Materials Literature
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Nanoprobes are advantageous over small molecular probes in sensitivity but most luminescence molecules used to construct nanoprobes often suffer from an aggregation-caused quenching effect. Herein, we rationally designed a small molecular probe Cys(StBu)-Lys(Ru(bpy)32+)-CBT (1) which "smartly" self-assembled into nano…
Chemical vapor deposition is used for the growth of scalable single-crystal graphene by seamlessly stitching millimeter-sized aligned hexagonal domains on different types of commercial Cu foils, without repeated substrate polishing and H <sub>2</sub> annealing.
YBaCo <sub>2</sub> O <sub>6</sub> epitaxial thin films with strong ferromagnetic anisotropy were obtained <italic>via</italic> low-temperature topotactic oxidation using a strong oxidizing agent NaClO.
Praseodymium forms complexes easily with nitrogen and oxygen donor pyrazolines and also forms mixed ligand complexes with these pyrazolines and sulfur donor thio ligands such as dithiocarbamates and xanthates. These newly synthesized complexes have been characterized using elemental analysis, FTIR, TGA, SEM, TEM, PXRD…
, respectively, at pH 6 and 25 °C. In this situation, intermolecular interactions including π-π interactions and hydrogen bonding are operative. The calculated results of density functional theory further demonstrate that 2,4-DCP molecules could be more easily absorbed than 4-CP molecules by the M-DF-RGO hybrid. Moreo…
This study presents the synthesis, characterization and toluene sensing properties of copper(II), indium(III) acetate, mono-lutetium(III) acetate and tin(IV) phthalocyanines substituted with 2,6-dimethoxyphenol bioactive groups at the peripheral and non-peripheral positions. The effects of the substituent’s position o…
Elemental mercury has become a global concern because of its significant impact on human health and the ecosystem. A lot of effort has been put towards the removal of elemental mercury from the 2H-MoS 2 (prismatic structure of MoS 2 ). However, the mechanism of 1T-MoS 2 (polytype structure of MoS 2 ) in Hg 0 capture r…
A novel eggplant derived carbon tube network/FeOOH composite for supercapacitor applications was synthesized <italic>via</italic> freeze-drying, <italic>in situ</italic> carbonization and a hydrothermal method.
ferroelectric/dielectric heteroepitaxial superlattice nanostructures is strongly influenced by the edges of the structures. Synchrotron X-ray nanobeam diffraction reveals that the spontaneously formed 180° ferroelectric stripe domains exhibited by such superlattices adopt a configuration in rectangular nanostructures…
A novel synthesis methodology was applied for obtaining ferrimagnetic Mn <sub>1+x</sub> M(IIIA) <sub>2−x</sub> O <sub>4</sub> spinels (M(IIIA) = Ga <sup>3+</sup> and Al <sup>3+</sup> ) with small optical band gaps due to mixed valence Mn <sup>2+</sup> –Mn <sup>3+</sup> states.
The linear correlation between the ratios of linear and nonlinear intrinsic mechanical properties allows the prediction of largely unknown nonlinear fracture properties of brittle two-dimensional (2D) solids using a reference model. It is demonstrated that from accurately known Young's moduli unknown theoretical stren…
A discontinuous lanthanum (La <sup>3+</sup> )-coated ZnO nanorod-based multisensor was fabricated for the first time. The H <sub>2</sub> gas and UV sensing properties were studied simultaneously.
Structure disorder especially edge disorder is unavoidable during the fabrication of nanomaterials. In this paper, using the non-equilibrium Green's function method, we investigate the influence of edge disorder on the thermoelectric performance of gamma(γ)-graphyne nanoribbons (GYNRs). Our results show that the high…
This study reports the high rate and low-temperature deposition of high-quality ITO films using a new 3-D confined magnetron sputtering method.
Study on the optoelectronic characteristics of a cation-substituted nanostructure is a specific area of recent interest for a wide range of photonic applications.
A new series of Mo( <sc>iv</sc> ) chloride complexes with thioether and seleneoether ligands is reported; [MoCl <sub>4</sub> ( <sup>n</sup> Bu <sub>2</sub> E) <sub>2</sub> ] (E = S, Se) function as single source precursors for the CVD of MoE <sub>2</sub> thin films.
The effects of the staggered double vacancies, hydrogen (H), 3d transition metals, for example cobalt, and semiconductor covalent atoms, for example, germanium, nitrogen, phosphorus (P) and silicon adsorption on the transport properties of monolayer phosphorene were studied using density functional theory and non-equi…
Phthalocyanines are proposed as catalytic, transparent, promisingly stable cathode coatings for cobalt mediated DSSCs, representing a nearly ideal cathode material.
A new layered antiferromagnet was synthesized from the reaction of a paddlewheel diruthenium( <sc>ii</sc> , <sc>ii</sc> ) complex with a TCNQ derivative. The complex has a short interlayer distance and forms part of a series of layered antiferromagnets.
The critical mixing intensity for secondary nucleation of paracetamol was determined in an oscillatory flow crystallizer for the first time.