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Electronic structures of CuTPP and CuTPP(F) complexes. A combined experimental and theoretical study I

Giulia Mangione、Silvia Carlotto、Mauro Sambi 等 8 位作者2016-01-01Physical Chemistry Chemical Physics

Copper complexes of tetraphenylporphyrin (H2TPP) and tetrakis(pentafluorophenyl)porphyrin (H2TPP(F)) deposited as thin films on Au(111) have been studied experimentally and theoretically. Core level emissions from C 1s, N 1s, F 1s and Cu 2p as well as valence states of CuTPP and CuTPP(F) have been investigated using s…

Organic Light-Emitting Diodes ResearchPorphyrin and Phthalocyanine ChemistryMolecular Junctions and Nanostructures

Perfect Plasticity with Damage and Healing at Small Strains, Its Modeling, Analysis, and Computer Implementation

Tomáš Roubı́ček、Jan Valdman2016-01-01SIAM Journal on Applied Mathematics

The quasistatic, Prandtl--Reuss perfect plasticity at small strains is combined with a gradient, reversible (i.e., admitting healing) damage which influences both the elastic moduli and the yield stress. Existence of weak solutions of the resulting system of variational inequalities is proved by a suitable fractional-…

Numerical methods in engineeringComposite Material MechanicsNonlocal and gradient elasticity in micro/nano structures

Hybrid polyurea elastomers with enzymatic degradation and tunable mechanical properties

Nicholas A. Sears、Geraldine Pena-Galea、Stacy Cereceres 等 4 位作者2016-01-01Journal of Tissue Engineering

Herein, we report on the synthesis and characterization of enzymatically labile polyureas for use as a tissue-engineered ligament scaffold. Polyureas were selected due to their excellent tensile properties, fatigue resistance, and highly tunable nature. Incorporation of a collagenase-sensitive peptide into the backbon…

Cellular Mechanics and InteractionsTendon Structure and TreatmentSilk-based biomaterials and applications

Preparation and structural characterization of turbostratic-carbon/graphene derived from amylose film

N. E. S. Sazali、Mohamad Deraman、R. Omar 等 11 位作者2016-01-01AIP conference proceedings

In this study, we report the preparation of turbostratic-carbon/graphene from biomass amylose film by carbonization (N2 gas) and activation (CO2 gas) over different temperatures 600, 700, 800, 900, and 1000 °C, respectively. The Raman spectroscopy results of the produced samples show that the values of the ID/IG ratio…

Graphene research and applicationsSupercapacitor Materials and FabricationGraphene and Nanomaterials Applications

Modulation of the relaxation dynamics of linear-shaped tetranuclear rare-earth clusters through utilizing different solvents

Ruxia Zhang、Yi-Xin Chang、Hai-Yun Shen 等 8 位作者2016-01-01Dalton Transactions

-based complexes (3 and 8) exhibit single-molecule magnet (SMM) behavior under a zero dc field. Furthermore, complex 3 presents one relaxation process under a zero dc field, while application of an external dc field (1500 Oe) induces multi-relaxation signals of the ac magnetic susceptibility.

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research

A highly adhesive siloxane LED encapsulant optimized for high thermal stability and optical efficiency

Yong Ho Kim、Young‐Woo Lim、Daewon Lee 等 5 位作者2016-01-01Journal of Materials Chemistry C

Herein, a highly adhesive LED encapsulant (HAEncap) is proposed based on a phenyl siloxane hybrid material with a high thermal stability, refractive index, and transparency which uses cost-effective radical polymerization.

Luminescence and Fluorescent MaterialsSynthesis and properties of polymersSilicone and Siloxane Chemistry

Optical advantages of graphene on the boron nitride in visible and SW-NIR regions

Jingang Wang、Shuo Cao、Peng Sun 等 6 位作者2016-01-01RSC Advances

We theoretically study optical advantages of graphene on boron nitride for advanced materials and reveals that the boron nitride is one of best substrates for graphene-based nano-photonic devices.

Graphene research and applications2D Materials and ApplicationsPlasmonic and Surface Plasmon Research

MoO 3 @Ni nanowire array hierarchical anode for high capacity and superior longevity all-metal-oxide asymmetric supercapacitors

Chao Xu、Jie Liao、Ruozheng Wang 等 7 位作者2016-01-01RSC Advances

An all-metal-oxide asymmetric supercapacitor based on MoO <sub>3</sub> @Ni nanowire array anode with high mass loading and VO <sub>2</sub> @NNA nanowire array cathode was constructed, which achieved a real capacity (307 mF cm <sup>−2</sup> ) and cyclability (116.6% capacitance retention after 20 000 cycles).

