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Optical Generation and Detection of Local Nonequilibrium Phonons in Suspended Graphene

Sean E. Sullivan、Ajit K. Vallabhaneni、Iskandar Kholmanov 等 6 位作者2017-02-21Nano Letters

The measured frequencies and intensities of different first- and second-order Raman peaks of suspended graphene are used to show that optical phonons and different acoustic phonon polarizations are driven out of local equilibrium inside a submicron laser spot. The experimental results are correlated with a first-princ…

Graphene research and applicationsThermal properties of materialsThermal Radiation and Cooling Technologies

Flexible Transparent Field-Effect Diodes Fabricated at Low-Temperature with All Oxide Materials

Yonghui Zhang、Zengxia Mei、Shujuan Cui 等 6 位作者2017-02-21arXiv

Flexible fully transparent diodes with high rectification ratio of 5 e 8 are fabricated with all oxide materials at low temperature. The devices are optically transparent in visible spectra range and electrically robust while mechanically bending. Distinguished from other diodes, these diodes utilize diode-connected t…

Materials Science

Transport band gap opening at metal-organic interfaces

Francisc Haidu、Georgeta Salvan、Dietrich R. T. Zahn 等 6 位作者2017-02-21arXiv

The interface formation between copper phthalocyanine (CuPc) and two representative metal substrates, i.e., Au and Co, was investigated by the combination of ultraviolet photoelectron spectroscopy and inverse photoelectron spectroscopy. The occupied and unoccupied molecular orbitals and thus the transport band gap of…

Materials ScienceChemical Physics

Two‐Dimensional Semiconductors Grown by Chemical Vapor Transport

Dake Hu、Guanchen Xu、Lei Xing 等 10 位作者2017-02-21Angewandte Chemie International Edition

Abstract Developing controlled approaches for synthesizing high‐quality two‐dimensional (2D) semiconductors is essential for their practical applications in novel electronics. The application of chemical vapor transport (CVT), an old single‐crystal growth technique, has been extended from growing 3D crystals to synthe…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Grain size threshold for enhanced irradiation resistance in nanocrystalline and ultrafine tungsten

Osman El‐Atwani、J.A. Hinks、Graeme Greaves 等 5 位作者2017-02-21Materials Research Letters

Nanocrystalline metals are considered highly radiation-resistant materials due to their large grain boundary areas. Here, the existence of a grain size threshold for enhanced irradiation resistance in high-temperature helium-irradiated nanocrystalline and ultrafine tungsten is demonstrated. Average bubble density, pro…

Fusion materials and technologiesIon-surface interactions and analysisNuclear materials and radiation effects

Molecular Engineering and Design of Semiconducting Polymer Dots with Narrow-Band, Near-Infrared Emission for in Vivo Biological Imaging

Chi-Shiang Ke、Chia-Chia Fang、Jia-Ying Yan 等 10 位作者2017-02-21ACS Nano

This article describes the design and synthesis of donor-bridge-acceptor-based semiconducting polymer dots (Pdots) that exhibit narrow-band emissions, ultrahigh brightness, and large Stokes shifts in the near-infrared (NIR) region. We systematically investigated the effect of π-bridges on the fluorescence quantum yiel…

Nanoplatforms for cancer theranosticsLuminescence and Fluorescent MaterialsPolydiacetylene-based materials and applications

Ultrasmall-Superbright Neodymium-Upconversion Nanoparticles via Energy Migration Manipulation and Lattice Modification: 808 nm-Activated Drug Release

Yan Zhang、Zhongzheng Yu、Jingqiu Li 等 8 位作者2017-02-21ACS Nano

Nd 3+ -sensitized upconversion nanoparticles are among the most promising emerging fluorescent nanotransducers. They are activated by 808 nm irradiation, which features merits such as limited tissue overheating and deeper penetration depth, and hence are attractive for diagnostic and therapeutic applications. Recent s…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesLuminescence and Fluorescent Materials

Synthesis and Fabrication of Collagen-Coated Ostholamide Electrospun Nanofiber Scaffold for Wound Healing

Subramani Kandhasamy、Sathiamurthi Perumal、Balaraman Madhan 等 7 位作者2017-02-21ACS Applied Materials & Interfaces

C, DEPT-135 NMR, ESI-MS, and FT-IR spectroscopy analysis. OSA was incorporated into polyhydroxybutyrate (PHB) and gelatin (GEL), which serve as templates for electrospun nanofibers. The coating of OSA-PHB-GEL nanofibers with collagen resulted in PHB-GEL-OSA-COL nanofibrous scaffold which mimics extracellular matrix an…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

In‐Plane 2H‐1T′ MoTe2 Homojunctions Synthesized by Flux‐Controlled Phase Engineering

Youngdong Yoo、Zachary P. Degregorio、Yang Su 等 5 位作者2017-02-21Advanced Materials

The fabrication of in‐plane 2H‐1T′ MoTe 2 homojunctions by the flux‐controlled, phase‐engineering of few‐layer MoTe 2 from Mo nanoislands is reported. The phase of few‐layer MoTe 2 is controlled by simply changing Te atomic flux controlled by the temperature of the reaction vessel. Few‐layer 2H MoTe 2 is formed with h…

Perovskite Materials and Applications2D Materials and ApplicationsMXene and MAX Phase Materials

Effect of Phase Transitions on Thermal Depoling in Lead-Free 0.94(Bi 0.5 Na 0.5 TiO 3 )–0.06(BaTiO 3 ) Based Piezoelectrics

Amit Mahajan、Hangfeng Zhang、Jiyue Wu 等 6 位作者2017-02-21The Journal of Physical Chemistry C

