986-04-30Journal of Physics C Solid State Physics

A model has been developed that shows that an applied alternating electric field modifies the migration of ions in a solid dielectric material. In the case of a homogeneous alternating electric field, the components in the direction of the field of the ionic fluxes due to concentration gradients, when averaged over on…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesAnalytical Chemistry and Sensors

Fundamental ideas on metal-dielectric transitions in 3d-metal compounds

R. O. Zaǐtsev、Е. В. Кузьмин、С. Г. Овчинников1986-04-30Soviet Physics Uspekhi

The fundamental mechanisms of a metal-dielectric transition are examined. The multiband theory of the metal-dielectric transition is reviewed, as based on realistic models of the band structure of a set of oxides and sulfides of the 3d-metals in which the transition is accompanied by structural and magnetic phase tran…

Gas Sensing Nanomaterials and SensorsMultiferroics and related materialsTransition Metal Oxide Nanomaterials

The response of protein structures to amino-acid sequence changes

Arthur M. Lesk、Cyrus Chothia1986-04-30Philosophical Transactions of the Royal Society of London Series A Mathematical and Physical Sciences

Abstract The general response of protein structures to mutations, insertions and deletions is conformational change. Comparisons of related proteins show that a large part of the polypeptide chain retains its basic folding pattern. This ‘core’ of the structures comprises major elements of secondary structure and resid…

Protein Structure and DynamicsGlycosylation and Glycoproteins ResearchEnzyme Structure and Function

Degree of Charge Transfer in Donor–Acceptor Systems of the π–π Type

E Kampar、O. Neilands1986-04-30Russian Chemical Reviews

The principal methods for the determination of the degree of charge transfer are examined and experimental data on the intermolecular distribution of electron density in charge-transfer complexes and radical-ion salts of the π–π are surveyed. The relation between the degree of charge transfer and the ionisation potent…

Magnetism in coordination complexesPhotochemistry and Electron Transfer StudiesOrganic and Molecular Conductors Research

Consequences of Bond-Orientational Order on the Macroscopic Orientation Patterns of Thin Tilted Hexatic Liquid-Crystal Films

S. B. Dierker、R. Pindak、Robert B. Meyer1986-04-28Physical Review Letters

By use of depolarized laser relection microscopy, unique textural defects have been observed in thin tilted hexatic liquid-crystal films which result from their bond-orientational order. The temperature dependence of the bond-orientational elasticity can be deduced from these textural patterns and is in qualitative ag…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Icosahedral-Phase Formation by Solid-State Interdiffusion

D.M. Follstaedt、J. A. Knapp1986-04-28Physical Review Letters

We have formed the icosahedral phase in ${\mathrm{Al}}_{86}$${\mathrm{Mn}}_{14}$, ${\mathrm{Al}}_{82}$${\mathrm{Mn}}_{18}$, and ${\mathrm{Al}}_{75.5}$${\mathrm{Mn}}_{20}$${\mathrm{Si}}_{4.5}$ alloys by the interdiffusion of elemental layers in the solid state. Annealing at 250-425\ifmmode^\circ\else\textdegree\fi{}C p…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesQuasicrystal Structures and Properties

Third harmonic generation as a structural diagnostic of ion-implanted amorphous and crystalline silicon

David Moss、H. M. van Driel、J. E. Sipe1986-04-28Applied Physics Letters

We demonstrate the use of third harmonic generation as a probe of the bulk symmetry properties of semiconductors. Using 20 ns, 1.06 μm laser pulses we have applied this probe to structural diagnostics of (100) annealed and unannealed Si wafers implanted with boron and arsenic ions at dosages above and below the thresh…

Laser Material Processing TechniquesSilicon Nanostructures and PhotoluminescenceNonlinear Optical Materials Studies

Crystal growth and the role of the organic network in eggshell biomineralization

Heather Silyn‐Roberts、R. M. Sharp1986-04-22Proceedings of the Royal Society B Biological Sciences

Abstract A model based on geometrical crystal growth considerations is proposed for the deposition of the crocodilian, testudinian and avian eggshells. Ir each shell column, crystal deposition is initiated at a single location, from which growth fans out at all angles to the shell normal. In both co1citic and aragonit…

Paleontology and Evolutionary BiologyCalcium Carbonate Crystallization and InhibitionCephalopods and Marine Biology

Quasicrystalline Textures of Cholesteric Liquid Crystals: Blue Phase III?

Daniel S. Rokhsar、James P. Sethna1986-04-21Physical Review Letters

The energetics of icosahedral ordering in cholesteric liquid crystals are studied within the Landau mean-field approximation, in an attempt to describe the blue fog (blue phase III). We expand the free energy of a quasicrystalline phase in the high-chirality limit (coherence length much greater than pitch), and find t…

Liquid Crystal Research AdvancementsSolidification and crystal growth phenomenaQuasicrystal Structures and Properties

Extreme Swelling of a Lyotropic Lamellar Liquid Crystal

F. Lärché、J. Appell、G. Porte 等 5 位作者1986-04-21Physical Review Letters

The angular distribution of light scattered by an extremely dilute birefringent lyotropic phase shows two well-defined Bragg peaks providing strong evidence of a true lamellar order (lamellae \ensuremath{\sim} 40 \AA{} thick and 6500 \AA{} apart in the diluent). The steric origin of the stabilization of this stacking…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsNonlinear Dynamics and Pattern Formation