Materials Literature
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The inscription of deep surface relief grating (SRG) in glassy monomeric azobenzene materials using a low intensity diode pumped solid state (DPSS) laser operating at 532 nm is demonstrated. Previously developed epoxy-based star-like azobenzene-containing material was applied. Both deep SRG and multi-dimensional struc…
We report the design and fabrication of V-shaped plasmonic meta-polymers on a glass substrate or silicon wafer using a surface functionalization approach. The efficacy of the assembly method is examined by analyzing the surface enhanced Raman scattering by an individual V-shaped antenna experimentally and using comput…
The LMO/BFO interface induces the transition from a cluster glass state to a spin glass state in the LMO/BFO heterostructure.
Sb doped Mg <sub>2</sub> Si <sub>0.4</sub> Sn <sub>0.6</sub> materials feature with lots of dislocations at grain boundaries and plenty of nanoscale Mg <sub>2</sub> Si–Mg <sub>2</sub> Sn spinodal phases, both of which can scatter heat carrying phonons and suppress the bipolar effects, with a optimal <italic>ZT</italic…
The effect of doping on the electronic properties in bulk single-walled carbon nanotube (SWCNT) samples is studied for the first time using a new in situ Raman spectroelectrochemical method, and further verified by DFT calculations and photoresponse. We use p-/n-doped SWCNTs prepared by diazonium reactions as a versat…
Compound (4,4[Formula: see text] -hex-3-ene-3,4-diyl)bis(4,1-phenylene)bis(oxy)diphthalonitrile 3 was synthesized by the reaction of 4-nitrophthalonitrile 1 and diethylstilbestrol 2 in dry DMF in presence of dry K 2 CO 3 . New mononuclear phthalocyanines 4-6 were obtained from compound 3 by addition of the correspondi…
Application of a grinding-heating strategy in the controlled synthesis of gallium-based supramolecular square nanoplates and γ-Ga <sub>2</sub> O <sub>3</sub> layer nanosheets.
Objective The objective of this paper is to evaluate potential dose-dependent adverse effects of gadolinium-based contrast agents (GBCAs) on MS progression. Methods Outcomes from a cohort of 612 secondary progressive MS (SPMS) patients, enrolled in a two-year, placebo-controlled (negative) trial assessing the efficacy…
While molecular dynamics (MD) has proven to be a promising approach to investigate the diffusion properties, the grand challenge resides in evaluating potential model parameters to accurately replicate experimentally measured properties. The Buckingham potential model with Columbic interaction is widely employed in MD…
The mutual interaction between two close bubbles in an acoustic field is studied. This interaction is modeled in the linear framework of the multiple scattering theory using spherical harmonics expansions and the addition theorem. In order to deal with small as well as large bubbles, viscous dissipation in the liquid,…
Monitoring the catalytically active state and online mass spectra clarified the fast transient phenomena occurring inside a NSR catalyst.
Polyion complex (PIC) micelles are frequently used as a means to deliver biologics such as proteins.
The frontier molecular orbitals, UV-Vis absorption spectra, charge transfer (CT) and triplet excited states of 12 expanded D-A porphyrin/benzoporphyrin complexes were investigated using the density functional theory (DFT) method and time-dependent DFT in this work. The results showed that thiophene was an effective fr…
Natural biomaterials are more and more used for the development of high technology solutions, setting the scene for a bio-based material economy that responds to the increasing demand of environmentally friendly products. Among natural biomaterials, silk fibre protein called silk fibroin (SF) produced by the Bombyx mo…
Dealloyed nanoporous metals hold great promise in the field of heterogeneous catalysis; however their tendency to coarsen at elevated temperatures or under catalytic reaction conditions sometimes limit further applications. Here, we report on a highly stable nanoporous gold catalyst (npAu) functionalized with praseody…
In this communication, we report the post-synthetic functionalization of K+/Ni2+/[Cr(CN)6]3- Prussian blue analogue (PBA) nanoparticles by the 2-aminoanthracene luminophore to yield a bifunctional magneto-luminescent nanosystem. The photoluminescence properties of the fluorophore are found modified by the confinement…
The experimental conditions necessary for stabilising irbesartan (IBS) tautomers in solution and selectively obtaining the desmotropic crystal forms are presented herein. 1H and 2H tautomers were stabilized in specific solution conditions and the 2H-tetrazole⋯imidazole interaction was confirmed by solution-state NMR.…
PLE spectra of the phosphors. Inset (a) excitation intensity at 352 nm and 468 nm as function of doping Ga <sup>3+</sup> concentration. Inset (b) ratio of excitation intensity at 468 nm to that at 352 nm as function of Ga <sup>3+</sup> concentration.
Two-dimensional (2D) crystals are candidate materials for electronics and spintronics, but their deficient carrier mobility, inappreciable spin-orbit coupling effect, and environmental instability have such limited applications. Herein, using density functional theory methods, we propose a novel 2D monolayer material,…
deposition diffusion aggregation (DDA) and the orientation attachment (OA) process, and (iii) nucleation and growth of Mg nanowires. In depth analysis confirms two types of nanowires, straight and serpentine-like, where the latter dominates as the holding duration/temperature of the synthesis increases. The straight n…