High Resolution Image Download MS PowerPoint Slide 0.94(Bi 0.5 Na 0.5 TiO 3 )–0.06(BaTiO 3 ) (BNTBT) is a potential lead-free piezoelectric candidate to replace lead-based PZT ceramics. The thermal depoling temperature sets the upper limit for the high temperature application of piezoelectric materials. Recently, an i…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesDielectric materials and actuators

The unique hydration state of poly(2-methacryloyloxyethyl phosphorylcholine)

Kazuhíko Ishihara、Mingwei Mu、Tomohiro Konno 等 5 位作者2017-02-21Journal of Biomaterials Science Polymer Edition

2-Methacryloyloxyethyl phosphorylcholine (MPC) is methacrylate bearing a phosphorylcholine group in the side chain. The phosphorylcholine group generates several unique properties arising from its zwitterionic structure, consisting of a phosphate anion and a trimethylammonium cation. Despite these charged groups, the…

Advanced Polymer Synthesis and CharacterizationMicrofluidic and Capillary Electrophoresis ApplicationsPolymer Surface Interaction Studies

Uniformly Dispersed ZnFe2O4 Nanoparticles on Nitrogen-Modified Graphene for High-Performance Supercapacitor as Electrode

Lei Li、Huiting Bi、Shili Gai 等 10 位作者2017-02-21Scientific Reports

Abstract A facile strategy has been adopted for the preparation of ZnFe 2 O 4 /NRG composite by anchoring ultrasmall ZnFe 2 O 4 nanoparticles on nitrogen-doped reduced graphene (denoted as NRG) for high-performance supercapacitor electrode. Remarkably, the growth of ZnFe 2 O 4 nanocrystals, the reduction of graphitic…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Experimental and Ab Initio Ultrafast Carrier Dynamics in Plasmonic Nanoparticles

Ana M. Brown、Ravishankar Sundararaman、P. Narang 等 6 位作者2017-02-21Physical Review Letters

Ultrafast pump-probe measurements of plasmonic nanostructures probe the nonequilibrium behavior of excited carriers, which involves several competing effects obscured in typical empirical analyses. Here we present pump-probe measurements of plasmonic nanoparticles along with a complete theoretical description based on…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchQuantum Dots Synthesis And Properties

Control of Surface and Edge Oxidation on Phosphorene

Kaci L. Kuntz、Rebekah A. Wells、Jun Hu 等 11 位作者2017-02-21ACS Applied Materials & Interfaces

Phosphorene is emerging as an important two-dimensional semiconductor, but controlling the surface chemistry of phosphorene remains a significant challenge. Here, we show that controlled oxidation of phosphorene determines the composition and spatial distribution of the resulting oxide. We used X-ray photoemission spe…

Advanced Photocatalysis TechniquesGraphene research and applications2D Materials and Applications

A Single Crystal with Multiple Functions of Optical Waveguide, Aggregation-Induced Emission, and Mechanochromism

Yan Li、Zhiyong Ma、Aisen Li 等 9 位作者2017-02-21ACS Applied Materials & Interfaces

A novel single crystal, PyB, is produced in a high yield by the simple method of connecting a pyrene unit and a rhodamine B moiety together. PyB shows multiple functions of aggregation-induced emission, low-loss optical waveguiding, and tricolored mechanochromism. The crucial point for fabricating such a multifunction…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

A Highly Durable, Transferable, and Substrate‐Versatile High‐Performance All‐Polymer Micro‐Supercapacitor with Plug‐and‐Play Function

Minshen Zhu、Yang Huang、Yan Huang 等 9 位作者2017-02-21Advanced Materials

A highly durable high-performance all-polymer micro-supercapacitor with plug-and-play function is developed. Through the newly developed technology, these micro-supercapacitors can be transferred to any substrate with all functions well retained.

Advancements in Battery MaterialsSupercapacitor Materials and FabricationConducting polymers and applications

Broadband terahertz half-wave plate based on anisotropic polarization conversion metamaterials

Rui Xia、Xufeng Jing、Xincui Gui 等 5 位作者2017-02-21Optical Materials Express

We propose a half wave plate in the terahertz region to realize broadband linear polarization conversion in the reflection mode through anisotropic metamaterials. The structure of this design is composed of two pairs of patches in one unit cell that can rotate the polarization direction of a linearly polarized inciden…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Gaussian-Based Coupled-Cluster Theory for the Ground-State and Band Structure of Solids

James McClain、Qiming Sun、Garnet Kin‐Lic Chan 等 4 位作者2017-02-21Journal of Chemical Theory and Computation

We present the results of Gaussian-based ground-state and excited-state equation-of-motion coupled-cluster theory with single and double excitations for three-dimensional solids. We focus on diamond and silicon, which are paradigmatic covalent semiconductors. In addition to ground-state properties (the lattice constan…

Advanced Chemical Physics StudiesHigh-pressure geophysics and materialsElectronic and Structural Properties of Oxides

Highly Efficient and Thermally Stable K3AlF6:Mn4+ as a Red Phosphor for Ultra-High-Performance Warm White Light-Emitting Diodes

Enhai Song、Jianqing Wang、Jiahao Shi 等 9 位作者2017-02-21ACS Applied Materials & Interfaces

Following pioneering work, solution-processable Mn 4+ -activated fluoride pigments, such as A 2 BF 6 (A = Na, K, Rb, Cs; A 2 = Ba, Zn; B = Si, Ge, Ti, Zr, Sn), have attracted considerable attention as highly promising red phosphors for warm white light-emitting diodes (W-LEDs). To date, these fluoride pigments have be…

Luminescence Properties of Advanced MaterialsSolid State Laser TechnologiesInorganic Fluorides and Related Compounds