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Kinetic consequences of methane combustion on Pd, Pt and Pd–Pt catalysts

Wenjie Qi、Jingyu Ran、Ruirui Wang 等 8 位作者2016-01-01RSC Advances

The kinetic consequences of methane combustion on Pd <sub>x</sub> Pt <sub>1−x</sub> oxide surfaces were investigated with kinetic data and density functional theory treatments.

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Stability, electronic structures and thermoelectric properties of binary Zn–Sb materials

Xin He、Yuhao Fu、David J. Singh 等 4 位作者2016-01-01Journal of Materials Chemistry C

The composition–structure–property relationship of a complex high-performance thermoelectric system, Zn–Sb compounds, is systemically investigated by first-principles calculations.

Advanced Thermoelectric Materials and DevicesThermal properties of materialsHeusler alloys: electronic and magnetic properties

Designed synthesis of MO x (M = Zn, Fe, Sn, Ni, Mn, Co, Ce, Mg, Ag), Pt, and Au nanoparticles supported on hierarchical CuO hollow structures

Zailei Zhang、Ji Chul Jung、Ning Yan2016-01-01Nanoscale

Despite intensive research into support substrates for the dispersal of nanoparticles and their applications, there has been a lack of general methods to produce metal oxide hollow substrates supporting a wide range of metal and metal oxides. Herein, a synthetic protocol for the preparation of CuO hollow structure-sup…

Catalytic Processes in Materials ScienceCopper-based nanomaterials and applicationsNanomaterials for catalytic reactions

Intercalated soft-crystalline mesophase exhibited by an unsymmetrical twist-bend nematogen

Richard J. Mandle、John W. Goodby2016-01-01CrystEngComm

A number of new states of matter have been reported in recent years for liquid crystal dimers, most notably the twist-bend nematic phase which exhibits spontaneous breaking of symmetry through the emergence of chiral structures in an achiral fluid. In this communication we report on an unsymmetrical liquid crystal dim…

Liquid Crystal Research AdvancementsPlant Reproductive BiologyMolecular spectroscopy and chirality

Effects of Multiwalled Carbon Nanotube Surface Modification and Purification on Bovine Serum Albumin Binding and Biological Responses

Wei Bai、Zheqiong Wu、Somenath Mitra 等 4 位作者2016-01-01Journal of Nanomaterials

The potential diagnostic and therapeutic applications such as drug delivery of multi-walled carbon nanotubes (MWCNTs) are being increasingly explored due to their unique mechanical, chemical and biological properties. Carboxylation of MWCNTs has been widely used to improve the solubility in aqueous systems, and for fu…

Nanoparticles: synthesis and applicationsVitamin C and Antioxidants ResearchGraphene and Nanomaterials Applications

Thiocyanate copper complexes with pyrazole-derived ligands – synthesis, crystal structures, DFT calculations and magnetic properties

Anna Świtlicka、Katarzyna Czerwińska、B. Machura 等 7 位作者2016-01-01CrystEngComm

This paper presents the synthesis, X-ray studies, spectroscopic characterization and variable temperature magnetic investigations and DFT calculation of four novel thiocyanato Cu(II) compounds [Cu(mpz)2(NCS)2]n·nH2O (1), {[Cu2(dmpz)4(NCS)4][Cu(dmpz)(NCS)2]}n·2nMeOH (2) [(bdmpzm)CuII(SCN)2(μ1,3-SCN)CuI(bdmpzm)]n (3) an…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

Two photochromic methylated nicotinohydrazide iodoargentate hybrids

Junju Shen、Feng Wang、Xiangxia Li 等 6 位作者2016-01-01RSC Advances

Two methylated nicotinohydrazide iodoargentate hybrids have been synthesized <italic>via</italic> modulating organic/inorganic ratio, which exhibit rare structure-dependent electron-transfer (ET) photochromism.

Porphyrin and Phthalocyanine ChemistryPolyoxometalates: Synthesis and ApplicationsPhotochromic and Fluorescence Chemistry

Novel aminoalkyl tris-cyclometalated iridium complexes as cellular stains

Anuson Sansee、Sureemas Meksawangwong、Kittipong Chainok 等 10 位作者2016-01-01Dalton Transactions

] bearing amino alkyl groups on one of the phenylpyridine rings. The complexes are highly emissive and exhibit structured emission peaks in aqueous solution while having only broad unstructured emission in organic solvents. The complexes have been shown to be taken up by NIH-3T3 and PC3 cells, where they localize in t…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials